Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts

Autores
Campo, Betiana Carla; Santori, Gerardo Fabian; Petit, Corinne; Volpe, María Alicia
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Three Au/CeO2 catalysts, with different specific surface area (80, 150 and 240 m2/g) were tested for the hydrogenation of crotonaldehyde in liquid phase. Reactions were carried out with molecular hydrogen as the reductant, in a batch reactor using isopropanol as the solvent, at 80 8C and 1 MPa. The high surface area catalyst (Au/CeO2, 240 m2/g) showed a selectivity towards crotyl alcohol of 29%. This value was much lower than the one previously obtained for the same sample under gas phase conditions (73%) [B. Campo, C. Petit, M. Volpe, J. Catal. 242 (2006) 162]. Under liquid phase the promotional effect of high surface area ceria is lost. The low and middle surface area samples (80 and 150 m2/g respectively) showed meager selectivity to carbonyl hydrogenation due to both the low promotional effect of the support and the relatively large size of gold particles. For the three catalysts the formation of propanol was observed, which decreases catalysts selectivity to crotyl alcohol.
Fil: Campo, Betiana Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Santori, Gerardo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Petit, Corinne. Centre National de la Recherche Scientifique; Francia
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Crotonaldehyde
Gold Catalysts
Ceria
Selective Hydrogenation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/36733
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalystsCampo, Betiana CarlaSantori, Gerardo FabianPetit, CorinneVolpe, María AliciaCrotonaldehydeGold CatalystsCeriaSelective Hydrogenationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Three Au/CeO2 catalysts, with different specific surface area (80, 150 and 240 m2/g) were tested for the hydrogenation of crotonaldehyde in liquid phase. Reactions were carried out with molecular hydrogen as the reductant, in a batch reactor using isopropanol as the solvent, at 80 8C and 1 MPa. The high surface area catalyst (Au/CeO2, 240 m2/g) showed a selectivity towards crotyl alcohol of 29%. This value was much lower than the one previously obtained for the same sample under gas phase conditions (73%) [B. Campo, C. Petit, M. Volpe, J. Catal. 242 (2006) 162]. Under liquid phase the promotional effect of high surface area ceria is lost. The low and middle surface area samples (80 and 150 m2/g respectively) showed meager selectivity to carbonyl hydrogenation due to both the low promotional effect of the support and the relatively large size of gold particles. For the three catalysts the formation of propanol was observed, which decreases catalysts selectivity to crotyl alcohol.Fil: Campo, Betiana Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Santori, Gerardo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Petit, Corinne. Centre National de la Recherche Scientifique; FranciaFil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2009-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/36733Campo, Betiana Carla; Santori, Gerardo Fabian; Petit, Corinne; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts; Elsevier Science; Applied Catalysis A: General; 359; 1-2; 12-2009; 79-830926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2009.03.001info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X09001914info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:15Zoai:ri.conicet.gov.ar:11336/36733instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:15.356CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
title Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
spellingShingle Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
Campo, Betiana Carla
Crotonaldehyde
Gold Catalysts
Ceria
Selective Hydrogenation
title_short Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
title_full Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
title_fullStr Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
title_full_unstemmed Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
title_sort Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts
dc.creator.none.fl_str_mv Campo, Betiana Carla
Santori, Gerardo Fabian
Petit, Corinne
Volpe, María Alicia
author Campo, Betiana Carla
author_facet Campo, Betiana Carla
Santori, Gerardo Fabian
Petit, Corinne
Volpe, María Alicia
author_role author
author2 Santori, Gerardo Fabian
Petit, Corinne
Volpe, María Alicia
author2_role author
author
author
dc.subject.none.fl_str_mv Crotonaldehyde
Gold Catalysts
Ceria
Selective Hydrogenation
topic Crotonaldehyde
Gold Catalysts
Ceria
Selective Hydrogenation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Three Au/CeO2 catalysts, with different specific surface area (80, 150 and 240 m2/g) were tested for the hydrogenation of crotonaldehyde in liquid phase. Reactions were carried out with molecular hydrogen as the reductant, in a batch reactor using isopropanol as the solvent, at 80 8C and 1 MPa. The high surface area catalyst (Au/CeO2, 240 m2/g) showed a selectivity towards crotyl alcohol of 29%. This value was much lower than the one previously obtained for the same sample under gas phase conditions (73%) [B. Campo, C. Petit, M. Volpe, J. Catal. 242 (2006) 162]. Under liquid phase the promotional effect of high surface area ceria is lost. The low and middle surface area samples (80 and 150 m2/g respectively) showed meager selectivity to carbonyl hydrogenation due to both the low promotional effect of the support and the relatively large size of gold particles. For the three catalysts the formation of propanol was observed, which decreases catalysts selectivity to crotyl alcohol.
Fil: Campo, Betiana Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Santori, Gerardo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Petit, Corinne. Centre National de la Recherche Scientifique; Francia
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Three Au/CeO2 catalysts, with different specific surface area (80, 150 and 240 m2/g) were tested for the hydrogenation of crotonaldehyde in liquid phase. Reactions were carried out with molecular hydrogen as the reductant, in a batch reactor using isopropanol as the solvent, at 80 8C and 1 MPa. The high surface area catalyst (Au/CeO2, 240 m2/g) showed a selectivity towards crotyl alcohol of 29%. This value was much lower than the one previously obtained for the same sample under gas phase conditions (73%) [B. Campo, C. Petit, M. Volpe, J. Catal. 242 (2006) 162]. Under liquid phase the promotional effect of high surface area ceria is lost. The low and middle surface area samples (80 and 150 m2/g respectively) showed meager selectivity to carbonyl hydrogenation due to both the low promotional effect of the support and the relatively large size of gold particles. For the three catalysts the formation of propanol was observed, which decreases catalysts selectivity to crotyl alcohol.
publishDate 2009
dc.date.none.fl_str_mv 2009-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/36733
Campo, Betiana Carla; Santori, Gerardo Fabian; Petit, Corinne; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts; Elsevier Science; Applied Catalysis A: General; 359; 1-2; 12-2009; 79-83
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/36733
identifier_str_mv Campo, Betiana Carla; Santori, Gerardo Fabian; Petit, Corinne; Volpe, María Alicia; Liquid phase hydrogenation of crotonaldehyde over Au/CeO2 catalysts; Elsevier Science; Applied Catalysis A: General; 359; 1-2; 12-2009; 79-83
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2009.03.001
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X09001914
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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