High-temperature thermoelectric properties of W-substituted CaMnO 3

Autores
Alfaruq, Dimas S.; Eilertsen, James; Thiel, Philipp; Aguirre, Myriam H.; Otal, Eugenio Hernan; Populoh, Sascha; Yoon, Songhak; Weidenkaff, Anke
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The thermoelectric properties of W-substituted CaMn1-xWxO3-δ (x = 0.01, 0.03; 0.05) samples, prepared by soft chemistry, were investigated from 300 K to 1000 K and compared to Nb-substituted CaMn0.98Nb0.02O3-δ. All compositions exhibit both an increase in absolute Seebeck coefficient and electrical resistivity with temperature. Moreover, compared to the Nb-substituted sample, the thermal conductivity of the W-substituted samples was strongly reduced. This reduction is attributed to the nearly two times greater mass of tungsten. Consequently, a ZT of 0.19 was found in CaMn0.97W0.03O3-δ at 1000 K, which was larger than ZT exhibited by the 2% Nb-doped sample.
Fil: Alfaruq, Dimas S.. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Eilertsen, James. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Thiel, Philipp. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Aguirre, Myriam H.. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Subsede Instituto Universitario Aeronáutico; Argentina
Fil: Populoh, Sascha. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Yoon, Songhak. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Weidenkaff, Anke. EMPA. Solid State Chemistry and Catalysis; Suiza
Materia
Termoelectricidad
Rayos X
Oxidos
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2185
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2185
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High-temperature thermoelectric properties of W-substituted CaMnO 3Alfaruq, Dimas S.Eilertsen, JamesThiel, PhilippAguirre, Myriam H.Otal, Eugenio HernanPopuloh, SaschaYoon, SonghakWeidenkaff, AnkeTermoelectricidadRayos XOxidoshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The thermoelectric properties of W-substituted CaMn1-xWxO3-δ (x = 0.01, 0.03; 0.05) samples, prepared by soft chemistry, were investigated from 300 K to 1000 K and compared to Nb-substituted CaMn0.98Nb0.02O3-δ. All compositions exhibit both an increase in absolute Seebeck coefficient and electrical resistivity with temperature. Moreover, compared to the Nb-substituted sample, the thermal conductivity of the W-substituted samples was strongly reduced. This reduction is attributed to the nearly two times greater mass of tungsten. Consequently, a ZT of 0.19 was found in CaMn0.97W0.03O3-δ at 1000 K, which was larger than ZT exhibited by the 2% Nb-doped sample.Fil: Alfaruq, Dimas S.. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Eilertsen, James. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Thiel, Philipp. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Aguirre, Myriam H.. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Subsede Instituto Universitario Aeronáutico; ArgentinaFil: Populoh, Sascha. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Yoon, Songhak. EMPA. Solid State Chemistry and Catalysis; SuizaFil: Weidenkaff, Anke. EMPA. Solid State Chemistry and Catalysis; SuizaMaterials Research Society2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2185Alfaruq, Dimas S.; Eilertsen, James; Thiel, Philipp; Aguirre, Myriam H.; Otal, Eugenio Hernan; et al.; High-temperature thermoelectric properties of W-substituted CaMnO 3; Materials Research Society; Mat. Res. Soc. Symp. Proc. (pittsburg); 1490; 12-2013; 3-80272-9172enginfo:eu-repo/semantics/altIdentifier/doi/10.1557/opl.2013.85info:eu-repo/semantics/altIdentifier/url/http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8825212&fileId=S1946427413000857info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:17Zoai:ri.conicet.gov.ar:11336/2185instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:17.772CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High-temperature thermoelectric properties of W-substituted CaMnO 3
title High-temperature thermoelectric properties of W-substituted CaMnO 3
spellingShingle High-temperature thermoelectric properties of W-substituted CaMnO 3
Alfaruq, Dimas S.
