A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions

Autores
Dennehy, Mariana; Delgado, Fermin; Freire Espeleta, Eleonora; Halac, Emilia Beatriz; Baggio, Ricardo Fortunato
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Silver(I) complexes with sulfur-donor ligands have a broad range of pharma­cological applications. One of the most important factors for tuning the biological activity is the type of donor atom and the ease of ligand replacement. Silver thio­saccharinates display a wide range of structures from mono- to polynuclear complexes. We report the synthesis, crystal structure and vibrational spectroscopic analysis of a two-dimensional AgI-thio­saccharinate coordination polymer, namely poly[tris­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')bis­([mu]3-1,1-dioxo-1,2-benz­iso­thia­zole-3-thiol­ato-[kappa]3N:S3:S3)bis­([mu]2-1,1-dioxo-1,2-benziso­thia­zole-3-thiol­ato-[kappa]2S3:S3)tetra­silver(I)], [Ag2(C7H4NO2S2)2(C10H8N2)1.5]n, with 4,4'-bi­pyridine acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag separation of 2.8859 (10) Å, well within the range of argentophilic inter­actions and confirmed as such by Raman analysis of the low-frequency spectrum. From a topological point of view, the structure presents inter­penetration in the form of a threefold entangled 2D[rightwards arrow]2D mesh (2D is two-dimensional).
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Delgado, Fermin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Materia
TWO-DIMENSIONAL SILVER(I) COORDINATION POLYMER
2D-2D INTERPENETRATION
THIOSACCHARINATE
ARGENTOPHILIC INTERACTION
CRYSTAL STRUCTURE
TOPOLOGICAL ANALYSIS
RAMAN
TWINNING
ENTANGLED MESH
VIBRATIONAL SPECTROSCOPY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/46449
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/46449
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactionsDennehy, MarianaDelgado, FerminFreire Espeleta, EleonoraHalac, Emilia BeatrizBaggio, Ricardo FortunatoTWO-DIMENSIONAL SILVER(I) COORDINATION POLYMER2D-2D INTERPENETRATIONTHIOSACCHARINATEARGENTOPHILIC INTERACTIONCRYSTAL STRUCTURETOPOLOGICAL ANALYSISRAMANTWINNINGENTANGLED MESHVIBRATIONAL SPECTROSCOPYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Silver(I) complexes with sulfur-donor ligands have a broad range of pharma­cological applications. One of the most important factors for tuning the biological activity is the type of donor atom and the ease of ligand replacement. Silver thio­saccharinates display a wide range of structures from mono- to polynuclear complexes. We report the synthesis, crystal structure and vibrational spectroscopic analysis of a two-dimensional AgI-thio­saccharinate coordination polymer, namely poly[tris­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')bis­([mu]3-1,1-dioxo-1,2-benz­iso­thia­zole-3-thiol­ato-[kappa]3N:S3:S3)bis­([mu]2-1,1-dioxo-1,2-benziso­thia­zole-3-thiol­ato-[kappa]2S3:S3)tetra­silver(I)], [Ag2(C7H4NO2S2)2(C10H8N2)1.5]n, with 4,4'-bi­pyridine acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag separation of 2.8859 (10) Å, well within the range of argentophilic inter­actions and confirmed as such by Raman analysis of the low-frequency spectrum. From a topological point of view, the structure presents inter­penetration in the form of a threefold entangled 2D[rightwards arrow]2D mesh (2D is two-dimensional).Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Delgado, Fermin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaWiley Blackwell Publishing, Inc2016-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/46449Dennehy, Mariana; Delgado, Fermin; Freire Espeleta, Eleonora; Halac, Emilia Beatriz; Baggio, Ricardo Fortunato; A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C Structural Chemistry; 72; 7; 6-2016; 572-5772053-2296CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229616009645info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229616009645info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:54Zoai:ri.conicet.gov.ar:11336/46449instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:54.546CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
title A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
spellingShingle A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
Dennehy, Mariana
TWO-DIMENSIONAL SILVER(I) COORDINATION POLYMER
2D-2D INTERPENETRATION
THIOSACCHARINATE
ARGENTOPHILIC INTERACTION
CRYSTAL STRUCTURE
TOPOLOGICAL ANALYSIS
RAMAN
TWINNING
ENTANGLED MESH
VIBRATIONAL SPECTROSCOPY
title_short A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
title_full A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
