Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc

Autores
Franco Arias, Lina Maria; Kleiman, Ariel Javier; Vega, Daniel Alberto; Fazio, Mariana Andrea; Halac, Eduardo; Marquez, Adriana Beatriz
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The rutile phase of TiO2 has raised a wide interest for biomaterial applications. Since rutile is generally synthesized at high temperatures, a deposition process based on a cathodic arc discharge has been investigated in order to obtain rutile coatings at lower temperature on stainless steel substrates. In this work, TiO2 films were deposited on AISI 316 L stainless steel substrates heated at 300 and 400 °C with a negative bias of 120 V, employing Ti interlayers of different thicknesses. TiO2 films of approximately 500 and 900 nm were grown on Ti interlayers with thicknesses in the range 0–550 nm. The effect of Ti interlayers on the crystalline structure of TiO2 coatings was systematically studied with X-ray diffraction and Raman spectroscopy. The introduction of the Ti layer increased the rutile/anatase proportion either at 300 or 400 °C, turning rutile into the main phase in the TiO2 film. The largest amount of rutile for both temperatures was attained with a 55 nm Ti interlayer, the thinnest thickness studied.
Fil: Franco Arias, Lina Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Kleiman, Ariel Javier. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Fazio, Mariana Andrea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina
Fil: Halac, Eduardo. Departamento Física de la Materia Condensada; Argentina
Fil: Marquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Materia
Austenitic Stainless Steel
Cathodic Arc
Rutile
Titanium Dioxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57650
Acceder
id CONICETDig_9386ade24efd4f856453edc1864f33da
oai_identifier_str oai:ri.conicet.gov.ar:11336/57650
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arcFranco Arias, Lina MariaKleiman, Ariel JavierVega, Daniel AlbertoFazio, Mariana AndreaHalac, EduardoMarquez, Adriana BeatrizAustenitic Stainless SteelCathodic ArcRutileTitanium Dioxidehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The rutile phase of TiO2 has raised a wide interest for biomaterial applications. Since rutile is generally synthesized at high temperatures, a deposition process based on a cathodic arc discharge has been investigated in order to obtain rutile coatings at lower temperature on stainless steel substrates. In this work, TiO2 films were deposited on AISI 316 L stainless steel substrates heated at 300 and 400 °C with a negative bias of 120 V, employing Ti interlayers of different thicknesses. TiO2 films of approximately 500 and 900 nm were grown on Ti interlayers with thicknesses in the range 0–550 nm. The effect of Ti interlayers on the crystalline structure of TiO2 coatings was systematically studied with X-ray diffraction and Raman spectroscopy. The introduction of the Ti layer increased the rutile/anatase proportion either at 300 or 400 °C, turning rutile into the main phase in the TiO2 film. The largest amount of rutile for both temperatures was attained with a 55 nm Ti interlayer, the thinnest thickness studied.Fil: Franco Arias, Lina Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; ArgentinaFil: Kleiman, Ariel Javier. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; ArgentinaFil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; ArgentinaFil: Fazio, Mariana Andrea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; ArgentinaFil: Halac, Eduardo. Departamento Física de la Materia Condensada; ArgentinaFil: Marquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; ArgentinaElsevier Science Sa2017-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57650Franco Arias, Lina Maria; Kleiman, Ariel Javier; Vega, Daniel Alberto; Fazio, Mariana Andrea; Halac, Eduardo; et al.; Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc; Elsevier Science Sa; Thin Solid Films; 638; 7-2017; 269-2760040-6090CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0040609017305412info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tsf.2017.07.047info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:34Zoai:ri.conicet.gov.ar:11336/57650instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:46:34.821CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
title Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
spellingShingle Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
Franco Arias, Lina Maria
Austenitic Stainless Steel
Cathodic Arc
Rutile
Titanium Dioxide
