Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy

Autores
Argüello, Dalma Sofía; Balsamo, Nancy Florentina; Eimer, Griselda Alejandra; Crivello, Mónica Elsie
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The glycerol generated as a by-product in the production of biodiesel could be used as a renewable rawmaterial to economically promote the production process. The catalytic conversion of glycerol to a product with higher added value, such as glycerol carbonate, has attracted great interest in the chemical, pharmaceutical, and lithium battery industries, among others, due to its low toxicity, hydration capacity, and biodegradability. Layered-double hydroxide (LDH) materials, the precursors of the catalysts, were synthesized by a direct coprecipitation method to incorporate a third metal ion in addition to magnesium and aluminum ions. This method is the easiest regularly applied technique to design these low cost anionic nanoclay. The atomic percentage of Cu, Zn, or Ni incorporated was 15% of the Mg load in the material. The synthesis atomic ratio, (M2++Mg2+)/Al3+ had a constant value of 3, where M represents the transition metal incorporated. LDHs produced the corresponding mixed metal oxides by thermal decomposition. These materials have excellent properties for reactions catalyzed by the basic sites, high surface area, homogeneous cation dispersion, and thermal stability. The physicochemical material properties were characterized byXRD, N2 sorption, MP-AES, TPD-CO2, SEM, and XPS. The mixed oxides were evaluated in the catalytic conversion of glycerol to glycerol carbonate. The addition of Cu, Ni, or Zn to the matrix of Mg and Al produced changes in its physicochemical properties and mostly in the catalytic activity. X-ray diffractograms of LDHs showed the typical characteristic structure of layers even with metallic ions of Cu, Ni, or Zn incorporated, because their ionic radii are similar to that of the Mg ion, 0.69, 0.73, and 0.74 Å, respectively. The obtained mixed oxides showed a high catalytic activity towards the conversion of glycerol to glycerol carbonate under mild reaction conditions, a 1:2 ratio of glycerol:ethylene carbonate and solvent free. Relative yields higher than 80% were obtained, attributable to an adequate distribution of basicity and textural parameters. The catalysts wereused in successive reaction cycles without significant loss of activity.
Fil: Argüello, Dalma Sofía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Balsamo, Nancy Florentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
LAYERED DOUBLE HYDROXIDES
MIXED OXIDES
HETEROGENEOUS CATALYSIS
GLYCEROL
GLYCEROL CARBONATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/203398
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/203398
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economyArgüello, Dalma SofíaBalsamo, Nancy FlorentinaEimer, Griselda AlejandraCrivello, Mónica ElsieLAYERED DOUBLE HYDROXIDESMIXED OXIDESHETEROGENEOUS CATALYSISGLYCEROLGLYCEROL CARBONATEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The glycerol generated as a by-product in the production of biodiesel could be used as a renewable rawmaterial to economically promote the production process. The catalytic conversion of glycerol to a product with higher added value, such as glycerol carbonate, has attracted great interest in the chemical, pharmaceutical, and lithium battery industries, among others, due to its low toxicity, hydration capacity, and biodegradability. Layered-double hydroxide (LDH) materials, the precursors of the catalysts, were synthesized by a direct coprecipitation method to incorporate a third metal ion in addition to magnesium and aluminum ions. This method is the easiest regularly applied technique to design these low cost anionic nanoclay. The atomic percentage of Cu, Zn, or Ni incorporated was 15% of the Mg load in the material. The synthesis atomic ratio, (M2++Mg2+)/Al3+ had a constant value of 3, where M represents the transition metal incorporated. LDHs produced the corresponding mixed metal oxides by thermal decomposition. These materials have excellent properties for reactions catalyzed by the basic sites, high surface area, homogeneous cation dispersion, and thermal stability. The physicochemical material properties were characterized byXRD, N2 sorption, MP-AES, TPD-CO2, SEM, and XPS. The mixed oxides were evaluated in the catalytic conversion of glycerol to glycerol carbonate. The addition of Cu, Ni, or Zn to the matrix of Mg and Al produced changes in its physicochemical properties and mostly in the catalytic activity. X-ray diffractograms of LDHs showed the typical characteristic structure of layers even with metallic ions of Cu, Ni, or Zn incorporated, because their ionic radii are similar to