Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept

Autores
Puszkiel, Julián Atilio; Bellosta von Colbe, José M.; Jepsen, Julian; Mitrokhin, Sergey V.; Movlaev, Elshad; Verbetsky, Victor; Klassen, Thomas
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 ◦C and from 15 to 500 bar: ∆Habs. = 22 ± 1 kJ/mol H2, ∆Sabs. = 107 ± 2 J/K mol H2, and ∆Hdes. = 24 ± 1 kJ/mol H2, ∆Sdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.
Fil: Puszkiel, Julián Atilio. Helmholtz-zentrum Geesthacht; Alemania. Instituto de Investigaciones Energéticas de Cataluña; España. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada CAB. Departamento Fisicoquímica de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bellosta von Colbe, José M.. Helmholtz-zentrum Geesthacht; Alemania
Fil: Jepsen, Julian. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
Fil: Mitrokhin, Sergey V.. Lomonosov Moscow State University; Rusia
Fil: Movlaev, Elshad. Lomonosov Moscow State University; Rusia
Fil: Verbetsky, Victor. Lomonosov Moscow State University; Rusia
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
Materia
AB2 ALLOY
COMPRESSED HYDROGEN
HYBRID
HYDROGEN STORAGE
KINETICS
METAL HYDRIDE
THERMODYNAMICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/126699
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage conceptPuszkiel, Julián AtilioBellosta von Colbe, José M.Jepsen, JulianMitrokhin, Sergey V.Movlaev, ElshadVerbetsky, VictorKlassen, ThomasAB2 ALLOYCOMPRESSED HYDROGENHYBRIDHYDROGEN STORAGEKINETICSMETAL HYDRIDETHERMODYNAMICShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 ◦C and from 15 to 500 bar: ∆Habs. = 22 ± 1 kJ/mol H2, ∆Sabs. = 107 ± 2 J/K mol H2, and ∆Hdes. = 24 ± 1 kJ/mol H2, ∆Sdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.Fil: Puszkiel, Julián Atilio. Helmholtz-zentrum Geesthacht; Alemania. Instituto de Investigaciones Energéticas de Cataluña; España. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada CAB. Departamento Fisicoquímica de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Bellosta von Colbe, José M.. Helmholtz-zentrum Geesthacht; AlemaniaFil: Jepsen, Julian. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; AlemaniaFil: Mitrokhin, Sergey V.. Lomonosov Moscow State University; RusiaFil: Movlaev, Elshad. Lomonosov Moscow State University; RusiaFil: Verbetsky, Victor. Lomonosov Moscow State University; RusiaFil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; AlemaniaMultidisciplinary Digital Publishing Institute2020-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/126699Puszkiel, Julián Atilio; Bellosta von Colbe, José M.; Jepsen, Julian; Mitrokhin, Sergey V.; Movlaev, Elshad; et al.; Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept; Multidisciplinary Digital Publishing Institute; Energies; 13; 11; 6-2020; 1-261996-1073CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/13/11/2751info:eu-repo/semantics/altIdentifier/doi/10.3390/en13112751info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-12-23T14:34:07Zoai:ri.conicet.gov.ar:11336/126699instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-12-23 14:34:08.213CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
title Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
spellingShingle Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
Puszkiel, Julián Atilio
AB2 ALLOY
COMPRESSED HYDROGEN
HYBRID
HYDROGEN STORAGE
KINETICS
METAL HYDRIDE
THERMODYNAMICS
title_short Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
title_full Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
title_fullStr Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
title_full_unstemmed Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
title_sort Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept
dc.creator.none.fl_str_mv Puszkiel, Julián Atilio
Bellosta von Colbe, José M.
Jepsen, Julian
Mitrokhin, Sergey V.
Movlaev, Elshad
Verbetsky, Victor
Klassen, Thomas
author Puszkiel, Julián Atilio
author_facet Puszkiel, Julián Atilio
Bellosta von Colbe, José M.
Jepsen, Julian
Mitrokhin, Sergey V.
Movlaev, Elshad
Verbetsky, Victor
Klassen, Thomas
author_role author
author2 Bellosta von Colbe, José M.
Jepsen, Julian
Mitrokhin, Sergey V.
Movlaev, Elshad
Verbetsky, Victor
Klassen, Thomas
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv AB2 ALLOY
COMPRESSED HYDROGEN
HYBRID
HYDROGEN STORAGE
KINETICS
METAL HYDRIDE
THERMODYNAMICS
topic AB2 ALLOY
COMPRESSED HYDROGEN
HYBRID
HYDROGEN STORAGE
KINETICS
METAL HYDRIDE
THERMODYNAMICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 ◦C and from 15 to 500 bar: ∆Habs. = 22 ± 1 kJ/mol H2, ∆Sabs. = 107 ± 2 J/K mol H2, and ∆Hdes. = 24 ± 1 kJ/mol H2, ∆Sdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.
Fil: Puszkiel, Julián Atilio. Helmholtz-zentrum Geesthacht; Alemania. Instituto de Investigaciones Energéticas de Cataluña; España. Comisión Nacional de Energía Atómica. Gerencia de Área de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada CAB. Departamento Fisicoquímica de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bellosta von Colbe, José M.. Helmholtz-zentrum Geesthacht; Alemania
Fil: Jepsen, Julian. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
Fil: Mitrokhin, Sergey V.. Lomonosov Moscow State University; Rusia
Fil: Movlaev, Elshad. Lomonosov Moscow State University; Rusia
Fil: Verbetsky, Victor. Lomonosov Moscow State University; Rusia
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania. Helmut Schmidt University; Alemania
description The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 ◦C and from 15 to 500 bar: ∆Habs. = 22 ± 1 kJ/mol H2, ∆Sabs. = 107 ± 2 J/K mol H2, and ∆Hdes. = 24 ± 1 kJ/mol H2, ∆Sdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (ENG) allows the improvement of the heat transfer properties, showing a reversible capacity of about 1.5 wt.%, cycling stability and hydrogenation/dehydrogenation times between 25 to 70 s. The feasibility for the utilization of the designed material in a high-pressure tank is also evaluated, considering practical design parameters.
publishDate 2020
dc.date.none.fl_str_mv 2020-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/126699
Puszkiel, Julián Atilio; Bellosta von Colbe, José M.; Jepsen, Julian; Mitrokhin, Sergey V.; Movlaev, Elshad; et al.; Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept; Multidisciplinary Digital Publishing Institute; Energies; 13; 11; 6-2020; 1-26
1996-1073
CONICET Digital
CONICET
url http://hdl.handle.net/11336/126699
identifier_str_mv Puszkiel, Julián Atilio; Bellosta von Colbe, José M.; Jepsen, Julian; Mitrokhin, Sergey V.; Movlaev, Elshad; et al.; Designing an Ab2-type alloy (TIZr-CrMNMO) for the hybrid hydrogen storage concept; Multidisciplinary Digital Publishing Institute; Energies; 13; 11; 6-2020; 1-26
1996-1073
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1073/13/11/2751
info:eu-repo/semantics/altIdentifier/doi/10.3390/en13112751
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.441415

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