Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide

Autores
Romanelli, Gustavo Pablo; Villabrille, Paula Isabel; Caceres, Carmen Victoria; Vazquez, Patricia Graciela; Tundo, Pietro
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
H4PMo11VO40, H5PMo 10V2O40 and H9PMo6V 6O40 acids and an acidic pyridinium salt of H 4PMo11VO40 were synthesized. They were characterized by FT-IR and the variations of their acid properties were determined by titration with n-butylamine. They proved to be highly active and selective catalysts for the hydrogen peroxide oxidation of methyl phenyl sulfide to the corresponding sulfoxide or sulfone. The conversion and selectivity results may be explained in terms of the co-existence of acidic and oxidative properties in the catalysts. On the other hand, a convenient catalytic homogeneous procedure has been found to oxidize different sulfides to sulfoxides or sulfones, with 35% aqueous H2O2, using (PyH)H 3PMo11VO40 as catalyst. The oxidation reaction is carried out at room temperature for sulfoxides or 40 °C for sulfones and requires a short time. The sulfoxides or sulfones were obtained with excellent yields by controlling the amount of H2O2.
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Villabrille, Paula Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Caceres, Carmen Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Tundo, Pietro. Consorzio Interuniversitario Nazionale La Chimica per l'Ambiente; Italia. Universita' Ca' Foscari Di Venezia; Italia
Materia
Hydrogen Peroxide
Keggin-Type Molybdovanadophosphate
Keggin-Type Molybdovanadophosphoric Acids
Pyridinium Salt
Sulfide Oxidation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77007
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/77007
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxideRomanelli, Gustavo PabloVillabrille, Paula IsabelCaceres, Carmen VictoriaVazquez, Patricia GracielaTundo, PietroHydrogen PeroxideKeggin-Type MolybdovanadophosphateKeggin-Type Molybdovanadophosphoric AcidsPyridinium SaltSulfide Oxidationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2H4PMo11VO40, H5PMo 10V2O40 and H9PMo6V 6O40 acids and an acidic pyridinium salt of H 4PMo11VO40 were synthesized. They were characterized by FT-IR and the variations of their acid properties were determined by titration with n-butylamine. They proved to be highly active and selective catalysts for the hydrogen peroxide oxidation of methyl phenyl sulfide to the corresponding sulfoxide or sulfone. The conversion and selectivity results may be explained in terms of the co-existence of acidic and oxidative properties in the catalysts. On the other hand, a convenient catalytic homogeneous procedure has been found to oxidize different sulfides to sulfoxides or sulfones, with 35% aqueous H2O2, using (PyH)H 3PMo11VO40 as catalyst. The oxidation reaction is carried out at room temperature for sulfoxides or 40 °C for sulfones and requires a short time. The sulfoxides or sulfones were obtained with excellent yields by controlling the amount of H2O2.Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Villabrille, Paula Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Caceres, Carmen Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Tundo, Pietro. Consorzio Interuniversitario Nazionale La Chimica per l'Ambiente; Italia. Universita' Ca' Foscari Di Venezia; ItaliaElsevier Science2011-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77007Romanelli, Gustavo Pablo; Villabrille, Paula Isabel; Caceres, Carmen Victoria; Vazquez, Patricia Graciela; Tundo, Pietro; Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide; Elsevier Science; Catalysis Communications; 12; 8; 3-2011; 726-7301566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.12.023info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710004085info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:45Zoai:ri.conicet.gov.ar:11336/77007instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:45.841CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
title Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
spellingShingle Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
Romanelli, Gustavo Pablo
Hydrogen Peroxide
Keggin-Type Molybdovanadophosphate
Keggin-Type Molybdovanadophosphoric Acids
Pyridinium Salt
Sulfide Oxidation
