Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde

Autores
Gutierrez, Victoria Soledad; Diez, Alejandra Silvina; Dennehy, Mariana; Volpe, María Alicia
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A series of copper/MCM-48 mesoporous samples is prepared and characterized following two methods: a traditional hydrothermal synthesis and an impregnation with Cu(AcAc)2 before eliminating the structure-directing agent. The samples are characterized by XRD, BET, FTIR, TPR and TEM. Only for certain cases the morphological aspects of MCM-48 are not modified by the incorporation of copper into the mesoporous framework. The samples are tested as catalysts for the liquid phase hydrogenation of cinnamaldehyde in a Batch reactor, employing H2 as the reductant. Some Cu/MCM-48 catalysts were more selective than copper supported on alumina (Cu/γ-Al2O3) tested under the same reaction conditions. The reason for the better catalytic performance would be that copper is finely dispersed and highly uncoordinated.
Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Α,Β-UNSATURATED COMPOUNDS
COPPER CATALYSTS
CU(ACAC)2
MCM-48
SELECTIVE HYDROGENATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/126233
Acceder
id CONICETDig_caa54b49ae7e353c7962711e677bf1dd
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehydeGutierrez, Victoria SoledadDiez, Alejandra SilvinaDennehy, MarianaVolpe, María AliciaΑ,Β-UNSATURATED COMPOUNDSCOPPER CATALYSTSCU(ACAC)2MCM-48SELECTIVE HYDROGENATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of copper/MCM-48 mesoporous samples is prepared and characterized following two methods: a traditional hydrothermal synthesis and an impregnation with Cu(AcAc)2 before eliminating the structure-directing agent. The samples are characterized by XRD, BET, FTIR, TPR and TEM. Only for certain cases the morphological aspects of MCM-48 are not modified by the incorporation of copper into the mesoporous framework. The samples are tested as catalysts for the liquid phase hydrogenation of cinnamaldehyde in a Batch reactor, employing H2 as the reductant. Some Cu/MCM-48 catalysts were more selective than copper supported on alumina (Cu/γ-Al2O3) tested under the same reaction conditions. The reason for the better catalytic performance would be that copper is finely dispersed and highly uncoordinated.Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2011-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/126233Gutierrez, Victoria Soledad; Diez, Alejandra Silvina; Dennehy, Mariana; Volpe, María Alicia; Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde; Elsevier Science; Microporous and Mesoporous Materials; 141; 1-3; 1-2011; 207-2131387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2010.11.009info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S1387181110003963?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:58:29Zoai:ri.conicet.gov.ar:11336/126233instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:58:30.153CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
title Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
spellingShingle Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
Gutierrez, Victoria Soledad
Α,Β-UNSATURATED COMPOUNDS
COPPER CATALYSTS
CU(ACAC)2
MCM-48
SELECTIVE HYDROGENATION
title_short Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
title_full Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
title_fullStr Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
title_full_unstemmed Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
title_sort Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde
dc.creator.none.fl_str_mv Gutierrez, Victoria Soledad
Diez, Alejandra Silvina
Dennehy, Mariana
Volpe, María Alicia
author Gutierrez, Victoria Soledad
author_facet Gutierrez, Victoria Soledad
Diez, Alejandra Silvina
Dennehy, Mariana
Volpe, María Alicia
author_role author
author2 Diez, Alejandra Silvina
Dennehy, Mariana
Volpe, María Alicia
author2_role author
author
author
dc.subject.none.fl_str_mv Α,Β-UNSATURATED COMPOUNDS
COPPER CATALYSTS
CU(ACAC)2
MCM-48
SELECTIVE HYDROGENATION
topic Α,Β-UNSATURATED COMPOUNDS
COPPER CATALYSTS
CU(ACAC)2
MCM-48
SELECTIVE HYDROGENATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A series of copper/MCM-48 mesoporous samples is prepared and characterized following two methods: a traditional hydrothermal synthesis and an impregnation with Cu(AcAc)2 before eliminating the structure-directing agent. The samples are characterized by XRD, BET, FTIR, TPR and TEM. Only for certain cases the morphological aspects of MCM-48 are not modified by the incorporation of copper into the mesoporous framework. The samples are tested as catalysts for the liquid phase hydrogenation of cinnamaldehyde in a Batch reactor, employing H2 as the reductant. Some Cu/MCM-48 catalysts were more selective than copper supported on alumina (Cu/γ-Al2O3) tested under the same reaction conditions. The reason for the better catalytic performance would be that copper is finely dispersed and highly uncoordinated.
Fil: Gutierrez, Victoria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Diez, Alejandra Silvina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description A series of copper/MCM-48 mesoporous samples is prepared and characterized following two methods: a traditional hydrothermal synthesis and an impregnation with Cu(AcAc)2 before eliminating the structure-directing agent. The samples are characterized by XRD, BET, FTIR, TPR and TEM. Only for certain cases the morphological aspects of MCM-48 are not modified by the incorporation of copper into the mesoporous framework. The samples are tested as catalysts for the liquid phase hydrogenation of cinnamaldehyde in a Batch reactor, employing H2 as the reductant. Some Cu/MCM-48 catalysts were more selective than copper supported on alumina (Cu/γ-Al2O3) tested under the same reaction conditions. The reason for the better catalytic performance would be that copper is finely dispersed and highly uncoordinated.
publishDate 2011
dc.date.none.fl_str_mv 2011-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/126233
Gutierrez, Victoria Soledad; Diez, Alejandra Silvina; Dennehy, Mariana; Volpe, María Alicia; Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde; Elsevier Science; Microporous and Mesoporous Materials; 141; 1-3; 1-2011; 207-213
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/126233
identifier_str_mv Gutierrez, Victoria Soledad; Diez, Alejandra Silvina; Dennehy, Mariana; Volpe, María Alicia; Cu incorporated MCM-48 for the liquid phase hydrogenation of cinnamaldehyde; Elsevier Science; Microporous and Mesoporous Materials; 141; 1-3; 1-2011; 207-213
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2010.11.009
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S1387181110003963?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269523529433088
score 13.13397

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