Effect of alloying elements in melt spun Mg-alloys for hydrogen storage

Autores
Rozenberg, Silvia; Saporiti, María Fabiana Sonia; Lang, Julien; Audebert, Fernando Enrique; Botta, Pablo Martín; Stoica, Mihai; Huot, Jacques; Eckert, Jürgen
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper we report the effect of alloying elements on hydrogen storage properties of melt-spun Mg-based alloys. The base alloys Mg90Si10, Mg90Cu10, Mg65Cu35 (at%) were studied. We also investigated the effect of rare earths (using MM: mischmetal) and Al in Mg65Cu25Al10, Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys. All the melt-spun alloys without MM show a crystalline structure, and the Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys showed an amorphous and partially amorphous structure respectively. At 350˚C all the alloys had a crystalline structure during the hydrogen absorption-desorption tests. It was observed that Si and Cu in the binaries alloys hindered completely the activation of thehydrogen absorption. The partial substitution of Cu by MM or Al allowed activation. The combined substitution of Cu by MM and Al showed the best results with the fastest absorption and desorption kinetics, which suggests that this combination can be used for new Mg-alloys to improve hydrogen storage properties.
Fil: Rozenberg, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; Argentina
Fil: Saporiti, María Fabiana Sonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; Argentina
Fil: Lang, Julien. Université du Québec a Montreal; Canadá
Fil: Audebert, Fernando Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Stoica, Mihai. Leibniz Institute for Solid State and Materials Research Dresden; Alemania
Fil: Huot, Jacques. Université du Québec a Montreal; Canadá
Fil: Eckert, Jürgen. The Erich Schmid Institute of Materials Science; Austria
Materia
Hydrogen storage
Mg based alloy
Rapid solidification
Nanomaterials
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34539
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34539
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of alloying elements in melt spun Mg-alloys for hydrogen storageRozenberg, SilviaSaporiti, María Fabiana SoniaLang, JulienAudebert, Fernando EnriqueBotta, Pablo MartínStoica, MihaiHuot, JacquesEckert, JürgenHydrogen storageMg based alloyRapid solidificationNanomaterialshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this paper we report the effect of alloying elements on hydrogen storage properties of melt-spun Mg-based alloys. The base alloys Mg90Si10, Mg90Cu10, Mg65Cu35 (at%) were studied. We also investigated the effect of rare earths (using MM: mischmetal) and Al in Mg65Cu25Al10, Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys. All the melt-spun alloys without MM show a crystalline structure, and the Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys showed an amorphous and partially amorphous structure respectively. At 350˚C all the alloys had a crystalline structure during the hydrogen absorption-desorption tests. It was observed that Si and Cu in the binaries alloys hindered completely the activation of thehydrogen absorption. The partial substitution of Cu by MM or Al allowed activation. The combined substitution of Cu by MM and Al showed the best results with the fastest absorption and desorption kinetics, which suggests that this combination can be used for new Mg-alloys to improve hydrogen storage properties.Fil: Rozenberg, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; ArgentinaFil: Saporiti, María Fabiana Sonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; ArgentinaFil: Lang, Julien. Université du Québec a Montreal; CanadáFil: Audebert, Fernando Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Stoica, Mihai. Leibniz Institute for Solid State and Materials Research Dresden; AlemaniaFil: Huot, Jacques. Université du Québec a Montreal; CanadáFil: Eckert, Jürgen. The Erich Schmid Institute of Materials Science; AustriaUniversidade Federal de São Carlos2016-07-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34539Rozenberg, Silvia; Saporiti, María Fabiana Sonia; Lang, Julien; Audebert, Fernando Enrique; Botta, Pablo Martín; et al.; Effect of alloying elements in melt spun Mg-alloys for hydrogen storage; Universidade Federal de São Carlos; Materials Research; 19; supl. 1; 25-7-2016; 20-261516-1439CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/np2mcninfo:eu-repo/semantics/altIdentifier/doi/10.1590/1980-5373-MR-2016-0048info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:19Zoai:ri.conicet.gov.ar:11336/34539instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:19.354CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
title Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
spellingShingle Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
Rozenberg, Silvia
Hydrogen storage
Mg based alloy
