3D Nanostructured Conjugated Polymers for Optical Applications

Autores
Dehmel, Raphael; Nicolas, Alexandre; Scherer, Maik R. J.; Steiner, Ullrich
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The self assembly of block-copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4-ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self-assembled morphology into self-supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
Fil: Dehmel, Raphael. University of Cambridge; Reino Unido
Fil: Nicolas, Alexandre. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Cambridge; Reino Unido
Fil: Scherer, Maik R. J.. University of Cambridge; Reino Unido
Fil: Steiner, Ullrich. Adolphe Merkle Institute; Suiza
Materia
Fresnel Zone Plates
Nanostructured Conjugated Polymers
Polymer Self-Assembly
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57814
Acceder
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network_name_str CONICET Digital (CONICET)
spelling 3D Nanostructured Conjugated Polymers for Optical ApplicationsDehmel, RaphaelNicolas, AlexandreScherer, Maik R. J.Steiner, UllrichFresnel Zone PlatesNanostructured Conjugated PolymersPolymer Self-Assemblyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The self assembly of block-copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4-ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self-assembled morphology into self-supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.Fil: Dehmel, Raphael. University of Cambridge; Reino UnidoFil: Nicolas, Alexandre. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Cambridge; Reino UnidoFil: Scherer, Maik R. J.. University of Cambridge; Reino UnidoFil: Steiner, Ullrich. Adolphe Merkle Institute; SuizaWiley VCH Verlag2015-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57814Dehmel, Raphael; Nicolas, Alexandre; Scherer, Maik R. J.; Steiner, Ullrich; 3D Nanostructured Conjugated Polymers for Optical Applications; Wiley VCH Verlag; Advanced Functional Materials; 25; 44; 11-2015; 6900-69051616-301XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/adfm.201502392info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201502392info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:59Zoai:ri.conicet.gov.ar:11336/57814instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:59.387CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv 3D Nanostructured Conjugated Polymers for Optical Applications
title 3D Nanostructured Conjugated Polymers for Optical Applications
spellingShingle 3D Nanostructured Conjugated Polymers for Optical Applications
Dehmel, Raphael
Fresnel Zone Plates
Nanostructured Conjugated Polymers
Polymer Self-Assembly
title_short 3D Nanostructured Conjugated Polymers for Optical Applications
title_full 3D Nanostructured Conjugated Polymers for Optical Applications
title_fullStr 3D Nanostructured Conjugated Polymers for Optical Applications
title_full_unstemmed 3D Nanostructured Conjugated Polymers for Optical Applications
title_sort 3D Nanostructured Conjugated Polymers for Optical Applications
dc.creator.none.fl_str_mv Dehmel, Raphael
Nicolas, Alexandre
Scherer, Maik R. J.
Steiner, Ullrich
author Dehmel, Raphael
author_facet Dehmel, Raphael
Nicolas, Alexandre
Scherer, Maik R. J.
Steiner, Ullrich
author_role author
author2 Nicolas, Alexandre
Scherer, Maik R. J.
Steiner, Ullrich
author2_role author
author
author
dc.subject.none.fl_str_mv Fresnel Zone Plates
Nanostructured Conjugated Polymers
Polymer Self-Assembly
topic Fresnel Zone Plates
Nanostructured Conjugated Polymers
Polymer Self-Assembly
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The self assembly of block-copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4-ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self-assembled morphology into self-supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
Fil: Dehmel, Raphael. University of Cambridge; Reino Unido
Fil: Nicolas, Alexandre. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Cambridge; Reino Unido
Fil: Scherer, Maik R. J.. University of Cambridge; Reino Unido
Fil: Steiner, Ullrich. Adolphe Merkle Institute; Suiza
description The self assembly of block-copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4-ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self-assembled morphology into self-supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
publishDate 2015
dc.date.none.fl_str_mv 2015-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57814
Dehmel, Raphael; Nicolas, Alexandre; Scherer, Maik R. J.; Steiner, Ullrich; 3D Nanostructured Conjugated Polymers for Optical Applications; Wiley VCH Verlag; Advanced Functional Materials; 25; 44; 11-2015; 6900-6905
1616-301X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57814
identifier_str_mv Dehmel, Raphael; Nicolas, Alexandre; Scherer, Maik R. J.; Steiner, Ullrich; 3D Nanostructured Conjugated Polymers for Optical Applications; Wiley VCH Verlag; Advanced Functional Materials; 25; 44; 11-2015; 6900-6905
1616-301X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/adfm.201502392
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201502392
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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