A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan

Autores
Zelin, Juan; Meyer, Camilo Ignacio; Duarte, Hernán Antonio; Marchi, Alberto Julio
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF is obtained from renewable sources, and BHMF is a raw material used for production of biodegradable polymers. Four copper-based catalysts were prepared by incipient wetness impregnation (Cu/SiO2-I, Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and coprecipitation (CuMgAl), and then tested in the liquid-phase hydrogenation of HMF. Metallic phases with large copper particles were obtained by incipient wetness impregnation, while precipitation methods gave highly dispersed metal copper nanoparticles. The pattern found for the concentration and strength of surface acid sites was: CuMgAl > Cu/Al2O3-I > Cu/SiO2-PD > Cu/SiO2-I. The copper-based catalysts active in HMF hydrogenation are all highly selective to BHMF, but the intrinsic activity and stability depend on metallic copper dispersion and support nature. The catalyst stability becomes poorer in the cases that the metallic phase is formed by large copper particles or interacts with high-acidity supports. Therefore, the catalyst with the highest activity, BHMF yield and stability was Cu/SiO2-PD. Furthermore, it was found that Cu/SiO2-PD is reusable in the selective liquid-phase HMF hydrogenation after being submitted to a two-step thermal treatment: (1) calcination under air flow at 673 K; (2) reduction under H2 flow at 523 K.
Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Duarte, Hernán Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
COPPER CATALYST
HYDROGENATION
5-HYDROXYMETHYLFURFURAL
2,5-BIS(HYDROXYMETHYL)FURANO
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/210616
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/210616
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furanZelin, JuanMeyer, Camilo IgnacioDuarte, Hernán AntonioMarchi, Alberto JulioCOPPER CATALYSTHYDROGENATION5-HYDROXYMETHYLFURFURAL2,5-BIS(HYDROXYMETHYL)FURANOhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF is obtained from renewable sources, and BHMF is a raw material used for production of biodegradable polymers. Four copper-based catalysts were prepared by incipient wetness impregnation (Cu/SiO2-I, Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and coprecipitation (CuMgAl), and then tested in the liquid-phase hydrogenation of HMF. Metallic phases with large copper particles were obtained by incipient wetness impregnation, while precipitation methods gave highly dispersed metal copper nanoparticles. The pattern found for the concentration and strength of surface acid sites was: CuMgAl > Cu/Al2O3-I > Cu/SiO2-PD > Cu/SiO2-I. The copper-based catalysts active in HMF hydrogenation are all highly selective to BHMF, but the intrinsic activity and stability depend on metallic copper dispersion and support nature. The catalyst stability becomes poorer in the cases that the metallic phase is formed by large copper particles or interacts with high-acidity supports. Therefore, the catalyst with the highest activity, BHMF yield and stability was Cu/SiO2-PD. Furthermore, it was found that Cu/SiO2-PD is reusable in the selective liquid-phase HMF hydrogenation after being submitted to a two-step thermal treatment: (1) calcination under air flow at 673 K; (2) reduction under H2 flow at 523 K.Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Duarte, Hernán Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaMDPI2022-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/210616Zelin, Juan; Meyer, Camilo Ignacio; Duarte, Hernán Antonio; Marchi, Alberto Julio; A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan; MDPI; Catalysts; 12; 11; 11-2022; 1-202073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/12/11/1476info:eu-repo/semantics/altIdentifier/doi/10.3390/catal12111476info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:19:42Zoai:ri.conicet.gov.ar:11336/210616instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:19:43.051CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
title A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
spellingShingle A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
Zelin, Juan
COPPER CATALYST
HYDROGENATION
5-HYDROXYMETHYLFURFURAL
2,5-BIS(HYDROXYMETHYL)FURANO
title_short A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
