Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods

Autores
Alburquenque, D.; Troncoso, L.; Denardin, J.C.; Butera, Alejandro Ricardo; Padmasree, K. D.; Ortiz, J.; Herrera, F.; Marco, J. F.; Gautier, J. L.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we present the structural, magnetic and surface characterization of the ceramic nickel manganite oxide NiMn2O4-δsynthesized by two methods: sol-gel and ultrasound-assisted sol-gel using nitrate salts as precursors. We have characterized the non-stoichiometric samples NiMn2O4-δusing different physicochemical analyses. X-ray diffraction and Rietveld refinement of the X-ray data indicated that the samples crystallize in the Fd3m space group characteristic of cubic spinel-related oxides. The specific surface area of the oxides was 1.3 m2/g (SG) and 16.3 m2/g (UASG). SEM results showed particle agglomerates of 1.05 μm (SG) and 0.85 μm (UASG). Temperature dependence magnetization measurements were performed and a ferrimagnetic transition was identified at 103 K and 105 K depending on the preparation method (SG and UASG, respectively). The observed Curie constant was found to vary from 7.4 to 7.7 cm3 K mol−1and hysteretic magnetization vs. applied field curves at different temperatures were obtained. XPS studies of these oxides reveal the presence of Ni2+, Mn2+, Mn3+and Mn4+ions at the surface. A probable ionic distribution as a function of the synthesis method is proposed.
Fil: Alburquenque, D.. Universidad de Santiago de Chile; Chile
Fil: Troncoso, L.. Universidad de Santiago de Chile; Chile
Fil: Denardin, J.C.. Universidad de Santiago de Chile; Chile
Fil: Butera, Alejandro Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Padmasree, K. D.. Consejo Superior de Investigaciones Científicas; España
Fil: Ortiz, J.. Universidad de Santiago de Chile; Chile
Fil: Herrera, F.. Universidad de Santiago de Chile; Chile
Fil: Marco, J. F.. Consejo Superior de Investigaciones Científicas; España
Fil: Gautier, J. L.. Universidad de Santiago de Chile; Chile
Materia
Magnetic Properties
Nickel Manganite
Spinel Oxides
X-Ray Diffraction
Xps
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/59932
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/59932
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methodsAlburquenque, D.Troncoso, L.Denardin, J.C.Butera, Alejandro RicardoPadmasree, K. D.Ortiz, J.Herrera, F.Marco, J. F.Gautier, J. L.Magnetic PropertiesNickel ManganiteSpinel OxidesX-Ray DiffractionXpshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work we present the structural, magnetic and surface characterization of the ceramic nickel manganite oxide NiMn2O4-δsynthesized by two methods: sol-gel and ultrasound-assisted sol-gel using nitrate salts as precursors. We have characterized the non-stoichiometric samples NiMn2O4-δusing different physicochemical analyses. X-ray diffraction and Rietveld refinement of the X-ray data indicated that the samples crystallize in the Fd3m space group characteristic of cubic spinel-related oxides. The specific surface area of the oxides was 1.3 m2/g (SG) and 16.3 m2/g (UASG). SEM results showed particle agglomerates of 1.05 μm (SG) and 0.85 μm (UASG). Temperature dependence magnetization measurements were performed and a ferrimagnetic transition was identified at 103 K and 105 K depending on the preparation method (SG and UASG, respectively). The observed Curie constant was found to vary from 7.4 to 7.7 cm3 K mol−1and hysteretic magnetization vs. applied field curves at different temperatures were obtained. XPS studies of these oxides reveal the presence of Ni2+, Mn2+, Mn3+and Mn4+ions at the surface. A probable ionic distribution as a function of the synthesis method is proposed.Fil: Alburquenque, D.. Universidad de Santiago de Chile; ChileFil: Troncoso, L.. Universidad de Santiago de Chile; ChileFil: Denardin, J.C.. Universidad de Santiago de Chile; ChileFil: Butera, Alejandro Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Padmasree, K. D.. Consejo Superior de Investigaciones Científicas; EspañaFil: Ortiz, J.. Universidad de Santiago de Chile; ChileFil: Herrera, F.. Universidad de Santiago de Chile; ChileFil: Marco, J. F.. Consejo Superior de Investigaciones Científicas; EspañaFil: Gautier, J. L.. Universidad de Santiago de Chile; ChileElsevier Science Sa2016-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/59932Alburquenque, D.; Troncoso, L.; Denardin, J.C.; Butera, Alejandro Ricardo; Padmasree, K. D.; et al.; Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods; Elsevier Science Sa; Journal of Alloys and Compounds; 672; 2-2016; 307-3160925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2016.02.090info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925838816303590info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:31Zoai:ri.conicet.gov.ar:11336/59932instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:31.479CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
title Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
spellingShingle Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
Alburquenque, D.
