Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium

Autores
Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.
Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Materia
ELECTROCHEMISTRY
MATERIALS SCIENCE
METHANOL ELECTROOXIDATION
NANOPARTICLES
SUPPORTED CATALYSTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/92488
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/92488
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid MediumComignani, VaninaSieben, Juan ManuelBrigante, Maximiliano EduardoDuarte, Marta María ElenaELECTROCHEMISTRYMATERIALS SCIENCEMETHANOL ELECTROOXIDATIONNANOPARTICLESSUPPORTED CATALYSTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaWiley-VCH Verlag2018-05-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/92488Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-21252196-0216CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/celc.201800413info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/celc.201800413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:02:59Zoai:ri.conicet.gov.ar:11336/92488instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:02:59.715CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
title Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
spellingShingle Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
Comignani, Vanina
ELECTROCHEMISTRY
MATERIALS SCIENCE
METHANOL ELECTROOXIDATION
NANOPARTICLES
SUPPORTED CATALYSTS
title_short Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
title_full Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
title_fullStr Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
title_full_unstemmed Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
title_sort Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
dc.creator.none.fl_str_mv Comignani, Vanina
Sieben, Juan Manuel
Brigante, Maximiliano Eduardo
Duarte, Marta María Elena
author Comignani, Vanina
author_facet Comignani, Vanina
Sieben, Juan Manuel
Brigante, Maximiliano Eduardo
Duarte, Marta María Elena
author_role author
author2 Sieben, Juan Manuel
Brigante, Maximiliano Eduardo
Duarte, Marta María Elena
author2_role author
author
author
dc.subject.none.fl_str_mv ELECTROCHEMISTRY
MATERIALS SCIENCE
METHANOL ELECTROOXIDATION
NANOPARTICLES
SUPPORTED CATALYSTS
topic ELECTROCHEMISTRY
MATERIALS SCIENCE
METHANOL ELECTROOXIDATION
NANOPARTICLES
SUPPORTED CATALYSTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.
Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
description In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.
publishDate 2018
dc.date.none.fl_str_mv 2018-05-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/92488
Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-2125
2196-0216
CONICET Digital
CONICET
url http://hdl.handle.net/11336/92488
identifier_str_mv Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-2125
2196-0216
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/celc.201800413
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/celc.201800413
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH Verlag
publisher.none.fl_str_mv Wiley-VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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