title_short Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
title_full Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
title_fullStr Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
title_full_unstemmed Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
title_sort Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc
dc.creator.none.fl_str_mv Franco Arias, Lina Maria
Kleiman, Ariel Javier
Vega, Daniel Alberto
Fazio, Mariana Andrea
Halac, Eduardo
Marquez, Adriana Beatriz
author Franco Arias, Lina Maria
author_facet Franco Arias, Lina Maria
Kleiman, Ariel Javier
Vega, Daniel Alberto
Fazio, Mariana Andrea
Halac, Eduardo
Marquez, Adriana Beatriz
author_role author
author2 Kleiman, Ariel Javier
Vega, Daniel Alberto
Fazio, Mariana Andrea
Halac, Eduardo
Marquez, Adriana Beatriz
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Austenitic Stainless Steel
Cathodic Arc
Rutile
Titanium Dioxide
topic Austenitic Stainless Steel
Cathodic Arc
Rutile
Titanium Dioxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The rutile phase of TiO2 has raised a wide interest for biomaterial applications. Since rutile is generally synthesized at high temperatures, a deposition process based on a cathodic arc discharge has been investigated in order to obtain rutile coatings at lower temperature on stainless steel substrates. In this work, TiO2 films were deposited on AISI 316 L stainless steel substrates heated at 300 and 400 °C with a negative bias of 120 V, employing Ti interlayers of different thicknesses. TiO2 films of approximately 500 and 900 nm were grown on Ti interlayers with thicknesses in the range 0–550 nm. The effect of Ti interlayers on the crystalline structure of TiO2 coatings was systematically studied with X-ray diffraction and Raman spectroscopy. The introduction of the Ti layer increased the rutile/anatase proportion either at 300 or 400 °C, turning rutile into the main phase in the TiO2 film. The largest amount of rutile for both temperatures was attained with a 55 nm Ti interlayer, the thinnest thickness studied.
Fil: Franco Arias, Lina Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Kleiman, Ariel Javier. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Vega, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
Fil: Fazio, Mariana Andrea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina
Fil: Halac, Eduardo. Departamento Física de la Materia Condensada; Argentina
Fil: Marquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física del Plasma. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física del Plasma; Argentina
description The rutile phase of TiO2 has raised a wide interest for biomaterial applications. Since rutile is generally synthesized at high temperatures, a deposition process based on a cathodic arc discharge has been investigated in order to obtain rutile coatings at lower temperature on stainless steel substrates. In this work, TiO2 films were deposited on AISI 316 L stainless steel substrates heated at 300 and 400 °C with a negative bias of 120 V, employing Ti interlayers of different thicknesses. TiO2 films of approximately 500 and 900 nm were grown on Ti interlayers with thicknesses in the range 0–550 nm. The effect of Ti interlayers on the crystalline structure of TiO2 coatings was systematically studied with X-ray diffraction and Raman spectroscopy. The introduction of the Ti layer increased the rutile/anatase proportion either at 300 or 400 °C, turning rutile into the main phase in the TiO2 film. The largest amount of rutile for both temperatures was attained with a 55 nm Ti interlayer, the thinnest thickness studied.
publishDate 2017
dc.date.none.fl_str_mv 2017-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57650
Franco Arias, Lina Maria; Kleiman, Ariel Javier; Vega, Daniel Alberto; Fazio, Mariana Andrea; Halac, Eduardo; et al.; Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc; Elsevier Science Sa; Thin Solid Films; 638; 7-2017; 269-276
0040-6090
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57650
identifier_str_mv Franco Arias, Lina Maria; Kleiman, Ariel Javier; Vega, Daniel Alberto; Fazio, Mariana Andrea; Halac, Eduardo; et al.; Enhancement of rutile phase formation in TiO2 films deposited on stainless steel substrates with a vacuum arc; Elsevier Science Sa; Thin Solid Films; 638; 7-2017; 269-276
0040-6090
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0040609017305412
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tsf.2017.07.047
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268803786866688
score 13.13397

Publicaciones similares