Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium
- Autores
- Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.
Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina - Materia
-
ELECTROCHEMISTRY
MATERIALS SCIENCE
METHANOL ELECTROOXIDATION
NANOPARTICLES
SUPPORTED CATALYSTS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/92488
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Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid MediumComignani, VaninaSieben, Juan ManuelBrigante, Maximiliano EduardoDuarte, Marta María ElenaELECTROCHEMISTRYMATERIALS SCIENCEMETHANOL ELECTROOXIDATIONNANOPARTICLESSUPPORTED CATALYSTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol.Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaWiley-VCH Verlag2018-05-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/92488Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-21252196-0216CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/celc.201800413info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/celc.201800413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:58Zoai:ri.conicet.gov.ar:11336/92488instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:58.257CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
title |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
spellingShingle |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium Comignani, Vanina ELECTROCHEMISTRY MATERIALS SCIENCE METHANOL ELECTROOXIDATION NANOPARTICLES SUPPORTED CATALYSTS |
title_short |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
title_full |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
title_fullStr |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
title_full_unstemmed |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
title_sort |
Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium |
dc.creator.none.fl_str_mv |
Comignani, Vanina Sieben, Juan Manuel Brigante, Maximiliano Eduardo Duarte, Marta María Elena |
author |
Comignani, Vanina |
author_facet |
Comignani, Vanina Sieben, Juan Manuel Brigante, Maximiliano Eduardo Duarte, Marta María Elena |
author_role |
author |
author2 |
Sieben, Juan Manuel Brigante, Maximiliano Eduardo Duarte, Marta María Elena |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
ELECTROCHEMISTRY MATERIALS SCIENCE METHANOL ELECTROOXIDATION NANOPARTICLES SUPPORTED CATALYSTS |
topic |
ELECTROCHEMISTRY MATERIALS SCIENCE METHANOL ELECTROOXIDATION NANOPARTICLES SUPPORTED CATALYSTS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol. Fil: Comignani, Vanina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina Fil: Brigante, Maximiliano Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Duarte, Marta María Elena. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina |
description |
In this work, PtRu nanoparticles supported on hybrid manganese (II,III)-carbon composites were prepared by a microwave-assisted polyol process in ethylene glycol. The obtained PtRu/(100-x) C.xMn 3 O 4 catalysts were characterized by XRD diffraction, TEM, SEM-EDX analysis, ICP-AES and electrochemical techniques. Small and well-distributed nanoparticles of about 2.6 nm were obtained over the hybrid support. The as-prepared catalysts presented similar Pt : Ru atomic ratio (ca. 3.4 : 1), indicating that the composition of the bimetallic system is unaffected by the oxide content in the hybrid support. However, the noble metal loading increased with the increase in the oxide content due to the formation of more nucleation sites during microwave heating. The electrochemical experiments showed that the best performance and the lowest poisoning rate are obtained with PtRu/90C.10Mn 3 O 4 followed by PtRu/70C.30Mn 3 O 4 . The bimetallic catalyst supported over 90C.10Mn 3 O 4 exhibited a steady current density of 215 mA mg PtRu −1 at 0.5 V, which is 40 % higher than that of PtRu/C. This behavior is mainly associated with the ability of Mn 3 O 4 to provide a large extra amount of hydroxyl groups and promote the dehydrogenation of methanol. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-05-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/92488 Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-2125 2196-0216 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/92488 |
identifier_str_mv |
Comignani, Vanina; Sieben, Juan Manuel; Brigante, Maximiliano Eduardo; Duarte, Marta María Elena; Manganese (II,III) Oxide-Activated Carbon Black Supported PtRu Nanoparticles for Methanol Electrooxidation in Acid Medium; Wiley-VCH Verlag; ChemElectroChem; 5; 15; 04-5-2018; 2118-2125 2196-0216 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/celc.201800413 info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/celc.201800413 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley-VCH Verlag |
publisher.none.fl_str_mv |
Wiley-VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613085236559872 |
score |
13.070432 |