title_short Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
title_full Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
title_fullStr Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
title_full_unstemmed Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
title_sort Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide
dc.creator.none.fl_str_mv Romanelli, Gustavo Pablo
Villabrille, Paula Isabel
Caceres, Carmen Victoria
Vazquez, Patricia Graciela
Tundo, Pietro
author Romanelli, Gustavo Pablo
author_facet Romanelli, Gustavo Pablo
Villabrille, Paula Isabel
Caceres, Carmen Victoria
Vazquez, Patricia Graciela
Tundo, Pietro
author_role author
author2 Villabrille, Paula Isabel
Caceres, Carmen Victoria
Vazquez, Patricia Graciela
Tundo, Pietro
author2_role author
author
author
author
dc.subject.none.fl_str_mv Hydrogen Peroxide
Keggin-Type Molybdovanadophosphate
Keggin-Type Molybdovanadophosphoric Acids
Pyridinium Salt
Sulfide Oxidation
topic Hydrogen Peroxide
Keggin-Type Molybdovanadophosphate
Keggin-Type Molybdovanadophosphoric Acids
Pyridinium Salt
Sulfide Oxidation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv H4PMo11VO40, H5PMo 10V2O40 and H9PMo6V 6O40 acids and an acidic pyridinium salt of H 4PMo11VO40 were synthesized. They were characterized by FT-IR and the variations of their acid properties were determined by titration with n-butylamine. They proved to be highly active and selective catalysts for the hydrogen peroxide oxidation of methyl phenyl sulfide to the corresponding sulfoxide or sulfone. The conversion and selectivity results may be explained in terms of the co-existence of acidic and oxidative properties in the catalysts. On the other hand, a convenient catalytic homogeneous procedure has been found to oxidize different sulfides to sulfoxides or sulfones, with 35% aqueous H2O2, using (PyH)H 3PMo11VO40 as catalyst. The oxidation reaction is carried out at room temperature for sulfoxides or 40 °C for sulfones and requires a short time. The sulfoxides or sulfones were obtained with excellent yields by controlling the amount of H2O2.
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Villabrille, Paula Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Caceres, Carmen Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Tundo, Pietro. Consorzio Interuniversitario Nazionale La Chimica per l'Ambiente; Italia. Universita' Ca' Foscari Di Venezia; Italia
description H4PMo11VO40, H5PMo 10V2O40 and H9PMo6V 6O40 acids and an acidic pyridinium salt of H 4PMo11VO40 were synthesized. They were characterized by FT-IR and the variations of their acid properties were determined by titration with n-butylamine. They proved to be highly active and selective catalysts for the hydrogen peroxide oxidation of methyl phenyl sulfide to the corresponding sulfoxide or sulfone. The conversion and selectivity results may be explained in terms of the co-existence of acidic and oxidative properties in the catalysts. On the other hand, a convenient catalytic homogeneous procedure has been found to oxidize different sulfides to sulfoxides or sulfones, with 35% aqueous H2O2, using (PyH)H 3PMo11VO40 as catalyst. The oxidation reaction is carried out at room temperature for sulfoxides or 40 °C for sulfones and requires a short time. The sulfoxides or sulfones were obtained with excellent yields by controlling the amount of H2O2.
publishDate 2011
dc.date.none.fl_str_mv 2011-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77007
Romanelli, Gustavo Pablo; Villabrille, Paula Isabel; Caceres, Carmen Victoria; Vazquez, Patricia Graciela; Tundo, Pietro; Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide; Elsevier Science; Catalysis Communications; 12; 8; 3-2011; 726-730
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77007
identifier_str_mv Romanelli, Gustavo Pablo; Villabrille, Paula Isabel; Caceres, Carmen Victoria; Vazquez, Patricia Graciela; Tundo, Pietro; Keggin heteropolycompounds as catalysts for liquid-phase oxidation of sulfides to sulfoxides/sulfones by hydrogen peroxide; Elsevier Science; Catalysis Communications; 12; 8; 3-2011; 726-730
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.12.023
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710004085
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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