that of the Mg ion, 0.69, 0.73, and 0.74 Å, respectively. The obtained mixed oxides showed a high catalytic activity towards the conversion of glycerol to glycerol carbonate under mild reaction conditions, a 1:2 ratio of glycerol:ethylene carbonate and solvent free. Relative yields higher than 80% were obtained, attributable to an adequate distribution of basicity and textural parameters. The catalysts wereused in successive reaction cycles without significant loss of activity.Fil: Argüello, Dalma Sofía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Balsamo, Nancy Florentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFrontiers Media2022-10-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/203398Argüello, Dalma Sofía; Balsamo, Nancy Florentina; Eimer, Griselda Alejandra; Crivello, Mónica Elsie; Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy; Frontiers Media; Frontiers in Chemical Engineering; 4; 1027152; 14-10-2022; 1-102673-2718CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.frontiersin.org/articles/10.3389/fceng.2022.1027152/fullinfo:eu-repo/semantics/altIdentifier/doi/ 10.3389/fceng.2022.1027152info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:35:26Zoai:ri.conicet.gov.ar:11336/203398instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:35:26.938CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
title Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
spellingShingle Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
Argüello, Dalma Sofía
LAYERED DOUBLE HYDROXIDES
MIXED OXIDES
HETEROGENEOUS CATALYSIS
GLYCEROL
GLYCEROL CARBONATE
title_short Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
title_full Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
title_fullStr Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
title_full_unstemmed Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
title_sort Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy
dc.creator.none.fl_str_mv Argüello, Dalma Sofía
Balsamo, Nancy Florentina
Eimer, Griselda Alejandra
Crivello, Mónica Elsie
author Argüello, Dalma Sofía
author_facet Argüello, Dalma Sofía
Balsamo, Nancy Florentina
Eimer, Griselda Alejandra
Crivello, Mónica Elsie
author_role author
author2 Balsamo, Nancy Florentina
Eimer, Griselda Alejandra
Crivello, Mónica Elsie
author2_role author
author
author
dc.subject.none.fl_str_mv LAYERED DOUBLE HYDROXIDES
MIXED OXIDES
HETEROGENEOUS CATALYSIS
GLYCEROL
GLYCEROL CARBONATE
topic LAYERED DOUBLE HYDROXIDES
MIXED OXIDES
HETEROGENEOUS CATALYSIS
GLYCEROL
GLYCEROL CARBONATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The glycerol generated as a by-product in the production of biodiesel could be used as a renewable rawmaterial to economically promote the production process. The catalytic conversion of glycerol to a product with higher added value, such as glycerol carbonate, has attracted great interest in the chemical, pharmaceutical, and lithium battery industries, among others, due to its low toxicity, hydration capacity, and biodegradability. Layered-double hydroxide (LDH) materials, the precursors of the catalysts, were synthesized by a direct coprecipitation method to incorporate a third metal ion in addition to magnesium and aluminum ions. This method is the easiest regularly applied technique to design these low cost anionic nanoclay. The atomic percentage of Cu, Zn, or Ni incorporated was 15% of the Mg load in the material. The synthesis atomic ratio, (M2++Mg2+)/Al3+ had a constant value of 3, where M represents the transition metal incorporated. LDHs produced the corresponding mixed metal oxides by thermal decomposition. These materials have excellent properties for reactions catalyzed by the basic sites, high surface area, homogeneous cation dispersion, and thermal stability. The physicochemical material properties were characterized byXRD, N2 sorption, MP-AES, TPD-CO2, SEM, and XPS. The mixed oxides were evaluated in the catalytic conversion of glycerol to glycerol carbonate. The addition of Cu, Ni, or Zn to the matrix of Mg and Al produced changes in its physicochemical properties and mostly in the catalytic activity. X-ray diffractograms of LDHs showed the typical characteristic structure of layers even with metallic ions of Cu, Ni, or Zn incorporated, because their ionic radii are similar to that of the Mg ion, 0.69, 0.73, and 0.74 Å, respectively. The obtained mixed oxides showed a high catalytic activity towards the conversion of glycerol to glycerol carbonate under mild reaction conditions, a 1:2 ratio of glycerol:ethylene carbonate and solvent free. Relative yields higher than 80% were obtained, attributable to an adequate distribution of basicity and textural parameters. The catalysts wereused in successive reaction cycles without significant loss of activity.
