The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate
- Autores
- Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- (Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Faccio, Ricardo. Universidad de la República; Uruguay
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay - Materia
-
Cobre complexes
Thiosaccharinates - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/188820
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The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinateDennehy, MarianaQuinzani, Oscar ValentínFaccio, RicardoFreire Espeleta, EleonoraMombru, Alvaro W.Cobre complexesThiosaccharinateshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1(Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å.Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Faccio, Ricardo. Universidad de la República; UruguayFil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mombru, Alvaro W.. Universidad de la República; UruguayWiley Blackwell Publishing, Inc2011-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/188820Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-160108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111052036info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111052036info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:33Zoai:ri.conicet.gov.ar:11336/188820instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:33.535CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
title |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
spellingShingle |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate Dennehy, Mariana Cobre complexes Thiosaccharinates |
title_short |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
title_full |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
title_fullStr |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
title_full_unstemmed |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
title_sort |
The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate |
dc.creator.none.fl_str_mv |
Dennehy, Mariana Quinzani, Oscar Valentín Faccio, Ricardo Freire Espeleta, Eleonora Mombru, Alvaro W. |
author |
Dennehy, Mariana |
author_facet |
Dennehy, Mariana Quinzani, Oscar Valentín Faccio, Ricardo Freire Espeleta, Eleonora Mombru, Alvaro W. |
author_role |
author |
author2 |
Quinzani, Oscar Valentín Faccio, Ricardo Freire Espeleta, Eleonora Mombru, Alvaro W. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Cobre complexes Thiosaccharinates |
topic |
Cobre complexes Thiosaccharinates |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
(Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å. Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Faccio, Ricardo. Universidad de la República; Uruguay Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay |
description |
(Acetonitrile-1N)[-1H-benzimidazole-2(3H)-thione-1:2 2 S:S][1H-benzimidazole-2(3H)-thione-2S]bis-(-1,1-dioxo-1 6,2-benzothia- zole-3-thiol-ato)-1:2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S) 2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thio-saccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu - Cu unit. In the complex mol-ecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridges via the endocyclic N and exocyclic S atoms (-S:N). The other anion and one of the mercaptobenzimidazole mol-ecules bridge the metals through their exocyclic S atoms (-S:S). The second Sbim ligand coordinates in a monodentate fashion (S) to one Cu atom, while an acetonitrile mol-ecule coordinates to the other Cu atom. The Cu I - Cu I distance [2.6286 (6) Å] can be considered a strong cuprophilic inter-action. In the case of [-1H-benzimidazole-2(3H)-thione-1:2 2 S:S]bis-[1H-benzimidazole-2(3H)- thione]-1S;2S-bis-(-1,1-dioxo-1 6,2-benzo-thia-zole-3-thiol-ato)-1: 2 2 S 3:N;1:2 2 S 3:S 3-dicopper(I)(Cu - Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile mol-ecule is substituted by an additional Sbim ligand, which binds one Cu atom via the exocylic S atom. In this case, the Cu I - Cu I distance is 2.6068 (11) Å. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/188820 Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-16 0108-2701 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/188820 |
identifier_str_mv |
Dennehy, Mariana; Quinzani, Oscar Valentín; Faccio, Ricardo; Freire Espeleta, Eleonora; Mombru, Alvaro W.; The conformations of two copper(I) complexes of 1H-benzimidazole- 2(3H)-thione and thiosaccharinate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 68; 1; 12-2011; 12-16 0108-2701 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111052036 info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111052036 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
publisher.none.fl_str_mv |
Wiley Blackwell Publishing, Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613183466110976 |
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13.070432 |