Magnetic Properties
Nickel Manganite
Spinel Oxides
X-Ray Diffraction
Xps
title_short Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
title_full Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
title_fullStr Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
title_full_unstemmed Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
title_sort Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods
dc.creator.none.fl_str_mv Alburquenque, D.
Troncoso, L.
Denardin, J.C.
Butera, Alejandro Ricardo
Padmasree, K. D.
Ortiz, J.
Herrera, F.
Marco, J. F.
Gautier, J. L.
author Alburquenque, D.
author_facet Alburquenque, D.
Troncoso, L.
Denardin, J.C.
Butera, Alejandro Ricardo
Padmasree, K. D.
Ortiz, J.
Herrera, F.
Marco, J. F.
Gautier, J. L.
author_role author
author2 Troncoso, L.
Denardin, J.C.
Butera, Alejandro Ricardo
Padmasree, K. D.
Ortiz, J.
Herrera, F.
Marco, J. F.
Gautier, J. L.
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Magnetic Properties
Nickel Manganite
Spinel Oxides
X-Ray Diffraction
Xps
topic Magnetic Properties
Nickel Manganite
Spinel Oxides
X-Ray Diffraction
Xps
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work we present the structural, magnetic and surface characterization of the ceramic nickel manganite oxide NiMn2O4-δsynthesized by two methods: sol-gel and ultrasound-assisted sol-gel using nitrate salts as precursors. We have characterized the non-stoichiometric samples NiMn2O4-δusing different physicochemical analyses. X-ray diffraction and Rietveld refinement of the X-ray data indicated that the samples crystallize in the Fd3m space group characteristic of cubic spinel-related oxides. The specific surface area of the oxides was 1.3 m2/g (SG) and 16.3 m2/g (UASG). SEM results showed particle agglomerates of 1.05 μm (SG) and 0.85 μm (UASG). Temperature dependence magnetization measurements were performed and a ferrimagnetic transition was identified at 103 K and 105 K depending on the preparation method (SG and UASG, respectively). The observed Curie constant was found to vary from 7.4 to 7.7 cm3 K mol−1and hysteretic magnetization vs. applied field curves at different temperatures were obtained. XPS studies of these oxides reveal the presence of Ni2+, Mn2+, Mn3+and Mn4+ions at the surface. A probable ionic distribution as a function of the synthesis method is proposed.
Fil: Alburquenque, D.. Universidad de Santiago de Chile; Chile
Fil: Troncoso, L.. Universidad de Santiago de Chile; Chile
Fil: Denardin, J.C.. Universidad de Santiago de Chile; Chile
Fil: Butera, Alejandro Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Padmasree, K. D.. Consejo Superior de Investigaciones Científicas; España
Fil: Ortiz, J.. Universidad de Santiago de Chile; Chile
Fil: Herrera, F.. Universidad de Santiago de Chile; Chile
Fil: Marco, J. F.. Consejo Superior de Investigaciones Científicas; España
Fil: Gautier, J. L.. Universidad de Santiago de Chile; Chile
description In this work we present the structural, magnetic and surface characterization of the ceramic nickel manganite oxide NiMn2O4-δsynthesized by two methods: sol-gel and ultrasound-assisted sol-gel using nitrate salts as precursors. We have characterized the non-stoichiometric samples NiMn2O4-δusing different physicochemical analyses. X-ray diffraction and Rietveld refinement of the X-ray data indicated that the samples crystallize in the Fd3m space group characteristic of cubic spinel-related oxides. The specific surface area of the oxides was 1.3 m2/g (SG) and 16.3 m2/g (UASG). SEM results showed particle agglomerates of 1.05 μm (SG) and 0.85 μm (UASG). Temperature dependence magnetization measurements were performed and a ferrimagnetic transition was identified at 103 K and 105 K depending on the preparation method (SG and UASG, respectively). The observed Curie constant was found to vary from 7.4 to 7.7 cm3 K mol−1and hysteretic magnetization vs. applied field curves at different temperatures were obtained. XPS studies of these oxides reveal the presence of Ni2+, Mn2+, Mn3+and Mn4+ions at the surface. A probable ionic distribution as a function of the synthesis method is proposed.
publishDate 2016
dc.date.none.fl_str_mv 2016-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/59932
Alburquenque, D.; Troncoso, L.; Denardin, J.C.; Butera, Alejandro Ricardo; Padmasree, K. D.; et al.; Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods; Elsevier Science Sa; Journal of Alloys and Compounds; 672; 2-2016; 307-316
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/59932
identifier_str_mv Alburquenque, D.; Troncoso, L.; Denardin, J.C.; Butera, Alejandro Ricardo; Padmasree, K. D.; et al.; Structural and physicochemical properties of nickel manganite NiMn2O4-δsynthesized by sol-gel and ultra sound assisted methods; Elsevier Science Sa; Journal of Alloys and Compounds; 672; 2-2016; 307-316
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2016.02.090
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925838816303590
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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