Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality
- Autores
- Díaz, Darío Ramón; Carmona, Francisco Javier; Palacio, Laura; Ochoa, Nelio Ariel; Hernández, Antonio; Pradanos del Pico, Pedro
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, the proper charge density of a microfiltration membrane has been determined by using two different methods. Firstly, the ionic transport of a KCl solution has been investigated by simultaneous measurements of saline flux and membrane potential (MP) resulting from a concentration gradient through the membrane. A simple model, including all the relevant contributions to the global electrical potential drop, allowed a calculation of transport numbers and membrane charge density. The response of ions inside the membrane to an oscillating electrical potential has been analyzed by impedance spectroscopy (or electrical impedance spectroscopy EIS). A quite simple experimental EIS design allowed, by taking into account MP measurements too, an easy assignation of an equivalent circuit. After a careful analysis of EIS results, it was possible to evaluate the electrical conductivity inside the pores and the charge density. Both were found to be quite similar to the values obtained from MP alone. This agreement of EIS results with the MP ones, that are much simpler to deal with, confirms the accuracy of EIS to study the electrical properties of microfiltration membranes. The influence of electrode roughness and, in our EIS cell, the membrane roughness, on the constant phase element (CPE) of the equivalent circuit has been proved. Within this frame, the roughness fractal dimension of the membrane surface could be determined from EIS measurements. It resulted in fair agreement with the atomic force microscopy (AFM) determination.
Fil: Díaz, Darío Ramón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Carmona, Francisco Javier. Universidad de Extremadura; España
Fil: Palacio, Laura. Universidad de Valladolid; España
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Hernández, Antonio. Universidad de Valladolid; España
Fil: Pradanos del Pico, Pedro. Universidad de Valladolid; España - Materia
-
ELECTRICAL IMPEDANCE SPECTROSCOPY
MEMBRANE POTENTIAL
MEMBRANE ROUGHNESS FRACTAL DIMENSION
MEMBRANE SURFACE CHARGE DENSITY
TRANSPORT NUMBERS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/86678
Ver los metadatos del registro completo
id |
CONICETDig_af187393a79c20ca1ff062fb6b24d6ea |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/86678 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractalityDíaz, Darío RamónCarmona, Francisco JavierPalacio, LauraOchoa, Nelio ArielHernández, AntonioPradanos del Pico, PedroELECTRICAL IMPEDANCE SPECTROSCOPYMEMBRANE POTENTIALMEMBRANE ROUGHNESS FRACTAL DIMENSIONMEMBRANE SURFACE CHARGE DENSITYTRANSPORT NUMBERShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, the proper charge density of a microfiltration membrane has been determined by using two different methods. Firstly, the ionic transport of a KCl solution has been investigated by simultaneous measurements of saline flux and membrane potential (MP) resulting from a concentration gradient through the membrane. A simple model, including all the relevant contributions to the global electrical potential drop, allowed a calculation of transport numbers and membrane charge density. The response of ions inside the membrane to an oscillating electrical potential has been analyzed by impedance spectroscopy (or electrical impedance spectroscopy EIS). A quite simple experimental EIS design allowed, by taking into account MP measurements too, an easy assignation of an equivalent circuit. After a careful analysis of EIS results, it was possible to evaluate the electrical conductivity inside the pores and the charge density. Both were found to be quite similar to the values obtained from MP alone. This agreement of EIS results with the MP ones, that are much simpler to deal with, confirms the accuracy of EIS to study the electrical properties of microfiltration membranes. The influence of electrode roughness and, in our EIS cell, the membrane roughness, on the constant phase element (CPE) of the equivalent circuit has been proved. Within this frame, the roughness fractal dimension of the membrane surface could be determined from EIS measurements. It resulted in fair agreement with the atomic force microscopy (AFM) determination.Fil: Díaz, Darío Ramón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Carmona, Francisco Javier. Universidad de Extremadura; EspañaFil: Palacio, Laura. Universidad de Valladolid; EspañaFil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Hernández, Antonio. Universidad de Valladolid; EspañaFil: Pradanos del Pico, Pedro. Universidad de Valladolid; EspañaPergamon-Elsevier Science Ltd2018-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86678Díaz, Darío Ramón; Carmona, Francisco Javier; Palacio, Laura; Ochoa, Nelio Ariel; Hernández, Antonio; et al.; Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 178; 3-2018; 27-380009-2509CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2017.12.027info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250917307649info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:45:09Zoai:ri.conicet.gov.ar:11336/86678instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:45:09.523CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
title |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
spellingShingle |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality Díaz, Darío Ramón ELECTRICAL IMPEDANCE SPECTROSCOPY MEMBRANE POTENTIAL MEMBRANE ROUGHNESS FRACTAL DIMENSION MEMBRANE SURFACE CHARGE DENSITY TRANSPORT NUMBERS |
