Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones

Autores
Frenzel, Romina Alejandra; Pizzio, Luis Rene; Blanco, Mirta Noemi; Sathicq, Angel Gabriel; Romanelli, Gustavo Pablo
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
H3PW12O40 in bulk form presents suitable properties to be used as catalyst in the selective oxidation of sulfides with 35% aqueous hydrogen peroxide, and sulfoxides or sulfones were obtained as products in high to excellent yields and selectivity. We found that sulfides were oxidized to the corresponding sulfoxides, with near stoichiometric 35% w/V aqueous hydrogen peroxide, at room temperature (20ºC) and with a catalytic amount of bulk H3PW12O40. Similarly, sulfides were transformed to the corresponding sulfones using excess of 35% w/V aqueous hydrogen peroxide and a temperature of 70ºC. In both cases acetonitrile was used as reaction solvent.
Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Materia
Aqueous Hydrogen Peroxide
Keggin Heteroplyacid
Sulfide Oxidation
Sulfoxides
Sulfones
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/9741
Acceder
id CONICETDig_482ded7a32874069ec13eaa93618176d
oai_identifier_str oai:ri.conicet.gov.ar:11336/9741
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfonesFrenzel, Romina AlejandraPizzio, Luis ReneBlanco, Mirta NoemiSathicq, Angel GabrielRomanelli, Gustavo PabloAqueous Hydrogen PeroxideKeggin HeteroplyacidSulfide OxidationSulfoxidesSulfoneshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1H3PW12O40 in bulk form presents suitable properties to be used as catalyst in the selective oxidation of sulfides with 35% aqueous hydrogen peroxide, and sulfoxides or sulfones were obtained as products in high to excellent yields and selectivity. We found that sulfides were oxidized to the corresponding sulfoxides, with near stoichiometric 35% w/V aqueous hydrogen peroxide, at room temperature (20ºC) and with a catalytic amount of bulk H3PW12O40. Similarly, sulfides were transformed to the corresponding sulfones using excess of 35% w/V aqueous hydrogen peroxide and a temperature of 70ºC. In both cases acetonitrile was used as reaction solvent.Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaBentham Science Publishers2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9741Frenzel, Romina Alejandra; Pizzio, Luis Rene; Blanco, Mirta Noemi; Sathicq, Angel Gabriel; Romanelli, Gustavo Pablo; Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones; Bentham Science Publishers; Current Catalyst; 3; 2; 12-2013; 124-1302211-54472211-5455enginfo:eu-repo/semantics/altIdentifier/doi/10.2174/2211544702666131224003356info:eu-repo/semantics/altIdentifier/url/https://benthamscience.com/journals/current-catalysis/volume/3/issue/2/page/124/info:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/119137/articleinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:43Zoai:ri.conicet.gov.ar:11336/9741instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:43.551CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
title Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
spellingShingle Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
Frenzel, Romina Alejandra
Aqueous Hydrogen Peroxide
Keggin Heteroplyacid
Sulfide Oxidation
Sulfoxides
Sulfones
title_short Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
title_full Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
title_fullStr Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
title_full_unstemmed Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
title_sort Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones
dc.creator.none.fl_str_mv Frenzel, Romina Alejandra
Pizzio, Luis Rene
Blanco, Mirta Noemi
Sathicq, Angel Gabriel
Romanelli, Gustavo Pablo
author Frenzel, Romina Alejandra
author_facet Frenzel, Romina Alejandra
Pizzio, Luis Rene
Blanco, Mirta Noemi
Sathicq, Angel Gabriel
Romanelli, Gustavo Pablo
author_role author
author2 Pizzio, Luis Rene
Blanco, Mirta Noemi
Sathicq, Angel Gabriel
Romanelli, Gustavo Pablo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Aqueous Hydrogen Peroxide
Keggin Heteroplyacid
Sulfide Oxidation
Sulfoxides
Sulfones
topic Aqueous Hydrogen Peroxide
Keggin Heteroplyacid
Sulfide Oxidation
Sulfoxides
Sulfones
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv H3PW12O40 in bulk form presents suitable properties to be used as catalyst in the selective oxidation of sulfides with 35% aqueous hydrogen peroxide, and sulfoxides or sulfones were obtained as products in high to excellent yields and selectivity. We found that sulfides were oxidized to the corresponding sulfoxides, with near stoichiometric 35% w/V aqueous hydrogen peroxide, at room temperature (20ºC) and with a catalytic amount of bulk H3PW12O40. Similarly, sulfides were transformed to the corresponding sulfones using excess of 35% w/V aqueous hydrogen peroxide and a temperature of 70ºC. In both cases acetonitrile was used as reaction solvent.
Fil: Frenzel, Romina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Sathicq, Angel Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
description H3PW12O40 in bulk form presents suitable properties to be used as catalyst in the selective oxidation of sulfides with 35% aqueous hydrogen peroxide, and sulfoxides or sulfones were obtained as products in high to excellent yields and selectivity. We found that sulfides were oxidized to the corresponding sulfoxides, with near stoichiometric 35% w/V aqueous hydrogen peroxide, at room temperature (20ºC) and with a catalytic amount of bulk H3PW12O40. Similarly, sulfides were transformed to the corresponding sulfones using excess of 35% w/V aqueous hydrogen peroxide and a temperature of 70ºC. In both cases acetonitrile was used as reaction solvent.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/9741
Frenzel, Romina Alejandra; Pizzio, Luis Rene; Blanco, Mirta Noemi; Sathicq, Angel Gabriel; Romanelli, Gustavo Pablo; Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones; Bentham Science Publishers; Current Catalyst; 3; 2; 12-2013; 124-130
2211-5447
2211-5455
url http://hdl.handle.net/11336/9741
identifier_str_mv Frenzel, Romina Alejandra; Pizzio, Luis Rene; Blanco, Mirta Noemi; Sathicq, Angel Gabriel; Romanelli, Gustavo Pablo; Evaluation of the catalytic activity of H3PW12O40 in the selective oxidation of sulfides to the corresponding sulfoxides or sulfones; Bentham Science Publishers; Current Catalyst; 3; 2; 12-2013; 124-130
2211-5447
2211-5455
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.2174/2211544702666131224003356
info:eu-repo/semantics/altIdentifier/url/https://benthamscience.com/journals/current-catalysis/volume/3/issue/2/page/124/
info:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/119137/article
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science Publishers
publisher.none.fl_str_mv Bentham Science Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613940790689792
score 13.069144

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