Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination

Autores
Muñoz De La Peña, Arsenio; Mujumdar, Nirvani; Heider, Emily C.; Goicoechea, Hector Casimiro; Muñoz De La Peña, David; Campiglia, Andres D.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The potential of total excitation-emission fluorescence microscopy combined with multiway chemometric analysis was investigated for the nondestructive forensic analysis of textile fibers. The four pairs of visually indistinguishable fibers consisted of nylon 361 dyed with acid yellow 17 and acid yellow 23, acetate satin 105B dyed with disperse blue 3 and disperse blue 14, polyester 777 dyed with disperse red 1 and disperse red 19, and acrylic 864 dyed with basic green 1 and basic green 4. Excitation emission matrices were recorded with the aid of an inverted microscope and a commercial spectrofluorimeter. The full information content of excitation-emission matrices was processed with the aid of unsupervised parallel factor analysis (PARAFAC), PARAFAC supervised by linear discriminant analysis (LDA), and discriminant unfolded partial least-squares (DU-PLS). The ability of the latter algorithm to classify the four pairs of fibers demonstrates the advantage of using the multidimensionality of fluorescence data formats for the nondestructive analysis of forensic fiber evidence.
Fil: Muñoz De La Peña, Arsenio. University of Central Florida; Estados Unidos. Universidad de Extremadura; España
Fil: Mujumdar, Nirvani. University of Central Florida; Estados Unidos
Fil: Heider, Emily C.. University of Central Florida; Estados Unidos
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Muñoz De La Peña, David. Universidad de Sevilla; España
Fil: Campiglia, Andres D.. University of Central Florida; Estados Unidos
Materia
Pca
Du-Pls
Lda
Parafac
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/56004
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber DiscriminationMuñoz De La Peña, ArsenioMujumdar, NirvaniHeider, Emily C.Goicoechea, Hector CasimiroMuñoz De La Peña, DavidCampiglia, Andres D.PcaDu-PlsLdaParafachttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The potential of total excitation-emission fluorescence microscopy combined with multiway chemometric analysis was investigated for the nondestructive forensic analysis of textile fibers. The four pairs of visually indistinguishable fibers consisted of nylon 361 dyed with acid yellow 17 and acid yellow 23, acetate satin 105B dyed with disperse blue 3 and disperse blue 14, polyester 777 dyed with disperse red 1 and disperse red 19, and acrylic 864 dyed with basic green 1 and basic green 4. Excitation emission matrices were recorded with the aid of an inverted microscope and a commercial spectrofluorimeter. The full information content of excitation-emission matrices was processed with the aid of unsupervised parallel factor analysis (PARAFAC), PARAFAC supervised by linear discriminant analysis (LDA), and discriminant unfolded partial least-squares (DU-PLS). The ability of the latter algorithm to classify the four pairs of fibers demonstrates the advantage of using the multidimensionality of fluorescence data formats for the nondestructive analysis of forensic fiber evidence.Fil: Muñoz De La Peña, Arsenio. University of Central Florida; Estados Unidos. Universidad de Extremadura; EspañaFil: Mujumdar, Nirvani. University of Central Florida; Estados UnidosFil: Heider, Emily C.. University of Central Florida; Estados UnidosFil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; ArgentinaFil: Muñoz De La Peña, David. Universidad de Sevilla; EspañaFil: Campiglia, Andres D.. University of Central Florida; Estados UnidosAmerican Chemical Society2016-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/56004Muñoz De La Peña, Arsenio; Mujumdar, Nirvani; Heider, Emily C.; Goicoechea, Hector Casimiro; Muñoz De La Peña, David; et al.; Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination; American Chemical Society; Analytical Chemistry; 88; 5; 3-2016; 2967-29750003-2700CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.analchem.6b00264info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.analchem.6b00264info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:12:40Zoai:ri.conicet.gov.ar:11336/56004instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:12:40.504CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
title Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
spellingShingle Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
Muñoz De La Peña, Arsenio
Pca
Du-Pls
Lda
Parafac
title_short Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
title_full Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
title_fullStr Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
title_full_unstemmed Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
title_sort Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination
dc.creator.none.fl_str_mv Muñoz De La Peña, Arsenio
Mujumdar, Nirvani
Heider, Emily C.
