Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding

Autores
Iguchi, Daniela; Ohashi, Seishi; Abarro, Ghizelle J. E.; Yin, Xianse; Winroth, Scott; Scott, Chris; Gleydura, Molly; Jin, Lin; Kanagasegar, Nithya; Lo, Cherie; Arza, Carlos R.; Froimowicz, Pablo; Ishida, Hatsuo
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A systematic study has been carried out to develop a material with significant protection properties from galactic cosmic radiation and solar energetic particles. The research focused on the development of hydrogen-rich benzoxazines, which are particularly effective for shielding against such radiation. Newly developed benzoxazine resin can be polymerized at 120 °C, which meets the low-temperature processing requirements for use with ultrahigh molecular weight polyethylene (UHMWPE) fiber, a hydrogen-rich composite reinforcement. This highly reactive benzoxazine resin also exhibits low viscosity and good shelf-life. The structure of the benzoxazine monomer is confirmed by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy. Polymerization behavior and thermal properties are evaluated by differential scanning calorimetry and thermogravimetric analysis. Dynamic mechanical analysis is used to study chemorheological properties of the benzoxazine monomer, rheological properties of the cross-linked polybenzoxazine, and rheological properties of UHMWPE-reinforced polybenzoxazine composites. The theoretical radiation shielding capability of the composite is also evaluated using computer-based simulations.
Fil: Iguchi, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Case Western Reserve University; Estados Unidos
Fil: Ohashi, Seishi. Case Western Reserve University; Estados Unidos
Fil: Abarro, Ghizelle J. E.. University of the Philippines Diliman; Filipinas. Case Western Reserve University; Estados Unidos
Fil: Yin, Xianse. Case Western Reserve University; Estados Unidos. Wuhan Textile University; República de China
Fil: Winroth, Scott. Material Answers LLC; Estados Unidos
Fil: Scott, Chris. Material Answers LLC; Estados Unidos
Fil: Gleydura, Molly. Case Western Reserve University; Estados Unidos. Hathaway Brown School; Estados Unidos
Fil: Jin, Lin. Case Western Reserve University; Estados Unidos
Fil: Kanagasegar, Nithya. Case Western Reserve University; Estados Unidos
Fil: Lo, Cherie. Case Western Reserve University; Estados Unidos
Fil: Arza, Carlos R.. Case Western Reserve University; Estados Unidos
Fil: Froimowicz, Pablo. Case Western Reserve University; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Ishida, Hatsuo. Case Western Reserve University; Estados Unidos
Materia
BENZOXAZINE
POLYBENZOXAZINE
LOW TEMPERATURE POLYMERIZATION
GALACTIC COSMIC RADIATION
SOLAR ENERGETIC PARTICLES
POLYMER MATRIX COMPOSITE
POLYETHYLENE
RADIATION SHIELD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/96104
Acceder
id CONICETDig_a935ab0d1ec64a5347cbd52e13f8a41c
oai_identifier_str oai:ri.conicet.gov.ar:11336/96104
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation ShieldingIguchi, DanielaOhashi, SeishiAbarro, Ghizelle J. E.Yin, XianseWinroth, ScottScott, ChrisGleydura, MollyJin, LinKanagasegar, NithyaLo, CherieArza, Carlos R.Froimowicz, PabloIshida, HatsuoBENZOXAZINEPOLYBENZOXAZINELOW TEMPERATURE POLYMERIZATIONGALACTIC COSMIC RADIATIONSOLAR ENERGETIC PARTICLESPOLYMER MATRIX COMPOSITEPOLYETHYLENERADIATION SHIELDhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A systematic study has been carried out to develop a material with significant protection properties from galactic cosmic radiation and solar energetic particles. The research focused on the development of hydrogen-rich benzoxazines, which are particularly effective for shielding against such radiation. Newly developed benzoxazine resin can be polymerized at 120 °C, which meets the low-temperature processing requirements