Termoelectricidad
Rayos X
Oxidos
title_short High-temperature thermoelectric properties of W-substituted CaMnO 3
title_full High-temperature thermoelectric properties of W-substituted CaMnO 3
title_fullStr High-temperature thermoelectric properties of W-substituted CaMnO 3
title_full_unstemmed High-temperature thermoelectric properties of W-substituted CaMnO 3
title_sort High-temperature thermoelectric properties of W-substituted CaMnO 3
dc.creator.none.fl_str_mv Alfaruq, Dimas S.
Eilertsen, James
Thiel, Philipp
Aguirre, Myriam H.
Otal, Eugenio Hernan
Populoh, Sascha
Yoon, Songhak
Weidenkaff, Anke
author Alfaruq, Dimas S.
author_facet Alfaruq, Dimas S.
Eilertsen, James
Thiel, Philipp
Aguirre, Myriam H.
Otal, Eugenio Hernan
Populoh, Sascha
Yoon, Songhak
Weidenkaff, Anke
author_role author
author2 Eilertsen, James
Thiel, Philipp
Aguirre, Myriam H.
Otal, Eugenio Hernan
Populoh, Sascha
Yoon, Songhak
Weidenkaff, Anke
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Termoelectricidad
Rayos X
Oxidos
topic Termoelectricidad
Rayos X
Oxidos
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The thermoelectric properties of W-substituted CaMn1-xWxO3-δ (x = 0.01, 0.03; 0.05) samples, prepared by soft chemistry, were investigated from 300 K to 1000 K and compared to Nb-substituted CaMn0.98Nb0.02O3-δ. All compositions exhibit both an increase in absolute Seebeck coefficient and electrical resistivity with temperature. Moreover, compared to the Nb-substituted sample, the thermal conductivity of the W-substituted samples was strongly reduced. This reduction is attributed to the nearly two times greater mass of tungsten. Consequently, a ZT of 0.19 was found in CaMn0.97W0.03O3-δ at 1000 K, which was larger than ZT exhibited by the 2% Nb-doped sample.
Fil: Alfaruq, Dimas S.. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Eilertsen, James. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Thiel, Philipp. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Aguirre, Myriam H.. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Subsede Instituto Universitario Aeronáutico; Argentina
Fil: Populoh, Sascha. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Yoon, Songhak. EMPA. Solid State Chemistry and Catalysis; Suiza
Fil: Weidenkaff, Anke. EMPA. Solid State Chemistry and Catalysis; Suiza
description The thermoelectric properties of W-substituted CaMn1-xWxO3-δ (x = 0.01, 0.03; 0.05) samples, prepared by soft chemistry, were investigated from 300 K to 1000 K and compared to Nb-substituted CaMn0.98Nb0.02O3-δ. All compositions exhibit both an increase in absolute Seebeck coefficient and electrical resistivity with temperature. Moreover, compared to the Nb-substituted sample, the thermal conductivity of the W-substituted samples was strongly reduced. This reduction is attributed to the nearly two times greater mass of tungsten. Consequently, a ZT of 0.19 was found in CaMn0.97W0.03O3-δ at 1000 K, which was larger than ZT exhibited by the 2% Nb-doped sample.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2185
Alfaruq, Dimas S.; Eilertsen, James; Thiel, Philipp; Aguirre, Myriam H.; Otal, Eugenio Hernan; et al.; High-temperature thermoelectric properties of W-substituted CaMnO 3; Materials Research Society; Mat. Res. Soc. Symp. Proc. (pittsburg); 1490; 12-2013; 3-8
0272-9172
url http://hdl.handle.net/11336/2185
identifier_str_mv Alfaruq, Dimas S.; Eilertsen, James; Thiel, Philipp; Aguirre, Myriam H.; Otal, Eugenio Hernan; et al.; High-temperature thermoelectric properties of W-substituted CaMnO 3; Materials Research Society; Mat. Res. Soc. Symp. Proc. (pittsburg); 1490; 12-2013; 3-8
0272-9172
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1557/opl.2013.85
info:eu-repo/semantics/altIdentifier/url/http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8825212&fileId=S1946427413000857
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Materials Research Society
publisher.none.fl_str_mv Materials Research Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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