Goicoechea, Hector Casimiro
Muñoz De La Peña, David
Campiglia, Andres D.
author Muñoz De La Peña, Arsenio
author_facet Muñoz De La Peña, Arsenio
Mujumdar, Nirvani
Heider, Emily C.
Goicoechea, Hector Casimiro
Muñoz De La Peña, David
Campiglia, Andres D.
author_role author
author2 Mujumdar, Nirvani
Heider, Emily C.
Goicoechea, Hector Casimiro
Muñoz De La Peña, David
Campiglia, Andres D.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Pca
Du-Pls
Lda
Parafac
topic Pca
Du-Pls
Lda
Parafac
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The potential of total excitation-emission fluorescence microscopy combined with multiway chemometric analysis was investigated for the nondestructive forensic analysis of textile fibers. The four pairs of visually indistinguishable fibers consisted of nylon 361 dyed with acid yellow 17 and acid yellow 23, acetate satin 105B dyed with disperse blue 3 and disperse blue 14, polyester 777 dyed with disperse red 1 and disperse red 19, and acrylic 864 dyed with basic green 1 and basic green 4. Excitation emission matrices were recorded with the aid of an inverted microscope and a commercial spectrofluorimeter. The full information content of excitation-emission matrices was processed with the aid of unsupervised parallel factor analysis (PARAFAC), PARAFAC supervised by linear discriminant analysis (LDA), and discriminant unfolded partial least-squares (DU-PLS). The ability of the latter algorithm to classify the four pairs of fibers demonstrates the advantage of using the multidimensionality of fluorescence data formats for the nondestructive analysis of forensic fiber evidence.
Fil: Muñoz De La Peña, Arsenio. University of Central Florida; Estados Unidos. Universidad de Extremadura; España
Fil: Mujumdar, Nirvani. University of Central Florida; Estados Unidos
Fil: Heider, Emily C.. University of Central Florida; Estados Unidos
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Muñoz De La Peña, David. Universidad de Sevilla; España
Fil: Campiglia, Andres D.. University of Central Florida; Estados Unidos
description The potential of total excitation-emission fluorescence microscopy combined with multiway chemometric analysis was investigated for the nondestructive forensic analysis of textile fibers. The four pairs of visually indistinguishable fibers consisted of nylon 361 dyed with acid yellow 17 and acid yellow 23, acetate satin 105B dyed with disperse blue 3 and disperse blue 14, polyester 777 dyed with disperse red 1 and disperse red 19, and acrylic 864 dyed with basic green 1 and basic green 4. Excitation emission matrices were recorded with the aid of an inverted microscope and a commercial spectrofluorimeter. The full information content of excitation-emission matrices was processed with the aid of unsupervised parallel factor analysis (PARAFAC), PARAFAC supervised by linear discriminant analysis (LDA), and discriminant unfolded partial least-squares (DU-PLS). The ability of the latter algorithm to classify the four pairs of fibers demonstrates the advantage of using the multidimensionality of fluorescence data formats for the nondestructive analysis of forensic fiber evidence.
publishDate 2016
dc.date.none.fl_str_mv 2016-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/56004
Muñoz De La Peña, Arsenio; Mujumdar, Nirvani; Heider, Emily C.; Goicoechea, Hector Casimiro; Muñoz De La Peña, David; et al.; Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination; American Chemical Society; Analytical Chemistry; 88; 5; 3-2016; 2967-2975
0003-2700
CONICET Digital
CONICET
url http://hdl.handle.net/11336/56004
identifier_str_mv Muñoz De La Peña, Arsenio; Mujumdar, Nirvani; Heider, Emily C.; Goicoechea, Hector Casimiro; Muñoz De La Peña, David; et al.; Nondestructive Total Excitation-Emission Fluorescence Microscopy Combined with Multi-Way Chemometric Analysis for Visually Indistinguishable Single Fiber Discrimination; American Chemical Society; Analytical Chemistry; 88; 5; 3-2016; 2967-2975
0003-2700
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.analchem.6b00264
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.analchem.6b00264
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083274800103424
score 13.22299

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