Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks

Autores
García Ubaque, Cesar A.; Moreno Piraján, Juan C.; Giraldo Gutierrez, Liliana; Sapag, Manuel Karim
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper presents the results of the lixiviation of metals from different mixtures of fly and bottom ashes that have been stabilized and solidified in clays used in the manufacture of bricks. The ashes used for this study were obtained from a Hoffmann-type brick furnace adapted for the incineration of municipal solid waste during the manufacturing of ceramic bricks. The ashes were stabilized in clay in different proportions of clay: ash mix (99: 1, 95: 5, 90: 10, 80: 20 and 60: 40). Such mixes were used to manufacture bricks that were calcined at a temperature ranging from 50 to 1100°C. The clay, ashes and manufactured bricks were characterized using X-ray diffraction, fluorescent X-ray, thermogravimetry, differential thermal analysis, atomic absorption spectroscopy and scanning electronic microscopy. In addition, toxicity characteristic leaching procedure lixiviation tests were performed according to the EPA 1311 method for the determination of heavy metals. The results showed an affinity between clay and ash, and also that the bricks manufactured with these mixtures present low lixiviation levels. The tests also showed the highest decrease in the concentration of arsenic, nickel, chromium, zinc and silver for 99: 1 mixtures. The 95: 5 mixture was found to be the most favourable for the stabilization (greater concentration decrease) of lead and cadmium. Selenium was the metal with the lowest concentration change whereas arsenic, nickel, chromium, zinc and cadmium showed the greatest concentration change in all mixtures, with the exception of cadmium in the mixture 99: 1.
Fil: García Ubaque, Cesar A.. Universidad de Los Andes. Facultad de Ingeniería; Colombia
Fil: Moreno Piraján, Juan C.. Universidad de Los Andes. Facultad de Ciencias. Departamento de Química. Grupo de Investigación en Sólidos Porosos y Calorimetría; Colombia
Fil: Giraldo Gutierrez, Liliana. Universidad Nacional de Colombia. Facultad de Ciencias. Departamento de Química; Colombia
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Materia
ASHES
CLAY
LIXIVIATION
STABILIZATION
WASTE INCINERATION
WMR 1055-5
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/117256
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/117256
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricksGarcía Ubaque, Cesar A.Moreno Piraján, Juan C.Giraldo Gutierrez, LilianaSapag, Manuel KarimASHESCLAYLIXIVIATIONSTABILIZATIONWASTE INCINERATIONWMR 1055-5https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This paper presents the results of the lixiviation of metals from different mixtures of fly and bottom ashes that have been stabilized and solidified in clays used in the manufacture of bricks. The ashes used for this study were obtained from a Hoffmann-type brick furnace adapted for the incineration of municipal solid waste during the manufacturing of ceramic bricks. The ashes were stabilized in clay in different proportions of clay: ash mix (99: 1, 95: 5, 90: 10, 80: 20 and 60: 40). Such mixes were used to manufacture bricks that were calcined at a temperature ranging from 50 to 1100°C. The clay, ashes and manufactured bricks were characterized using X-ray diffraction, fluorescent X-ray, thermogravimetry, differential thermal analysis, atomic absorption spectroscopy and scanning electronic microscopy. In addition, toxicity characteristic leaching procedure lixiviation tests were performed according to the EPA 1311 method for the determination of heavy metals. The results showed an affinity between clay and ash, and also that the bricks manufactured with these mixtures present low lixiviation levels. The tests also showed the highest decrease in the concentration of arsenic, nickel, chromium, zinc and silver for 99: 1 mixtures. The 95: 5 mixture was found to be the most favourable for the stabilization (greater concentration decrease) of lead and cadmium. Selenium was the metal with the lowest concentration change whereas arsenic, nickel, chromium, zinc and cadmium showed the greatest concentration change in all mixtures, with the exception of cadmium in the mixture 99: 1.Fil: García Ubaque, Cesar A.. Universidad de Los Andes. Facultad de Ingeniería; ColombiaFil: Moreno Piraján, Juan C.. Universidad de Los Andes. Facultad de Ciencias. Departamento de Química. Grupo de Investigación en Sólidos Porosos y Calorimetría; ColombiaFil: Giraldo Gutierrez, Liliana. Universidad Nacional de Colombia. Facultad de Ciencias. Departamento de Química; ColombiaFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaSage Publications Ltd2007-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/117256García Ubaque, Cesar A.; Moreno Piraján, Juan C.; Giraldo Gutierrez, Liliana; Sapag, Manuel Karim; Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks; Sage Publications Ltd; Waste Management & Research; 25; 4; 12-2007; 352-3620734-242XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1177/0734242X07077820info:eu-repo/semantics/altIdentifier/url/https://journals.sagepub.com/doi/abs/10.1177/0734242X07077820info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:52Zoai:ri.conicet.gov.ar:11336/117256instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:53.214CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
title Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
spellingShingle Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
García Ubaque, Cesar A.
ASHES
CLAY
LIXIVIATION
STABILIZATION
WASTE INCINERATION
WMR 1055-5
title_short Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
title_full Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
title_fullStr Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
title_full_unstemmed Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
title_sort Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks
dc.creator.none.fl_str_mv García Ubaque, Cesar A.