for use with ultrahigh molecular weight polyethylene (UHMWPE) fiber, a hydrogen-rich composite reinforcement. This highly reactive benzoxazine resin also exhibits low viscosity and good shelf-life. The structure of the benzoxazine monomer is confirmed by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy. Polymerization behavior and thermal properties are evaluated by differential scanning calorimetry and thermogravimetric analysis. Dynamic mechanical analysis is used to study chemorheological properties of the benzoxazine monomer, rheological properties of the cross-linked polybenzoxazine, and rheological properties of UHMWPE-reinforced polybenzoxazine composites. The theoretical radiation shielding capability of the composite is also evaluated using computer-based simulations.Fil: Iguchi, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Case Western Reserve University; Estados UnidosFil: Ohashi, Seishi. Case Western Reserve University; Estados UnidosFil: Abarro, Ghizelle J. E.. University of the Philippines Diliman; Filipinas. Case Western Reserve University; Estados UnidosFil: Yin, Xianse. Case Western Reserve University; Estados Unidos. Wuhan Textile University; República de ChinaFil: Winroth, Scott. Material Answers LLC; Estados UnidosFil: Scott, Chris. Material Answers LLC; Estados UnidosFil: Gleydura, Molly. Case Western Reserve University; Estados Unidos. Hathaway Brown School; Estados UnidosFil: Jin, Lin. Case Western Reserve University; Estados UnidosFil: Kanagasegar, Nithya. Case Western Reserve University; Estados UnidosFil: Lo, Cherie. Case Western Reserve University; Estados UnidosFil: Arza, Carlos R.. Case Western Reserve University; Estados UnidosFil: Froimowicz, Pablo. Case Western Reserve University; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Ishida, Hatsuo. Case Western Reserve University; Estados UnidosAmerican Chemical Society2018-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96104Iguchi, Daniela; Ohashi, Seishi; Abarro, Ghizelle J. E.; Yin, Xianse; Winroth, Scott; et al.; Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding; American Chemical Society; ACS Omega; 3; 9; 9-2018; 11569-115812470-1343CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.8b01297info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.8b01297info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644943/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:06Zoai:ri.conicet.gov.ar:11336/96104instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:06.733CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
title Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
spellingShingle Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
Iguchi, Daniela
BENZOXAZINE
POLYBENZOXAZINE
LOW TEMPERATURE POLYMERIZATION
GALACTIC COSMIC RADIATION
SOLAR ENERGETIC PARTICLES
POLYMER MATRIX COMPOSITE
POLYETHYLENE
RADIATION SHIELD
title_short Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
title_full Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
title_fullStr Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
title_full_unstemmed Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
title_sort Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding
dc.creator.none.fl_str_mv Iguchi, Daniela
Ohashi, Seishi
Abarro, Ghizelle J. E.
Yin, Xianse
Winroth, Scott
Scott, Chris
Gleydura, Molly
Jin, Lin
Kanagasegar, Nithya
Lo, Cherie
Arza, Carlos R.
Froimowicz, Pablo
Ishida, Hatsuo
author Iguchi, Daniela
author_facet Iguchi, Daniela
Ohashi, Seishi
Abarro, Ghizelle J. E.
Yin, Xianse
Winroth, Scott
Scott, Chris
Gleydura, Molly
Jin, Lin
Kanagasegar, Nithya
Lo, Cherie
Arza, Carlos R.
Froimowicz, Pablo
Ishida, Hatsuo
author_role author
author2 Ohashi, Seishi
Abarro, Ghizelle J. E.
Yin, Xianse
Winroth, Scott
Scott, Chris
Gleydura, Molly
Jin, Lin
Kanagasegar, Nithya
Lo, Cherie
Arza, Carlos R.
