Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48

Autores
Gutierrez, Victoria Soledad; Dennehy, Mariana; Diez, Alejandra Silvina; Volpe, María Alicia
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A series of Cu/MCM-48 catalysts is studied for the liquid phase hydrogenation of crotonaldehyde. Copper is incorporated in MCM-48 following a classical hydrothermal synthesis or by wet impregnation of the MCM-48 precursor (before eliminating the directing agent) with Cu(AcAc)2. The copper loading is in the 2-20 wt% range. Characterization results from TPR and XRD indicate that copper crystals supported on MCM-48 surface coexist with copper incorporated in the MCM-48 walls. The presence of Cu+ in MCM-48 is concluded from characterization with FTIR of adsorbed CO. This species would be the responsible for the relatively high selectivity of Cu/MCM-48. These catalysts show approximately 50% of selectivity against 7% of Cu/SiO2 (both values measured at 10% of conversion).
Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
CO ADSORPTION
COPPER CATALYSTS
CROTONALDEHYDE
MCM-48
SELECTIVE HYDROGENATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/97033
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/97033
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48Gutierrez, Victoria SoledadDennehy, MarianaDiez, Alejandra SilvinaVolpe, María AliciaCO ADSORPTIONCOPPER CATALYSTSCROTONALDEHYDEMCM-48SELECTIVE HYDROGENATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of Cu/MCM-48 catalysts is studied for the liquid phase hydrogenation of crotonaldehyde. Copper is incorporated in MCM-48 following a classical hydrothermal synthesis or by wet impregnation of the MCM-48 precursor (before eliminating the directing agent) with Cu(AcAc)2. The copper loading is in the 2-20 wt% range. Characterization results from TPR and XRD indicate that copper crystals supported on MCM-48 surface coexist with copper incorporated in the MCM-48 walls. The presence of Cu+ in MCM-48 is concluded from characterization with FTIR of adsorbed CO. This species would be the responsible for the relatively high selectivity of Cu/MCM-48. These catalysts show approximately 50% of selectivity against 7% of Cu/SiO2 (both values measured at 10% of conversion).Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2012-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/97033Gutierrez, Victoria Soledad; Dennehy, Mariana; Diez, Alejandra Silvina; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48; Elsevier Science; Applied Catalysis A: General; 437-438; 9-2012; 72-780926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.06.011info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X12003432info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:49:32Zoai:ri.conicet.gov.ar:11336/97033instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:49:33.174CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
title Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
spellingShingle Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
Gutierrez, Victoria Soledad
CO ADSORPTION
COPPER CATALYSTS
CROTONALDEHYDE
MCM-48
SELECTIVE HYDROGENATION
title_short Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
title_full Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
title_fullStr Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
title_full_unstemmed Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
title_sort Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48
dc.creator.none.fl_str_mv Gutierrez, Victoria Soledad
Dennehy, Mariana
Diez, Alejandra Silvina
Volpe, María Alicia
author Gutierrez, Victoria Soledad
author_facet Gutierrez, Victoria Soledad
Dennehy, Mariana
Diez, Alejandra Silvina
Volpe, María Alicia
author_role author
author2 Dennehy, Mariana
Diez, Alejandra Silvina
Volpe, María Alicia
author2_role author
author
author
dc.subject.none.fl_str_mv CO ADSORPTION
COPPER CATALYSTS
CROTONALDEHYDE
MCM-48
SELECTIVE HYDROGENATION
topic CO ADSORPTION
COPPER CATALYSTS
CROTONALDEHYDE
MCM-48
SELECTIVE HYDROGENATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A series of Cu/MCM-48 catalysts is studied for the liquid phase hydrogenation of crotonaldehyde. Copper is incorporated in MCM-48 following a classical hydrothermal synthesis or by wet impregnation of the MCM-48 precursor (before eliminating the directing agent) with Cu(AcAc)2. The copper loading is in the 2-20 wt% range. Characterization results from TPR and XRD indicate that copper crystals supported on MCM-48 surface coexist with copper incorporated in the MCM-48 walls. The presence of Cu+ in MCM-48 is concluded from characterization with FTIR of adsorbed CO. This species would be the responsible for the relatively high selectivity of Cu/MCM-48. These catalysts show approximately 50% of selectivity against 7% of Cu/SiO2 (both values measured at 10% of conversion).
Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description A series of Cu/MCM-48 catalysts is studied for the liquid phase hydrogenation of crotonaldehyde. Copper is incorporated in MCM-48 following a classical hydrothermal synthesis or by wet impregnation of the MCM-48 precursor (before eliminating the directing agent) with Cu(AcAc)2. The copper loading is in the 2-20 wt% range. Characterization results from TPR and XRD indicate that copper crystals supported on MCM-48 surface coexist with copper incorporated in the MCM-48 walls. The presence of Cu+ in MCM-48 is concluded from characterization with FTIR of adsorbed CO. This species would be the responsible for the relatively high selectivity of Cu/MCM-48. These catalysts show approximately 50% of selectivity against 7% of Cu/SiO2 (both values measured at 10% of conversion).
publishDate 2012
dc.date.none.fl_str_mv 2012-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/97033
Gutierrez, Victoria Soledad; Dennehy, Mariana; Diez, Alejandra Silvina; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48; Elsevier Science; Applied Catalysis A: General; 437-438; 9-2012; 72-78
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/97033
identifier_str_mv Gutierrez, Victoria Soledad; Dennehy, Mariana; Diez, Alejandra Silvina; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over copper incorporated in MCM-48; Elsevier Science; Applied Catalysis A: General; 437-438; 9-2012; 72-78
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.06.011
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X12003432
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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