title_fullStr A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
title_full_unstemmed A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
title_sort A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions
dc.creator.none.fl_str_mv Dennehy, Mariana
Delgado, Fermin
Freire Espeleta, Eleonora
Halac, Emilia Beatriz
Baggio, Ricardo Fortunato
author Dennehy, Mariana
author_facet Dennehy, Mariana
Delgado, Fermin
Freire Espeleta, Eleonora
Halac, Emilia Beatriz
Baggio, Ricardo Fortunato
author_role author
author2 Delgado, Fermin
Freire Espeleta, Eleonora
Halac, Emilia Beatriz
Baggio, Ricardo Fortunato
author2_role author
author
author
author
dc.subject.none.fl_str_mv TWO-DIMENSIONAL SILVER(I) COORDINATION POLYMER
2D-2D INTERPENETRATION
THIOSACCHARINATE
ARGENTOPHILIC INTERACTION
CRYSTAL STRUCTURE
TOPOLOGICAL ANALYSIS
RAMAN
TWINNING
ENTANGLED MESH
VIBRATIONAL SPECTROSCOPY
topic TWO-DIMENSIONAL SILVER(I) COORDINATION POLYMER
2D-2D INTERPENETRATION
THIOSACCHARINATE
ARGENTOPHILIC INTERACTION
CRYSTAL STRUCTURE
TOPOLOGICAL ANALYSIS
RAMAN
TWINNING
ENTANGLED MESH
VIBRATIONAL SPECTROSCOPY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Silver(I) complexes with sulfur-donor ligands have a broad range of pharma­cological applications. One of the most important factors for tuning the biological activity is the type of donor atom and the ease of ligand replacement. Silver thio­saccharinates display a wide range of structures from mono- to polynuclear complexes. We report the synthesis, crystal structure and vibrational spectroscopic analysis of a two-dimensional AgI-thio­saccharinate coordination polymer, namely poly[tris­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')bis­([mu]3-1,1-dioxo-1,2-benz­iso­thia­zole-3-thiol­ato-[kappa]3N:S3:S3)bis­([mu]2-1,1-dioxo-1,2-benziso­thia­zole-3-thiol­ato-[kappa]2S3:S3)tetra­silver(I)], [Ag2(C7H4NO2S2)2(C10H8N2)1.5]n, with 4,4'-bi­pyridine acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag separation of 2.8859 (10) Å, well within the range of argentophilic inter­actions and confirmed as such by Raman analysis of the low-frequency spectrum. From a topological point of view, the structure presents inter­penetration in the form of a threefold entangled 2D[rightwards arrow]2D mesh (2D is two-dimensional).
Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Delgado, Fermin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Halac, Emilia Beatriz. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description Silver(I) complexes with sulfur-donor ligands have a broad range of pharma­cological applications. One of the most important factors for tuning the biological activity is the type of donor atom and the ease of ligand replacement. Silver thio­saccharinates display a wide range of structures from mono- to polynuclear complexes. We report the synthesis, crystal structure and vibrational spectroscopic analysis of a two-dimensional AgI-thio­saccharinate coordination polymer, namely poly[tris­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')bis­([mu]3-1,1-dioxo-1,2-benz­iso­thia­zole-3-thiol­ato-[kappa]3N:S3:S3)bis­([mu]2-1,1-dioxo-1,2-benziso­thia­zole-3-thiol­ato-[kappa]2S3:S3)tetra­silver(I)], [Ag2(C7H4NO2S2)2(C10H8N2)1.5]n, with 4,4'-bi­pyridine acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag separation of 2.8859 (10) Å, well within the range of argentophilic inter­actions and confirmed as such by Raman analysis of the low-frequency spectrum. From a topological point of view, the structure presents inter­penetration in the form of a threefold entangled 2D[rightwards arrow]2D mesh (2D is two-dimensional).
publishDate 2016
dc.date.none.fl_str_mv 2016-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/46449
Dennehy, Mariana; Delgado, Fermin; Freire Espeleta, Eleonora; Halac, Emilia Beatriz; Baggio, Ricardo Fortunato; A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C Structural Chemistry; 72; 7; 6-2016; 572-577
2053-2296
CONICET Digital
CONICET
url http://hdl.handle.net/11336/46449
identifier_str_mv Dennehy, Mariana; Delgado, Fermin; Freire Espeleta, Eleonora; Halac, Emilia Beatriz; Baggio, Ricardo Fortunato; A polymeric silver thiosaccarinate complex with a two-dimensional triply entangled mesh and argentophilic interactions; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C Structural Chemistry; 72; 7; 6-2016; 572-577
2053-2296
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229616009645
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229616009645
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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