Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines

Autores
Han, Lu; Zhang, Kan; Ishida, Hatsuo; Froimowicz, Pablo
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pure para and ortho position amide benzoxazines, pHBA-a and oHBA-a, are synthesized. The hydrogen bonding interactions occurring in pHBA-a and oHBA-a are studied by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H NMR) spectroscopy. FT-IR results show that, while pHBA-a presents intermolecular hydrogen bonding interactions, oHBA-a exhibits an intramolecular five-membered-ring hydrogenbonding system between the NH in the amide group and the oxygen in the oxazine ring. Differential scanning calorimetry (DSC) is used to study the thermal properties of the resins and their respective polymers. A deeper understanding of the hydrogen bond interactions in this family of resins is attempted to have better insights on how these systems influence the polymerization behavior not only with respect to the polymerization temperature but also with respect to the propagation step.
Fil: Han, Lu. Case Western Reserve University; Estados Unidos
Fil: Zhang, Kan. Jiangsu University; China
Fil: Ishida, Hatsuo. Case Western Reserve University; Estados Unidos
Fil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Materia
Benzoxazine
Ft-Ir
Hydrogen Bonding
Nmr
Polybenzoxazine
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/49055
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing BenzoxazinesHan, LuZhang, KanIshida, HatsuoFroimowicz, PabloBenzoxazineFt-IrHydrogen BondingNmrPolybenzoxazinehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Pure para and ortho position amide benzoxazines, pHBA-a and oHBA-a, are synthesized. The hydrogen bonding interactions occurring in pHBA-a and oHBA-a are studied by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H NMR) spectroscopy. FT-IR results show that, while pHBA-a presents intermolecular hydrogen bonding interactions, oHBA-a exhibits an intramolecular five-membered-ring hydrogenbonding system between the NH in the amide group and the oxygen in the oxazine ring. Differential scanning calorimetry (DSC) is used to study the thermal properties of the resins and their respective polymers. A deeper understanding of the hydrogen bond interactions in this family of resins is attempted to have better insights on how these systems influence the polymerization behavior not only with respect to the polymerization temperature but also with respect to the propagation step.Fil: Han, Lu. Case Western Reserve University; Estados UnidosFil: Zhang, Kan. Jiangsu University; ChinaFil: Ishida, Hatsuo. Case Western Reserve University; Estados UnidosFil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaWiley VCH Verlag2017-02-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/49055Han, Lu; Zhang, Kan; Ishida, Hatsuo; Froimowicz, Pablo; Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 218; 18; 14-2-2017; 1-10;16005621022-1352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/macp.201600562info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.201600562info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:45Zoai:ri.conicet.gov.ar:11336/49055instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:46.133CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
title Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
spellingShingle Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
Han, Lu
Benzoxazine
Ft-Ir
Hydrogen Bonding
Nmr
Polybenzoxazine
title_short Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
title_full Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
title_fullStr Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
title_full_unstemmed Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
title_sort Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines
dc.creator.none.fl_str_mv Han, Lu
Zhang, Kan
Ishida, Hatsuo
Froimowicz, Pablo
author Han, Lu
author_facet Han, Lu
Zhang, Kan
Ishida, Hatsuo
Froimowicz, Pablo
author_role author
author2 Zhang, Kan
Ishida, Hatsuo
Froimowicz, Pablo
author2_role author
author
author
dc.subject.none.fl_str_mv Benzoxazine
Ft-Ir
Hydrogen Bonding
Nmr
Polybenzoxazine
topic Benzoxazine
Ft-Ir
Hydrogen Bonding
Nmr
Polybenzoxazine
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Pure para and ortho position amide benzoxazines, pHBA-a and oHBA-a, are synthesized. The hydrogen bonding interactions occurring in pHBA-a and oHBA-a are studied by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H NMR) spectroscopy. FT-IR results show that, while pHBA-a presents intermolecular hydrogen bonding interactions, oHBA-a exhibits an intramolecular five-membered-ring hydrogenbonding system between the NH in the amide group and the oxygen in the oxazine ring. Differential scanning calorimetry (DSC) is used to study the thermal properties of the resins and their respective polymers. A deeper understanding of the hydrogen bond interactions in this family of resins is attempted to have better insights on how these systems influence the polymerization behavior not only with respect to the polymerization temperature but also with respect to the propagation step.
Fil: Han, Lu. Case Western Reserve University; Estados Unidos
Fil: Zhang, Kan. Jiangsu University; China
Fil: Ishida, Hatsuo. Case Western Reserve University; Estados Unidos
Fil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
description Pure para and ortho position amide benzoxazines, pHBA-a and oHBA-a, are synthesized. The hydrogen bonding interactions occurring in pHBA-a and oHBA-a are studied by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H NMR) spectroscopy. FT-IR results show that, while pHBA-a presents intermolecular hydrogen bonding interactions, oHBA-a exhibits an intramolecular five-membered-ring hydrogenbonding system between the NH in the amide group and the oxygen in the oxazine ring. Differential scanning calorimetry (DSC) is used to study the thermal properties of the resins and their respective polymers. A deeper understanding of the hydrogen bond interactions in this family of resins is attempted to have better insights on how these systems influence the polymerization behavior not only with respect to the polymerization temperature but also with respect to the propagation step.
publishDate 2017
dc.date.none.fl_str_mv 2017-02-14
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/49055
Han, Lu; Zhang, Kan; Ishida, Hatsuo; Froimowicz, Pablo; Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 218; 18; 14-2-2017; 1-10;1600562
1022-1352
CONICET Digital
CONICET
url http://hdl.handle.net/11336/49055
identifier_str_mv Han, Lu; Zhang, Kan; Ishida, Hatsuo; Froimowicz, Pablo; Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 218; 18; 14-2-2017; 1-10;1600562
1022-1352
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.201600562
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.201600562
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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