Composite ceramic membranes from natural aluminosilicates for microfiltration applications

Autores
Almandoz, M. C.; Pagliero, Cecilia Liliana; Ochoa, Nelio Ariel; Marchese, Jose
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work concerns to the development and characterisation of support, active layer and tubular composite membranes (CM) from natural aluminosilicates as principal components (clay, bentonite, feldspar, quartz, alumina). The selection of these raw materials was primarily based on their low cost and they are locally produced. In the substrates preparation, the effect of materials compositions, additives, particle sizes, paste rheological properties, and drying-sintering temperatures was investigated. The consolidated ceramic substrates were characterised by SEM, DTA–TG, X-Ray diffraction, Hg intrusion, mechanical resistance, and water flux measurements. Extrusion has been used as the forming process of tubular support. The CM was fabricated depositing a thin active layer by slip-casting method on the support. The CM sintered at 1200 1C showed the best structural characteristics, porosities of 50%, active layer pore size between 0.08 and 0.55 μm. The CM hydraulic permeabilities (10–274 L/h m2 kPa) were comparable and greater than several inorganic commercial membranes and CM obtained from other researches. The CM microfiltration effectiveness was tested with different substances from food industry, i.e. slaughterhouse wastewater treatment and goat milk pasteurisation. The obtained results, insoluble residue rejections (100%) and high bacterial removal (87–99%), make the ceramic CM suitable for microfiltration processes.
Fil: Almandoz, M. C.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Pagliero, Cecilia Liliana. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Materia
Sintering
Aluminosilicates
Ceramic Membrane
Microfiltration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/22106
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/22106
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Composite ceramic membranes from natural aluminosilicates for microfiltration applicationsAlmandoz, M. C.Pagliero, Cecilia LilianaOchoa, Nelio ArielMarchese, JoseSinteringAluminosilicatesCeramic MembraneMicrofiltrationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2This work concerns to the development and characterisation of support, active layer and tubular composite membranes (CM) from natural aluminosilicates as principal components (clay, bentonite, feldspar, quartz, alumina). The selection of these raw materials was primarily based on their low cost and they are locally produced. In the substrates preparation, the effect of materials compositions, additives, particle sizes, paste rheological properties, and drying-sintering temperatures was investigated. The consolidated ceramic substrates were characterised by SEM, DTA–TG, X-Ray diffraction, Hg intrusion, mechanical resistance, and water flux measurements. Extrusion has been used as the forming process of tubular support. The CM was fabricated depositing a thin active layer by slip-casting method on the support. The CM sintered at 1200 1C showed the best structural characteristics, porosities of 50%, active layer pore size between 0.08 and 0.55 μm. The CM hydraulic permeabilities (10–274 L/h m2 kPa) were comparable and greater than several inorganic commercial membranes and CM obtained from other researches. The CM microfiltration effectiveness was tested with different substances from food industry, i.e. slaughterhouse wastewater treatment and goat milk pasteurisation. The obtained results, insoluble residue rejections (100%) and high bacterial removal (87–99%), make the ceramic CM suitable for microfiltration processes.Fil: Almandoz, M. C.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; ArgentinaFil: Pagliero, Cecilia Liliana. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaElsevier2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/22106Almandoz, M. C.; Pagliero, Cecilia Liliana; Ochoa, Nelio Ariel; Marchese, Jose; Composite ceramic membranes from natural aluminosilicates for microfiltration applications; Elsevier; Ceramics International; 41; 4; 1-2015; 5621-56330272-8842CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2014.12.144info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0272884214020653info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:15Zoai:ri.conicet.gov.ar:11336/22106instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:15.869CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Composite ceramic membranes from natural aluminosilicates for microfiltration applications
title Composite ceramic membranes from natural aluminosilicates for microfiltration applications
spellingShingle Composite ceramic membranes from natural aluminosilicates for microfiltration applications
Almandoz, M. C.