Fil: Argüello, Dalma Sofía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Balsamo, Nancy Florentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Crivello, Mónica Elsie. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description The glycerol generated as a by-product in the production of biodiesel could be used as a renewable rawmaterial to economically promote the production process. The catalytic conversion of glycerol to a product with higher added value, such as glycerol carbonate, has attracted great interest in the chemical, pharmaceutical, and lithium battery industries, among others, due to its low toxicity, hydration capacity, and biodegradability. Layered-double hydroxide (LDH) materials, the precursors of the catalysts, were synthesized by a direct coprecipitation method to incorporate a third metal ion in addition to magnesium and aluminum ions. This method is the easiest regularly applied technique to design these low cost anionic nanoclay. The atomic percentage of Cu, Zn, or Ni incorporated was 15% of the Mg load in the material. The synthesis atomic ratio, (M2++Mg2+)/Al3+ had a constant value of 3, where M represents the transition metal incorporated. LDHs produced the corresponding mixed metal oxides by thermal decomposition. These materials have excellent properties for reactions catalyzed by the basic sites, high surface area, homogeneous cation dispersion, and thermal stability. The physicochemical material properties were characterized byXRD, N2 sorption, MP-AES, TPD-CO2, SEM, and XPS. The mixed oxides were evaluated in the catalytic conversion of glycerol to glycerol carbonate. The addition of Cu, Ni, or Zn to the matrix of Mg and Al produced changes in its physicochemical properties and mostly in the catalytic activity. X-ray diffractograms of LDHs showed the typical characteristic structure of layers even with metallic ions of Cu, Ni, or Zn incorporated, because their ionic radii are similar to that of the Mg ion, 0.69, 0.73, and 0.74 Å, respectively. The obtained mixed oxides showed a high catalytic activity towards the conversion of glycerol to glycerol carbonate under mild reaction conditions, a 1:2 ratio of glycerol:ethylene carbonate and solvent free. Relative yields higher than 80% were obtained, attributable to an adequate distribution of basicity and textural parameters. The catalysts wereused in successive reaction cycles without significant loss of activity.
publishDate 2022
dc.date.none.fl_str_mv 2022-10-14
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/203398
Argüello, Dalma Sofía; Balsamo, Nancy Florentina; Eimer, Griselda Alejandra; Crivello, Mónica Elsie; Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy; Frontiers Media; Frontiers in Chemical Engineering; 4; 1027152; 14-10-2022; 1-10
2673-2718
CONICET Digital
CONICET
url http://hdl.handle.net/11336/203398
identifier_str_mv Argüello, Dalma Sofía; Balsamo, Nancy Florentina; Eimer, Griselda Alejandra; Crivello, Mónica Elsie; Mixed oxides from calcined layered double hydroxides for glycerol carbonate production to contribute to the biodiesel economy; Frontiers Media; Frontiers in Chemical Engineering; 4; 1027152; 14-10-2022; 1-10
2673-2718
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.frontiersin.org/articles/10.3389/fceng.2022.1027152/full
info:eu-repo/semantics/altIdentifier/doi/ 10.3389/fceng.2022.1027152
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
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dc.publisher.none.fl_str_mv Frontiers Media
publisher.none.fl_str_mv Frontiers Media
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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