One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction

Autores
Lazzarini, Irene C.; Carrella, Luca; Rentschler, Eva; Alborés, Pablo
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.
Fil: Lazzarini, Irene C.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Carrella, Luca. Johannes Gutenberg Universitat Mainz; Alemania
Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania
Fil: Alborés, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
MAGNETIC PROPERTIES
MANGANESE(III)
ONE DIMENSIONAL CHAIN
SCHIFF BASE
SYMMETRIC H-BOND
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/182486
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/182486
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interactionLazzarini, Irene C.Carrella, LucaRentschler, EvaAlborés, PabloMAGNETIC PROPERTIESMANGANESE(III)ONE DIMENSIONAL CHAINSCHIFF BASESYMMETRIC H-BONDhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.Fil: Lazzarini, Irene C.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Carrella, Luca. Johannes Gutenberg Universitat Mainz; AlemaniaFil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; AlemaniaFil: Alborés, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaElsevier Science SA2016-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/182486Lazzarini, Irene C.; Carrella, Luca; Rentschler, Eva; Alborés, Pablo; One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction; Elsevier Science SA; Inorganica Chimica Acta; 453; 9-2016; 692-6960020-1693CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ica.2016.09.040info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:11:10Zoai:ri.conicet.gov.ar:11336/182486instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:11:11.069CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
spellingShingle One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
Lazzarini, Irene C.
MAGNETIC PROPERTIES
MANGANESE(III)
ONE DIMENSIONAL CHAIN
SCHIFF BASE
SYMMETRIC H-BOND
title_short One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_full One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_fullStr One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_full_unstemmed One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
title_sort One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
dc.creator.none.fl_str_mv Lazzarini, Irene C.
Carrella, Luca
Rentschler, Eva
Alborés, Pablo
author Lazzarini, Irene C.
author_facet Lazzarini, Irene C.
Carrella, Luca
Rentschler, Eva
Alborés, Pablo
author_role author
author2 Carrella, Luca
Rentschler, Eva
Alborés, Pablo
author2_role author
author
author
dc.subject.none.fl_str_mv MAGNETIC PROPERTIES
MANGANESE(III)
ONE DIMENSIONAL CHAIN
SCHIFF BASE
SYMMETRIC H-BOND
topic MAGNETIC PROPERTIES
MANGANESE(III)
ONE DIMENSIONAL CHAIN
SCHIFF BASE
SYMMETRIC H-BOND
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.
Fil: Lazzarini, Irene C.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Carrella, Luca. Johannes Gutenberg Universitat Mainz; Alemania
Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania
Fil: Alborés, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.
publishDate 2016
dc.date.none.fl_str_mv 2016-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/182486
Lazzarini, Irene C.; Carrella, Luca; Rentschler, Eva; Alborés, Pablo; One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction; Elsevier Science SA; Inorganica Chimica Acta; 453; 9-2016; 692-696
0020-1693
CONICET Digital
CONICET
url http://hdl.handle.net/11336/182486
identifier_str_mv Lazzarini, Irene C.; Carrella, Luca; Rentschler, Eva; Alborés, Pablo; One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction; Elsevier Science SA; Inorganica Chimica Acta; 453; 9-2016; 692-696
0020-1693
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ica.2016.09.040
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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