Moreno Piraján, Juan C.
Giraldo Gutierrez, Liliana
Sapag, Manuel Karim
author García Ubaque, Cesar A.
author_facet García Ubaque, Cesar A.
Moreno Piraján, Juan C.
Giraldo Gutierrez, Liliana
Sapag, Manuel Karim
author_role author
author2 Moreno Piraján, Juan C.
Giraldo Gutierrez, Liliana
Sapag, Manuel Karim
author2_role author
author
author
dc.subject.none.fl_str_mv ASHES
CLAY
LIXIVIATION
STABILIZATION
WASTE INCINERATION
WMR 1055-5
topic ASHES
CLAY
LIXIVIATION
STABILIZATION
WASTE INCINERATION
WMR 1055-5
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This paper presents the results of the lixiviation of metals from different mixtures of fly and bottom ashes that have been stabilized and solidified in clays used in the manufacture of bricks. The ashes used for this study were obtained from a Hoffmann-type brick furnace adapted for the incineration of municipal solid waste during the manufacturing of ceramic bricks. The ashes were stabilized in clay in different proportions of clay: ash mix (99: 1, 95: 5, 90: 10, 80: 20 and 60: 40). Such mixes were used to manufacture bricks that were calcined at a temperature ranging from 50 to 1100°C. The clay, ashes and manufactured bricks were characterized using X-ray diffraction, fluorescent X-ray, thermogravimetry, differential thermal analysis, atomic absorption spectroscopy and scanning electronic microscopy. In addition, toxicity characteristic leaching procedure lixiviation tests were performed according to the EPA 1311 method for the determination of heavy metals. The results showed an affinity between clay and ash, and also that the bricks manufactured with these mixtures present low lixiviation levels. The tests also showed the highest decrease in the concentration of arsenic, nickel, chromium, zinc and silver for 99: 1 mixtures. The 95: 5 mixture was found to be the most favourable for the stabilization (greater concentration decrease) of lead and cadmium. Selenium was the metal with the lowest concentration change whereas arsenic, nickel, chromium, zinc and cadmium showed the greatest concentration change in all mixtures, with the exception of cadmium in the mixture 99: 1.
Fil: García Ubaque, Cesar A.. Universidad de Los Andes. Facultad de Ingeniería; Colombia
Fil: Moreno Piraján, Juan C.. Universidad de Los Andes. Facultad de Ciencias. Departamento de Química. Grupo de Investigación en Sólidos Porosos y Calorimetría; Colombia
Fil: Giraldo Gutierrez, Liliana. Universidad Nacional de Colombia. Facultad de Ciencias. Departamento de Química; Colombia
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
description This paper presents the results of the lixiviation of metals from different mixtures of fly and bottom ashes that have been stabilized and solidified in clays used in the manufacture of bricks. The ashes used for this study were obtained from a Hoffmann-type brick furnace adapted for the incineration of municipal solid waste during the manufacturing of ceramic bricks. The ashes were stabilized in clay in different proportions of clay: ash mix (99: 1, 95: 5, 90: 10, 80: 20 and 60: 40). Such mixes were used to manufacture bricks that were calcined at a temperature ranging from 50 to 1100°C. The clay, ashes and manufactured bricks were characterized using X-ray diffraction, fluorescent X-ray, thermogravimetry, differential thermal analysis, atomic absorption spectroscopy and scanning electronic microscopy. In addition, toxicity characteristic leaching procedure lixiviation tests were performed according to the EPA 1311 method for the determination of heavy metals. The results showed an affinity between clay and ash, and also that the bricks manufactured with these mixtures present low lixiviation levels. The tests also showed the highest decrease in the concentration of arsenic, nickel, chromium, zinc and silver for 99: 1 mixtures. The 95: 5 mixture was found to be the most favourable for the stabilization (greater concentration decrease) of lead and cadmium. Selenium was the metal with the lowest concentration change whereas arsenic, nickel, chromium, zinc and cadmium showed the greatest concentration change in all mixtures, with the exception of cadmium in the mixture 99: 1.
publishDate 2007
dc.date.none.fl_str_mv 2007-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/117256
García Ubaque, Cesar A.; Moreno Piraján, Juan C.; Giraldo Gutierrez, Liliana; Sapag, Manuel Karim; Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks; Sage Publications Ltd; Waste Management & Research; 25; 4; 12-2007; 352-362
0734-242X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/117256
identifier_str_mv García Ubaque, Cesar A.; Moreno Piraján, Juan C.; Giraldo Gutierrez, Liliana; Sapag, Manuel Karim; Stabilization/solidification of ashes in clays used in the manufacturing of ceramic bricks; Sage Publications Ltd; Waste Management & Research; 25; 4; 12-2007; 352-362
0734-242X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1177/0734242X07077820
info:eu-repo/semantics/altIdentifier/url/https://journals.sagepub.com/doi/abs/10.1177/0734242X07077820
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sage Publications Ltd
publisher.none.fl_str_mv Sage Publications Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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