A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones

Autores
Frenzel, Romina Alejandra; Palermo, Valeria; Sathicq, Angel Gabriel; Elsharif, Asma M.; Luque, Rafael; Pizzio, Luis Rene; Romanelli, Gustavo Pablo
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two vanadium-containing Keggin silicopolyoxotungsto compounds K5SiVW11O40 and K6SiV2W10O40 were synthesized and characterized. They were incorporated in a superporous hydrogel constitute by prop-2-enamide and propenoic acid as initial monomers and bis-acrylamide as cross-linking moiety. Materials were characterized by several techniques. According to FTIR and 51V MAS-NMR, the (SiVxW12-xO40)(4+x)- anions are the main species present in the hybrid materials. Additionally, they do not decompose during the preparation of the composite. XRD and SEM-EDX results suggest that (SiVxW12-xO40)(4+x)- anions were well dispersed in the support or present as amorphous phases. These materials were evaluated as catalysts in the oxidation of sulfides to sulfones, using an eco-friendly oxidant and mild reaction conditions. The hybrid materials with higher content of the heteropoly compound displayed a remarkable catalytic behaviour in the oxidation of diphenyl sulfide. Materials also exhibited a stable catalytic performance through consecutive reuses. Optimum reaction parameters established were subsequently translated to the oxidation of a sulfide of interest (dapsone) due to its pharmacological activities.
Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Elsharif, Asma M.. Imam Abdulrahman Bin Faisal University; Arabia Saudita
Fil: Luque, Rafael. Universidad de Córdoba; España
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
DAPSONE
KEGGIN SILICOPOLYOXOTUNGSTO COMPOUNDS
SULFIDE OXIDATION
SUPERABSORBENT HYDROGEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/164875
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/164875
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfonesFrenzel, Romina AlejandraPalermo, ValeriaSathicq, Angel GabrielElsharif, Asma M.Luque, RafaelPizzio, Luis ReneRomanelli, Gustavo PabloDAPSONEKEGGIN SILICOPOLYOXOTUNGSTO COMPOUNDSSULFIDE OXIDATIONSUPERABSORBENT HYDROGELhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two vanadium-containing Keggin silicopolyoxotungsto compounds K5SiVW11O40 and K6SiV2W10O40 were synthesized and characterized. They were incorporated in a superporous hydrogel constitute by prop-2-enamide and propenoic acid as initial monomers and bis-acrylamide as cross-linking moiety. Materials were characterized by several techniques. According to FTIR and 51V MAS-NMR, the (SiVxW12-xO40)(4+x)- anions are the main species present in the hybrid materials. Additionally, they do not decompose during the preparation of the composite. XRD and SEM-EDX results suggest that (SiVxW12-xO40)(4+x)- anions were well dispersed in the support or present as amorphous phases. These materials were evaluated as catalysts in the oxidation of sulfides to sulfones, using an eco-friendly oxidant and mild reaction conditions. The hybrid materials with higher content of the heteropoly compound displayed a remarkable catalytic behaviour in the oxidation of diphenyl sulfide. Materials also exhibited a stable catalytic performance through consecutive reuses. Optimum reaction parameters established were subsequently translated to the oxidation of a sulfide of interest (dapsone) due to its pharmacological activities.Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Elsharif, Asma M.. Imam Abdulrahman Bin Faisal University; Arabia SauditaFil: Luque, Rafael. Universidad de Córdoba; EspañaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2021-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/164875Frenzel, Romina Alejandra; Palermo, Valeria; Sathicq, Angel Gabriel; Elsharif, Asma M.; Luque, Rafael; et al.; A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones; Elsevier Science; Microporous and Mesoporous Materials; 310; 1-2021; 1-121387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2020.110584info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:41:12Zoai:ri.conicet.gov.ar:11336/164875instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:41:13.347CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
title A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
spellingShingle A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
Frenzel, Romina Alejandra
DAPSONE
KEGGIN SILICOPOLYOXOTUNGSTO COMPOUNDS
SULFIDE OXIDATION
SUPERABSORBENT HYDROGEL
title_short A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
title_full A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
title_fullStr A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
title_full_unstemmed A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
title_sort A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones
dc.creator.none.fl_str_mv Frenzel, Romina Alejandra
Palermo, Valeria
Sathicq, Angel Gabriel
Elsharif, Asma M.
