The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate

Autores
Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
(Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Faccio, Ricardo. Universidad de la República; Uruguay
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay
Materia
Cobre complexes
Thiosaccharinates
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
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Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/188820
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinateDennehy, MarianaQuinzani, Oscar ValentínFaccio, RicardoFreire Espeleta, EleonoraMombru, Alvaro W.Cobre complexesThiosaccharinateshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1(Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Faccio, Ricardo. Universidad de la República; UruguayFil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mombru, Alvaro W.. Universidad de la República; UruguayWiley Blackwell Publishing, Inc2011-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/188820Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-160108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111052036info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111052036info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:05:42Zoai:ri.conicet.gov.ar:11336/188820instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:05:42.692CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
title The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
spellingShingle The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
Dennehy, Mariana
Cobre complexes
Thiosaccharinates
title_short The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
title_full The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
title_fullStr The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
title_full_unstemmed The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
title_sort The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
dc.creator.none.fl_str_mv Dennehy, Mariana
Quinzani, Oscar Valentín
Faccio, Ricardo
Freire Espeleta, Eleonora
Mombru, Alvaro W.
author Dennehy, Mariana
author_facet Dennehy, Mariana
Quinzani, Oscar Valentín
Faccio, Ricardo
Freire Espeleta, Eleonora
Mombru, Alvaro W.
author_role author
author2 Quinzani, Oscar Valentín
Faccio, Ricardo
Freire Espeleta, Eleonora
Mombru, Alvaro W.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Cobre complexes
Thiosaccharinates
topic Cobre complexes
Thiosaccharinates
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv (Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Faccio, Ricardo. Universidad de la República; Uruguay
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay
description (Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.
publishDate 2011
dc.date.none.fl_str_mv 2011-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/188820
Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-16
0108-2701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/188820
identifier_str_mv Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-16
0108-2701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111052036
info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111052036
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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