title_full A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
title_fullStr A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
title_full_unstemmed A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
title_sort A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan
dc.creator.none.fl_str_mv Zelin, Juan
Meyer, Camilo Ignacio
Duarte, Hernán Antonio
Marchi, Alberto Julio
author Zelin, Juan
author_facet Zelin, Juan
Meyer, Camilo Ignacio
Duarte, Hernán Antonio
Marchi, Alberto Julio
author_role author
author2 Meyer, Camilo Ignacio
Duarte, Hernán Antonio
Marchi, Alberto Julio
author2_role author
author
author
dc.subject.none.fl_str_mv COPPER CATALYST
HYDROGENATION
5-HYDROXYMETHYLFURFURAL
2,5-BIS(HYDROXYMETHYL)FURANO
topic COPPER CATALYST
HYDROGENATION
5-HYDROXYMETHYLFURFURAL
2,5-BIS(HYDROXYMETHYL)FURANO
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF is obtained from renewable sources, and BHMF is a raw material used for production of biodegradable polymers. Four copper-based catalysts were prepared by incipient wetness impregnation (Cu/SiO2-I, Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and coprecipitation (CuMgAl), and then tested in the liquid-phase hydrogenation of HMF. Metallic phases with large copper particles were obtained by incipient wetness impregnation, while precipitation methods gave highly dispersed metal copper nanoparticles. The pattern found for the concentration and strength of surface acid sites was: CuMgAl > Cu/Al2O3-I > Cu/SiO2-PD > Cu/SiO2-I. The copper-based catalysts active in HMF hydrogenation are all highly selective to BHMF, but the intrinsic activity and stability depend on metallic copper dispersion and support nature. The catalyst stability becomes poorer in the cases that the metallic phase is formed by large copper particles or interacts with high-acidity supports. Therefore, the catalyst with the highest activity, BHMF yield and stability was Cu/SiO2-PD. Furthermore, it was found that Cu/SiO2-PD is reusable in the selective liquid-phase HMF hydrogenation after being submitted to a two-step thermal treatment: (1) calcination under air flow at 673 K; (2) reduction under H2 flow at 523 K.
Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Duarte, Hernán Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF is obtained from renewable sources, and BHMF is a raw material used for production of biodegradable polymers. Four copper-based catalysts were prepared by incipient wetness impregnation (Cu/SiO2-I, Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and coprecipitation (CuMgAl), and then tested in the liquid-phase hydrogenation of HMF. Metallic phases with large copper particles were obtained by incipient wetness impregnation, while precipitation methods gave highly dispersed metal copper nanoparticles. The pattern found for the concentration and strength of surface acid sites was: CuMgAl > Cu/Al2O3-I > Cu/SiO2-PD > Cu/SiO2-I. The copper-based catalysts active in HMF hydrogenation are all highly selective to BHMF, but the intrinsic activity and stability depend on metallic copper dispersion and support nature. The catalyst stability becomes poorer in the cases that the metallic phase is formed by large copper particles or interacts with high-acidity supports. Therefore, the catalyst with the highest activity, BHMF yield and stability was Cu/SiO2-PD. Furthermore, it was found that Cu/SiO2-PD is reusable in the selective liquid-phase HMF hydrogenation after being submitted to a two-step thermal treatment: (1) calcination under air flow at 673 K; (2) reduction under H2 flow at 523 K.
publishDate 2022
dc.date.none.fl_str_mv 2022-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/210616
Zelin, Juan; Meyer, Camilo Ignacio; Duarte, Hernán Antonio; Marchi, Alberto Julio; A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan; MDPI; Catalysts; 12; 11; 11-2022; 1-20
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/210616
identifier_str_mv Zelin, Juan; Meyer, Camilo Ignacio; Duarte, Hernán Antonio; Marchi, Alberto Julio; A Stable and Reusable Supported Copper Catalyst for the Selective Liquid-Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan; MDPI; Catalysts; 12; 11; 11-2022; 1-20
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/12/11/1476
info:eu-repo/semantics/altIdentifier/doi/10.3390/catal12111476
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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