Froimowicz, Pablo
Ishida, Hatsuo
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BENZOXAZINE
POLYBENZOXAZINE
LOW TEMPERATURE POLYMERIZATION
GALACTIC COSMIC RADIATION
SOLAR ENERGETIC PARTICLES
POLYMER MATRIX COMPOSITE
POLYETHYLENE
RADIATION SHIELD
topic BENZOXAZINE
POLYBENZOXAZINE
LOW TEMPERATURE POLYMERIZATION
GALACTIC COSMIC RADIATION
SOLAR ENERGETIC PARTICLES
POLYMER MATRIX COMPOSITE
POLYETHYLENE
RADIATION SHIELD
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A systematic study has been carried out to develop a material with significant protection properties from galactic cosmic radiation and solar energetic particles. The research focused on the development of hydrogen-rich benzoxazines, which are particularly effective for shielding against such radiation. Newly developed benzoxazine resin can be polymerized at 120 °C, which meets the low-temperature processing requirements for use with ultrahigh molecular weight polyethylene (UHMWPE) fiber, a hydrogen-rich composite reinforcement. This highly reactive benzoxazine resin also exhibits low viscosity and good shelf-life. The structure of the benzoxazine monomer is confirmed by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy. Polymerization behavior and thermal properties are evaluated by differential scanning calorimetry and thermogravimetric analysis. Dynamic mechanical analysis is used to study chemorheological properties of the benzoxazine monomer, rheological properties of the cross-linked polybenzoxazine, and rheological properties of UHMWPE-reinforced polybenzoxazine composites. The theoretical radiation shielding capability of the composite is also evaluated using computer-based simulations.
Fil: Iguchi, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Case Western Reserve University; Estados Unidos
Fil: Ohashi, Seishi. Case Western Reserve University; Estados Unidos
Fil: Abarro, Ghizelle J. E.. University of the Philippines Diliman; Filipinas. Case Western Reserve University; Estados Unidos
Fil: Yin, Xianse. Case Western Reserve University; Estados Unidos. Wuhan Textile University; República de China
Fil: Winroth, Scott. Material Answers LLC; Estados Unidos
Fil: Scott, Chris. Material Answers LLC; Estados Unidos
Fil: Gleydura, Molly. Case Western Reserve University; Estados Unidos. Hathaway Brown School; Estados Unidos
Fil: Jin, Lin. Case Western Reserve University; Estados Unidos
Fil: Kanagasegar, Nithya. Case Western Reserve University; Estados Unidos
Fil: Lo, Cherie. Case Western Reserve University; Estados Unidos
Fil: Arza, Carlos R.. Case Western Reserve University; Estados Unidos
Fil: Froimowicz, Pablo. Case Western Reserve University; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Ishida, Hatsuo. Case Western Reserve University; Estados Unidos
description A systematic study has been carried out to develop a material with significant protection properties from galactic cosmic radiation and solar energetic particles. The research focused on the development of hydrogen-rich benzoxazines, which are particularly effective for shielding against such radiation. Newly developed benzoxazine resin can be polymerized at 120 °C, which meets the low-temperature processing requirements for use with ultrahigh molecular weight polyethylene (UHMWPE) fiber, a hydrogen-rich composite reinforcement. This highly reactive benzoxazine resin also exhibits low viscosity and good shelf-life. The structure of the benzoxazine monomer is confirmed by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy. Polymerization behavior and thermal properties are evaluated by differential scanning calorimetry and thermogravimetric analysis. Dynamic mechanical analysis is used to study chemorheological properties of the benzoxazine monomer, rheological properties of the cross-linked polybenzoxazine, and rheological properties of UHMWPE-reinforced polybenzoxazine composites. The theoretical radiation shielding capability of the composite is also evaluated using computer-based simulations.
publishDate 2018
dc.date.none.fl_str_mv 2018-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/96104
Iguchi, Daniela; Ohashi, Seishi; Abarro, Ghizelle J. E.; Yin, Xianse; Winroth, Scott; et al.; Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding; American Chemical Society; ACS Omega; 3; 9; 9-2018; 11569-11581
2470-1343
CONICET Digital
CONICET
url http://hdl.handle.net/11336/96104
identifier_str_mv Iguchi, Daniela; Ohashi, Seishi; Abarro, Ghizelle J. E.; Yin, Xianse; Winroth, Scott; et al.; Development of Hydrogen-Rich Benzoxazine Resins with Low Polymerization Temperature for Space Radiation Shielding; American Chemical Society; ACS Omega; 3; 9; 9-2018; 11569-11581
2470-1343
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.8b01297
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.8b01297
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644943/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270106702315520
score 13.13397

Publicaciones similares