Rapid solidification
Nanomaterials
title_short Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
title_full Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
title_fullStr Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
title_full_unstemmed Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
title_sort Effect of alloying elements in melt spun Mg-alloys for hydrogen storage
dc.creator.none.fl_str_mv Rozenberg, Silvia
Saporiti, María Fabiana Sonia
Lang, Julien
Audebert, Fernando Enrique
Botta, Pablo Martín
Stoica, Mihai
Huot, Jacques
Eckert, Jürgen
author Rozenberg, Silvia
author_facet Rozenberg, Silvia
Saporiti, María Fabiana Sonia
Lang, Julien
Audebert, Fernando Enrique
Botta, Pablo Martín
Stoica, Mihai
Huot, Jacques
Eckert, Jürgen
author_role author
author2 Saporiti, María Fabiana Sonia
Lang, Julien
Audebert, Fernando Enrique
Botta, Pablo Martín
Stoica, Mihai
Huot, Jacques
Eckert, Jürgen
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Hydrogen storage
Mg based alloy
Rapid solidification
Nanomaterials
topic Hydrogen storage
Mg based alloy
Rapid solidification
Nanomaterials
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this paper we report the effect of alloying elements on hydrogen storage properties of melt-spun Mg-based alloys. The base alloys Mg90Si10, Mg90Cu10, Mg65Cu35 (at%) were studied. We also investigated the effect of rare earths (using MM: mischmetal) and Al in Mg65Cu25Al10, Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys. All the melt-spun alloys without MM show a crystalline structure, and the Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys showed an amorphous and partially amorphous structure respectively. At 350˚C all the alloys had a crystalline structure during the hydrogen absorption-desorption tests. It was observed that Si and Cu in the binaries alloys hindered completely the activation of thehydrogen absorption. The partial substitution of Cu by MM or Al allowed activation. The combined substitution of Cu by MM and Al showed the best results with the fastest absorption and desorption kinetics, which suggests that this combination can be used for new Mg-alloys to improve hydrogen storage properties.
Fil: Rozenberg, Silvia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; Argentina
Fil: Saporiti, María Fabiana Sonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería ; Argentina
Fil: Lang, Julien. Université du Québec a Montreal; Canadá
Fil: Audebert, Fernando Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Stoica, Mihai. Leibniz Institute for Solid State and Materials Research Dresden; Alemania
Fil: Huot, Jacques. Université du Québec a Montreal; Canadá
Fil: Eckert, Jürgen. The Erich Schmid Institute of Materials Science; Austria
description In this paper we report the effect of alloying elements on hydrogen storage properties of melt-spun Mg-based alloys. The base alloys Mg90Si10, Mg90Cu10, Mg65Cu35 (at%) were studied. We also investigated the effect of rare earths (using MM: mischmetal) and Al in Mg65Cu25Al10, Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys. All the melt-spun alloys without MM show a crystalline structure, and the Mg65Cu25MM10 and Mg65Cu10Al15MM10 alloys showed an amorphous and partially amorphous structure respectively. At 350˚C all the alloys had a crystalline structure during the hydrogen absorption-desorption tests. It was observed that Si and Cu in the binaries alloys hindered completely the activation of thehydrogen absorption. The partial substitution of Cu by MM or Al allowed activation. The combined substitution of Cu by MM and Al showed the best results with the fastest absorption and desorption kinetics, which suggests that this combination can be used for new Mg-alloys to improve hydrogen storage properties.
publishDate 2016
dc.date.none.fl_str_mv 2016-07-25
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34539
Rozenberg, Silvia; Saporiti, María Fabiana Sonia; Lang, Julien; Audebert, Fernando Enrique; Botta, Pablo Martín; et al.; Effect of alloying elements in melt spun Mg-alloys for hydrogen storage; Universidade Federal de São Carlos; Materials Research; 19; supl. 1; 25-7-2016; 20-26
1516-1439
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34539
identifier_str_mv Rozenberg, Silvia; Saporiti, María Fabiana Sonia; Lang, Julien; Audebert, Fernando Enrique; Botta, Pablo Martín; et al.; Effect of alloying elements in melt spun Mg-alloys for hydrogen storage; Universidade Federal de São Carlos; Materials Research; 19; supl. 1; 25-7-2016; 20-26
1516-1439
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/np2mcn
info:eu-repo/semantics/altIdentifier/doi/10.1590/1980-5373-MR-2016-0048
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de São Carlos
publisher.none.fl_str_mv Universidade Federal de São Carlos
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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