Luque, Rafael
Pizzio, Luis Rene
Romanelli, Gustavo Pablo
author Frenzel, Romina Alejandra
author_facet Frenzel, Romina Alejandra
Palermo, Valeria
Sathicq, Angel Gabriel
Elsharif, Asma M.
Luque, Rafael
Pizzio, Luis Rene
Romanelli, Gustavo Pablo
author_role author
author2 Palermo, Valeria
Sathicq, Angel Gabriel
Elsharif, Asma M.
Luque, Rafael
Pizzio, Luis Rene
Romanelli, Gustavo Pablo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv DAPSONE
KEGGIN SILICOPOLYOXOTUNGSTO COMPOUNDS
SULFIDE OXIDATION
SUPERABSORBENT HYDROGEL
topic DAPSONE
KEGGIN SILICOPOLYOXOTUNGSTO COMPOUNDS
SULFIDE OXIDATION
SUPERABSORBENT HYDROGEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two vanadium-containing Keggin silicopolyoxotungsto compounds K5SiVW11O40 and K6SiV2W10O40 were synthesized and characterized. They were incorporated in a superporous hydrogel constitute by prop-2-enamide and propenoic acid as initial monomers and bis-acrylamide as cross-linking moiety. Materials were characterized by several techniques. According to FTIR and 51V MAS-NMR, the (SiVxW12-xO40)(4+x)- anions are the main species present in the hybrid materials. Additionally, they do not decompose during the preparation of the composite. XRD and SEM-EDX results suggest that (SiVxW12-xO40)(4+x)- anions were well dispersed in the support or present as amorphous phases. These materials were evaluated as catalysts in the oxidation of sulfides to sulfones, using an eco-friendly oxidant and mild reaction conditions. The hybrid materials with higher content of the heteropoly compound displayed a remarkable catalytic behaviour in the oxidation of diphenyl sulfide. Materials also exhibited a stable catalytic performance through consecutive reuses. Optimum reaction parameters established were subsequently translated to the oxidation of a sulfide of interest (dapsone) due to its pharmacological activities.
Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Elsharif, Asma M.. Imam Abdulrahman Bin Faisal University; Arabia Saudita
Fil: Luque, Rafael. Universidad de Córdoba; España
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Two vanadium-containing Keggin silicopolyoxotungsto compounds K5SiVW11O40 and K6SiV2W10O40 were synthesized and characterized. They were incorporated in a superporous hydrogel constitute by prop-2-enamide and propenoic acid as initial monomers and bis-acrylamide as cross-linking moiety. Materials were characterized by several techniques. According to FTIR and 51V MAS-NMR, the (SiVxW12-xO40)(4+x)- anions are the main species present in the hybrid materials. Additionally, they do not decompose during the preparation of the composite. XRD and SEM-EDX results suggest that (SiVxW12-xO40)(4+x)- anions were well dispersed in the support or present as amorphous phases. These materials were evaluated as catalysts in the oxidation of sulfides to sulfones, using an eco-friendly oxidant and mild reaction conditions. The hybrid materials with higher content of the heteropoly compound displayed a remarkable catalytic behaviour in the oxidation of diphenyl sulfide. Materials also exhibited a stable catalytic performance through consecutive reuses. Optimum reaction parameters established were subsequently translated to the oxidation of a sulfide of interest (dapsone) due to its pharmacological activities.
publishDate 2021
dc.date.none.fl_str_mv 2021-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/164875
Frenzel, Romina Alejandra; Palermo, Valeria; Sathicq, Angel Gabriel; Elsharif, Asma M.; Luque, Rafael; et al.; A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones; Elsevier Science; Microporous and Mesoporous Materials; 310; 1-2021; 1-12
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/164875
identifier_str_mv Frenzel, Romina Alejandra; Palermo, Valeria; Sathicq, Angel Gabriel; Elsharif, Asma M.; Luque, Rafael; et al.; A green and reusable catalytic system based on silicopolyoxotungstovanadates incorporated in a polymeric material for the selective oxidation of sulfides to sulfones; Elsevier Science; Microporous and Mesoporous Materials; 310; 1-2021; 1-12
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2020.110584
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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