Cation distribution and magnetic properties of LiMnZn ferrites

Autores
Arana, M.; Galván Josa, Víctor Martín; Jacobo, S. E.; Bercoff, Paula Gabriela
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Spinel compounds Li0.5xZn0.6xMn0.4Fe2+0.5xO4 (x = 0.0; 0.1; 0.2; 0.4) were produced by the selfcombustion sol–gel method. The obtained powders were calcined at 1000 C for 2 h in Ar atmosphere . The structural and microstructural characteristics of the resulting samples were studied by magnetization measurements, Mössbauer spectroscopy and X-ray powder diffraction in combination with the Rietveld method. Based on magnetization results, a cation distribution model is proposed which is tested with Rietveld refinements and supported by Mössbauer results. The observed increase in saturation magnetization wit h Li content in the structure is explained by an unusual distribution of Zn2+ ions in octahedral sites.
Fil: Arana, M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Jacobo, S. E.. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Bercoff, Paula Gabriela. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Materia
Ceramics
Oxide Materials
Crystal Structure
Magnetization
X-Ray Diffraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8938
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/8938
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Cation distribution and magnetic properties of LiMnZn ferritesArana, M.Galván Josa, Víctor MartínJacobo, S. E.Bercoff, Paula GabrielaCeramicsOxide MaterialsCrystal StructureMagnetizationX-Ray Diffractionhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Spinel compounds Li0.5xZn0.6xMn0.4Fe2+0.5xO4 (x = 0.0; 0.1; 0.2; 0.4) were produced by the selfcombustion sol–gel method. The obtained powders were calcined at 1000 C for 2 h in Ar atmosphere . The structural and microstructural characteristics of the resulting samples were studied by magnetization measurements, Mössbauer spectroscopy and X-ray powder diffraction in combination with the Rietveld method. Based on magnetization results, a cation distribution model is proposed which is tested with Rietveld refinements and supported by Mössbauer results. The observed increase in saturation magnetization wit h Li content in the structure is explained by an unusual distribution of Zn2+ ions in octahedral sites.Fil: Arana, M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; ArgentinaFil: Jacobo, S. E.. Universidad de Buenos Aires. Facultad de Ingeniería; ArgentinaFil: Bercoff, Paula Gabriela. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; ArgentinaElsevier2013-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8938Arana, M.; Galván Josa, Víctor Martín; Jacobo, S. E.; Bercoff, Paula Gabriela; Cation distribution and magnetic properties of LiMnZn ferrites; Elsevier; Journal Of Alloys And Compounds; 568; 8-2013; 5-100925-8388enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925838813005999info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.jallcom.2013.03.068info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:55:43Zoai:ri.conicet.gov.ar:11336/8938instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:55:43.457CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cation distribution and magnetic properties of LiMnZn ferrites
title Cation distribution and magnetic properties of LiMnZn ferrites
spellingShingle Cation distribution and magnetic properties of LiMnZn ferrites
Arana, M.
Ceramics
Oxide Materials
Crystal Structure
Magnetization
X-Ray Diffraction
title_short Cation distribution and magnetic properties of LiMnZn ferrites
title_full Cation distribution and magnetic properties of LiMnZn ferrites
title_fullStr Cation distribution and magnetic properties of LiMnZn ferrites
title_full_unstemmed Cation distribution and magnetic properties of LiMnZn ferrites
title_sort Cation distribution and magnetic properties of LiMnZn ferrites
dc.creator.none.fl_str_mv Arana, M.
Galván Josa, Víctor Martín
Jacobo, S. E.
Bercoff, Paula Gabriela
author Arana, M.
author_facet Arana, M.
Galván Josa, Víctor Martín
Jacobo, S. E.
Bercoff, Paula Gabriela
author_role author
author2 Galván Josa, Víctor Martín
Jacobo, S. E.
Bercoff, Paula Gabriela
author2_role author
author
author
dc.subject.none.fl_str_mv Ceramics
Oxide Materials
Crystal Structure
Magnetization
X-Ray Diffraction
topic Ceramics
Oxide Materials
Crystal Structure
Magnetization
X-Ray Diffraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Spinel compounds Li0.5xZn0.6xMn0.4Fe2+0.5xO4 (x = 0.0; 0.1; 0.2; 0.4) were produced by the selfcombustion sol–gel method. The obtained powders were calcined at 1000 C for 2 h in Ar atmosphere . The structural and microstructural characteristics of the resulting samples were studied by magnetization measurements, Mössbauer spectroscopy and X-ray powder diffraction in combination with the Rietveld method. Based on magnetization results, a cation distribution model is proposed which is tested with Rietveld refinements and supported by Mössbauer results. The observed increase in saturation magnetization wit h Li content in the structure is explained by an unusual distribution of Zn2+ ions in octahedral sites.
Fil: Arana, M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Galván Josa, Víctor Martín. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
Fil: Jacobo, S. E.. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina
Fil: Bercoff, Paula Gabriela. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina
description Spinel compounds Li0.5xZn0.6xMn0.4Fe2+0.5xO4 (x = 0.0; 0.1; 0.2; 0.4) were produced by the selfcombustion sol–gel method. The obtained powders were calcined at 1000 C for 2 h in Ar atmosphere . The structural and microstructural characteristics of the resulting samples were studied by magnetization measurements, Mössbauer spectroscopy and X-ray powder diffraction in combination with the Rietveld method. Based on magnetization results, a cation distribution model is proposed which is tested with Rietveld refinements and supported by Mössbauer results. The observed increase in saturation magnetization wit h Li content in the structure is explained by an unusual distribution of Zn2+ ions in octahedral sites.
publishDate 2013
dc.date.none.fl_str_mv 2013-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8938
Arana, M.; Galván Josa, Víctor Martín; Jacobo, S. E.; Bercoff, Paula Gabriela; Cation distribution and magnetic properties of LiMnZn ferrites; Elsevier; Journal Of Alloys And Compounds; 568; 8-2013; 5-10
0925-8388
url http://hdl.handle.net/11336/8938
identifier_str_mv Arana, M.; Galván Josa, Víctor Martín; Jacobo, S. E.; Bercoff, Paula Gabriela; Cation distribution and magnetic properties of LiMnZn ferrites; Elsevier; Journal Of Alloys And Compounds; 568; 8-2013; 5-10
0925-8388
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925838813005999
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.jallcom.2013.03.068
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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