title_short |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
title_full |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
title_fullStr |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
title_full_unstemmed |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
title_sort |
Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality |
dc.creator.none.fl_str_mv |
Díaz, Darío Ramón Carmona, Francisco Javier Palacio, Laura Ochoa, Nelio Ariel Hernández, Antonio Pradanos del Pico, Pedro |
author |
Díaz, Darío Ramón |
author_facet |
Díaz, Darío Ramón Carmona, Francisco Javier Palacio, Laura Ochoa, Nelio Ariel Hernández, Antonio Pradanos del Pico, Pedro |
author_role |
author |
author2 |
Carmona, Francisco Javier Palacio, Laura Ochoa, Nelio Ariel Hernández, Antonio Pradanos del Pico, Pedro |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
ELECTRICAL IMPEDANCE SPECTROSCOPY MEMBRANE POTENTIAL MEMBRANE ROUGHNESS FRACTAL DIMENSION MEMBRANE SURFACE CHARGE DENSITY TRANSPORT NUMBERS |
topic |
ELECTRICAL IMPEDANCE SPECTROSCOPY MEMBRANE POTENTIAL MEMBRANE ROUGHNESS FRACTAL DIMENSION MEMBRANE SURFACE CHARGE DENSITY TRANSPORT NUMBERS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In this work, the proper charge density of a microfiltration membrane has been determined by using two different methods. Firstly, the ionic transport of a KCl solution has been investigated by simultaneous measurements of saline flux and membrane potential (MP) resulting from a concentration gradient through the membrane. A simple model, including all the relevant contributions to the global electrical potential drop, allowed a calculation of transport numbers and membrane charge density. The response of ions inside the membrane to an oscillating electrical potential has been analyzed by impedance spectroscopy (or electrical impedance spectroscopy EIS). A quite simple experimental EIS design allowed, by taking into account MP measurements too, an easy assignation of an equivalent circuit. After a careful analysis of EIS results, it was possible to evaluate the electrical conductivity inside the pores and the charge density. Both were found to be quite similar to the values obtained from MP alone. This agreement of EIS results with the MP ones, that are much simpler to deal with, confirms the accuracy of EIS to study the electrical properties of microfiltration membranes. The influence of electrode roughness and, in our EIS cell, the membrane roughness, on the constant phase element (CPE) of the equivalent circuit has been proved. Within this frame, the roughness fractal dimension of the membrane surface could be determined from EIS measurements. It resulted in fair agreement with the atomic force microscopy (AFM) determination. Fil: Díaz, Darío Ramón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Carmona, Francisco Javier. Universidad de Extremadura; España Fil: Palacio, Laura. Universidad de Valladolid; España Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Hernández, Antonio. Universidad de Valladolid; España Fil: Pradanos del Pico, Pedro. Universidad de Valladolid; España |
description |
In this work, the proper charge density of a microfiltration membrane has been determined by using two different methods. Firstly, the ionic transport of a KCl solution has been investigated by simultaneous measurements of saline flux and membrane potential (MP) resulting from a concentration gradient through the membrane. A simple model, including all the relevant contributions to the global electrical potential drop, allowed a calculation of transport numbers and membrane charge density. The response of ions inside the membrane to an oscillating electrical potential has been analyzed by impedance spectroscopy (or electrical impedance spectroscopy EIS). A quite simple experimental EIS design allowed, by taking into account MP measurements too, an easy assignation of an equivalent circuit. After a careful analysis of EIS results, it was possible to evaluate the electrical conductivity inside the pores and the charge density. Both were found to be quite similar to the values obtained from MP alone. This agreement of EIS results with the MP ones, that are much simpler to deal with, confirms the accuracy of EIS to study the electrical properties of microfiltration membranes. The influence of electrode roughness and, in our EIS cell, the membrane roughness, on the constant phase element (CPE) of the equivalent circuit has been proved. Within this frame, the roughness fractal dimension of the membrane surface could be determined from EIS measurements. It resulted in fair agreement with the atomic force microscopy (AFM) determination. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/86678 Díaz, Darío Ramón; Carmona, Francisco Javier; Palacio, Laura; Ochoa, Nelio Ariel; Hernández, Antonio; et al.; Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 178; 3-2018; 27-38 0009-2509 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/86678 |
identifier_str_mv |
Díaz, Darío Ramón; Carmona, Francisco Javier; Palacio, Laura; Ochoa, Nelio Ariel; Hernández, Antonio; et al.; Impedance spectroscopy and membrane potential analysis of microfiltration membranes. The influence of surface fractality; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 178; 3-2018; 27-38 0009-2509 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2017.12.027 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250917307649 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613419585503232 |
score |
13.070432 |