Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review

Autores
Cabrera, Maria Ines; Grau, Ricardo José Antonio
Año de publicación
2008
Idioma
alemán
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.
Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Kinetic Modeling
Hydrogenation Competitive Model
Non-Competitive Model
Semicompetitive Model
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/25376

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spelling Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief ReviewCabrera, Maria InesGrau, Ricardo José AntonioKinetic ModelingHydrogenation Competitive ModelNon-Competitive ModelSemicompetitive Modelhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaResearch Trends2008-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25376Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-530972-4478CONICET DigitalCONICETdeuinfo:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=11&tid=1&aid=2512&pub=2008&type=3info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:28:04Zoai:ri.conicet.gov.ar:11336/25376instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:28:05.097CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
title Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
spellingShingle Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
Cabrera, Maria Ines
Kinetic Modeling
Hydrogenation Competitive Model
Non-Competitive Model
Semicompetitive Model
title_short Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
title_full Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
title_fullStr Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
title_full_unstemmed Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
title_sort Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
dc.creator.none.fl_str_mv Cabrera, Maria Ines
Grau, Ricardo José Antonio
author Cabrera, Maria Ines
author_facet Cabrera, Maria Ines
Grau, Ricardo José Antonio
author_role author
author2 Grau, Ricardo José Antonio
author2_role author
dc.subject.none.fl_str_mv Kinetic Modeling
Hydrogenation Competitive Model
Non-Competitive Model
Semicompetitive Model
topic Kinetic Modeling
Hydrogenation Competitive Model
Non-Competitive Model
Semicompetitive Model
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.
Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.
publishDate 2008
dc.date.none.fl_str_mv 2008-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/25376
Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-53
0972-4478
CONICET Digital
CONICET
url http://hdl.handle.net/11336/25376
identifier_str_mv Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-53
0972-4478
CONICET Digital
CONICET
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language deu
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
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application/pdf
dc.publisher.none.fl_str_mv Research Trends
publisher.none.fl_str_mv Research Trends
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