Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review
- Autores
- Cabrera, Maria Ines; Grau, Ricardo José Antonio
- Año de publicación
- 2008
- Idioma
- alemán
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.
Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina - Materia
-
Kinetic Modeling
Hydrogenation Competitive Model
Non-Competitive Model
Semicompetitive Model - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/25376
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Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief ReviewCabrera, Maria InesGrau, Ricardo José AntonioKinetic ModelingHydrogenation Competitive ModelNon-Competitive ModelSemicompetitive Modelhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches.Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaResearch Trends2008-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25376Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-530972-4478CONICET DigitalCONICETdeuinfo:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=11&tid=1&aid=2512&pub=2008&type=3info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:28:04Zoai:ri.conicet.gov.ar:11336/25376instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:28:05.097CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
title |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
spellingShingle |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review Cabrera, Maria Ines Kinetic Modeling Hydrogenation Competitive Model Non-Competitive Model Semicompetitive Model |
title_short |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
title_full |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
title_fullStr |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
title_full_unstemmed |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
title_sort |
Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review |
dc.creator.none.fl_str_mv |
Cabrera, Maria Ines Grau, Ricardo José Antonio |
author |
Cabrera, Maria Ines |
author_facet |
Cabrera, Maria Ines Grau, Ricardo José Antonio |
author_role |
author |
author2 |
Grau, Ricardo José Antonio |
author2_role |
author |
dc.subject.none.fl_str_mv |
Kinetic Modeling Hydrogenation Competitive Model Non-Competitive Model Semicompetitive Model |
topic |
Kinetic Modeling Hydrogenation Competitive Model Non-Competitive Model Semicompetitive Model |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches. Fil: Cabrera, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
description |
This brief review focuses on the evolving concepts related to the kinetic modeling of catalytic hydrogenation systems involving organic compounds of large molecular size. After a short paragraph introducing the scope of the article, different mathematical approaches are reviewed from a Chemical Reaction Engineering viewpoint. Their chronological development is described, going from the early simple LHHW model to recent advanced models based on the concept of multicentered and semicompetitive adsorption. First, the review presents and critically analyzes the simplest mathematical attempts to deal with the classical kinetic models based upon extreme adsorption regimes, i.e., competitive and non-competitive adsorption between hydrogen and organic molecules. Then, it discusses progressive attempts based on more rigorous frameworks for conciliating the understanding of finite differences in the molecular size of species, admitting a distinction between occupied-sites and covered-sites by the large molecules of organic species. Accordingly, the concepts of multicentered and semi-competitive adsorption are brought on the scene, and recent proposals are analyzed in detail to link the two seemingly separate kinetic models describing the extreme modes of competitive and non-competitive adsorption. The additional indication of the number of surface sites that would likely be covered by organic molecules appears to be the most fascinating result of these advanced approaches. Finally, the review highlights the need for examining the robustness of these recent approaches. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/25376 Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-53 0972-4478 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/25376 |
identifier_str_mv |
Cabrera, Maria Ines; Grau, Ricardo José Antonio; Kinetic Modeling of Hydrogenation Reactions over Metal-Supported Catalysts, Recognizing the Differences Between the Molecular Sizes of Hydrogen and Organic Species: A Brief Review; Research Trends; Trends in Chemical Engineering; 11; 8-2008; 39-53 0972-4478 CONICET Digital CONICET |
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info:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=11&tid=1&aid=2512&pub=2008&type=3 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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application/pdf application/pdf application/pdf |
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Research Trends |
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Research Trends |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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