Sintering
Aluminosilicates
Ceramic Membrane
Microfiltration
title_short Composite ceramic membranes from natural aluminosilicates for microfiltration applications
title_full Composite ceramic membranes from natural aluminosilicates for microfiltration applications
title_fullStr Composite ceramic membranes from natural aluminosilicates for microfiltration applications
title_full_unstemmed Composite ceramic membranes from natural aluminosilicates for microfiltration applications
title_sort Composite ceramic membranes from natural aluminosilicates for microfiltration applications
dc.creator.none.fl_str_mv Almandoz, M. C.
Pagliero, Cecilia Liliana
Ochoa, Nelio Ariel
Marchese, Jose
author Almandoz, M. C.
author_facet Almandoz, M. C.
Pagliero, Cecilia Liliana
Ochoa, Nelio Ariel
Marchese, Jose
author_role author
author2 Pagliero, Cecilia Liliana
Ochoa, Nelio Ariel
Marchese, Jose
author2_role author
author
author
dc.subject.none.fl_str_mv Sintering
Aluminosilicates
Ceramic Membrane
Microfiltration
topic Sintering
Aluminosilicates
Ceramic Membrane
Microfiltration
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work concerns to the development and characterisation of support, active layer and tubular composite membranes (CM) from natural aluminosilicates as principal components (clay, bentonite, feldspar, quartz, alumina). The selection of these raw materials was primarily based on their low cost and they are locally produced. In the substrates preparation, the effect of materials compositions, additives, particle sizes, paste rheological properties, and drying-sintering temperatures was investigated. The consolidated ceramic substrates were characterised by SEM, DTA–TG, X-Ray diffraction, Hg intrusion, mechanical resistance, and water flux measurements. Extrusion has been used as the forming process of tubular support. The CM was fabricated depositing a thin active layer by slip-casting method on the support. The CM sintered at 1200 1C showed the best structural characteristics, porosities of 50%, active layer pore size between 0.08 and 0.55 μm. The CM hydraulic permeabilities (10–274 L/h m2 kPa) were comparable and greater than several inorganic commercial membranes and CM obtained from other researches. The CM microfiltration effectiveness was tested with different substances from food industry, i.e. slaughterhouse wastewater treatment and goat milk pasteurisation. The obtained results, insoluble residue rejections (100%) and high bacterial removal (87–99%), make the ceramic CM suitable for microfiltration processes.
Fil: Almandoz, M. C.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Pagliero, Cecilia Liliana. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
description This work concerns to the development and characterisation of support, active layer and tubular composite membranes (CM) from natural aluminosilicates as principal components (clay, bentonite, feldspar, quartz, alumina). The selection of these raw materials was primarily based on their low cost and they are locally produced. In the substrates preparation, the effect of materials compositions, additives, particle sizes, paste rheological properties, and drying-sintering temperatures was investigated. The consolidated ceramic substrates were characterised by SEM, DTA–TG, X-Ray diffraction, Hg intrusion, mechanical resistance, and water flux measurements. Extrusion has been used as the forming process of tubular support. The CM was fabricated depositing a thin active layer by slip-casting method on the support. The CM sintered at 1200 1C showed the best structural characteristics, porosities of 50%, active layer pore size between 0.08 and 0.55 μm. The CM hydraulic permeabilities (10–274 L/h m2 kPa) were comparable and greater than several inorganic commercial membranes and CM obtained from other researches. The CM microfiltration effectiveness was tested with different substances from food industry, i.e. slaughterhouse wastewater treatment and goat milk pasteurisation. The obtained results, insoluble residue rejections (100%) and high bacterial removal (87–99%), make the ceramic CM suitable for microfiltration processes.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/22106
Almandoz, M. C.; Pagliero, Cecilia Liliana; Ochoa, Nelio Ariel; Marchese, Jose; Composite ceramic membranes from natural aluminosilicates for microfiltration applications; Elsevier; Ceramics International; 41; 4; 1-2015; 5621-5633
0272-8842
CONICET Digital
CONICET
url http://hdl.handle.net/11336/22106
identifier_str_mv Almandoz, M. C.; Pagliero, Cecilia Liliana; Ochoa, Nelio Ariel; Marchese, Jose; Composite ceramic membranes from natural aluminosilicates for microfiltration applications; Elsevier; Ceramics International; 41; 4; 1-2015; 5621-5633
0272-8842
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2014.12.144
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0272884214020653
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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