Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems

Autores
Talagañis, Basilio Andres; Castro, Facundo; Baruj, Alberto Leonardo; Meyer, Gabriel Omar
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Hydrogen storage materials can form more than one hydride phase. These different phases, in turn, display different hydrogen absorption/desorption capacities, kinetics, and stabilities. Studies aimed at characterizing and improving these materials usually need to correlate hydrogen intake with the precise determination of the hydride phase involved in the process. Here, we present a device designed to perform measurements of well known volumetric techniques with simultaneous x-ray diffraction on the material under study. The compact design can stand up to 6000 kPa of internal pressure while the sample can be heated up to 450 °C. The design process was assisted by finite element modeling and by the use of mock-up prototypes in order to optimize the thermal and under load behaviors. We provide two examples of use for this new device: (1) hydride decomposition in LaNi5 at 115 °C and (2) formation of MgCo during the programmed thermal desorption of the Mg2 CoH5 hydride.
Fil: Talagañis, Basilio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Fil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baruj, Alberto Leonardo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Meyer, Gabriel Omar. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
hydride
reactor chamber
thermal desorption spectroscopy
hydrogen storage
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70279
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/70279
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systemsTalagañis, Basilio AndresCastro, FacundoBaruj, Alberto LeonardoMeyer, Gabriel Omarhydridereactor chamberthermal desorption spectroscopyhydrogen storagehttps://purl.org/becyt/ford/2.3https://purl.org/becyt/ford/2Hydrogen storage materials can form more than one hydride phase. These different phases, in turn, display different hydrogen absorption/desorption capacities, kinetics, and stabilities. Studies aimed at characterizing and improving these materials usually need to correlate hydrogen intake with the precise determination of the hydride phase involved in the process. Here, we present a device designed to perform measurements of well known volumetric techniques with simultaneous x-ray diffraction on the material under study. The compact design can stand up to 6000 kPa of internal pressure while the sample can be heated up to 450 °C. The design process was assisted by finite element modeling and by the use of mock-up prototypes in order to optimize the thermal and under load behaviors. We provide two examples of use for this new device: (1) hydride decomposition in LaNi5 at 115 °C and (2) formation of MgCo during the programmed thermal desorption of the Mg2 CoH5 hydride.Fil: Talagañis, Basilio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; ArgentinaFil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Baruj, Alberto Leonardo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Meyer, Gabriel Omar. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Institute of Physics2009-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70279Talagañis, Basilio Andres; Castro, Facundo; Baruj, Alberto Leonardo; Meyer, Gabriel Omar; Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems; American Institute of Physics; Review of Scientific Instruments; 80; 7; 7-20090034-6748CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://rsi.aip.orginfo:eu-repo/semantics/altIdentifier/doi/10.1063/1.3157086info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:40:01Zoai:ri.conicet.gov.ar:11336/70279instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:40:01.9CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
title Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
spellingShingle Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
Talagañis, Basilio Andres
hydride
reactor chamber
thermal desorption spectroscopy
hydrogen storage
title_short Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
title_full Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
title_fullStr Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
title_full_unstemmed Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
title_sort Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems
dc.creator.none.fl_str_mv Talagañis, Basilio Andres
Castro, Facundo
Baruj, Alberto Leonardo
Meyer, Gabriel Omar
author Talagañis, Basilio Andres
author_facet Talagañis, Basilio Andres
Castro, Facundo
Baruj, Alberto Leonardo
Meyer, Gabriel Omar
author_role author
author2 Castro, Facundo
Baruj, Alberto Leonardo
Meyer, Gabriel Omar
author2_role author
author
author
dc.subject.none.fl_str_mv hydride
reactor chamber
thermal desorption spectroscopy
hydrogen storage
topic hydride
reactor chamber
thermal desorption spectroscopy
hydrogen storage
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.3
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Hydrogen storage materials can form more than one hydride phase. These different phases, in turn, display different hydrogen absorption/desorption capacities, kinetics, and stabilities. Studies aimed at characterizing and improving these materials usually need to correlate hydrogen intake with the precise determination of the hydride phase involved in the process. Here, we present a device designed to perform measurements of well known volumetric techniques with simultaneous x-ray diffraction on the material under study. The compact design can stand up to 6000 kPa of internal pressure while the sample can be heated up to 450 °C. The design process was assisted by finite element modeling and by the use of mock-up prototypes in order to optimize the thermal and under load behaviors. We provide two examples of use for this new device: (1) hydride decomposition in LaNi5 at 115 °C and (2) formation of MgCo during the programmed thermal desorption of the Mg2 CoH5 hydride.
Fil: Talagañis, Basilio Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo y Diseño. Universidad Tecnológica Nacional. Facultad Regional Santa Fe. Instituto de Desarrollo y Diseño; Argentina
Fil: Castro, Facundo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baruj, Alberto Leonardo. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Meyer, Gabriel Omar. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Hydrogen storage materials can form more than one hydride phase. These different phases, in turn, display different hydrogen absorption/desorption capacities, kinetics, and stabilities. Studies aimed at characterizing and improving these materials usually need to correlate hydrogen intake with the precise determination of the hydride phase involved in the process. Here, we present a device designed to perform measurements of well known volumetric techniques with simultaneous x-ray diffraction on the material under study. The compact design can stand up to 6000 kPa of internal pressure while the sample can be heated up to 450 °C. The design process was assisted by finite element modeling and by the use of mock-up prototypes in order to optimize the thermal and under load behaviors. We provide two examples of use for this new device: (1) hydride decomposition in LaNi5 at 115 °C and (2) formation of MgCo during the programmed thermal desorption of the Mg2 CoH5 hydride.
publishDate 2009
dc.date.none.fl_str_mv 2009-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70279
Talagañis, Basilio Andres; Castro, Facundo; Baruj, Alberto Leonardo; Meyer, Gabriel Omar; Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems; American Institute of Physics; Review of Scientific Instruments; 80; 7; 7-2009
0034-6748
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70279
identifier_str_mv Talagañis, Basilio Andres; Castro, Facundo; Baruj, Alberto Leonardo; Meyer, Gabriel Omar; Novel device for simultaneous volumetric and x-ray diffraction measurements on metal-hydrogen systems; American Institute of Physics; Review of Scientific Instruments; 80; 7; 7-2009
0034-6748
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://rsi.aip.org
info:eu-repo/semantics/altIdentifier/doi/10.1063/1.3157086
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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