Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions

Autores
Martínez Zambrano, José Jobanny; Silva, David F.; Aguilera, Edna X.; Rojas, Hugo A.; Brijaldo, María H.; Passos, Fabio B.; Romanelli, Gustavo Pablo
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The dehydration of fructose and glucose to 5-hydroxymethylfurfural was studied using LaOCl/Nb2O5 in hot compressed water conditions. The catalysts were prepared by impregnation of LaCl3 on Nb2O5 with different loadings. The solids were characterized by EDX, XRD, TGA and N2 physisorption at 77 K and pyridine and CO2 adsorption followed by FTIR; the strength of acidity and basicity was determined by NH3- TPD and CO2- TPD, respectively. The use of acid–base systems for HMF production mainly from glucose requires weak basic sites and moderate acidity condition that is reached with LaOCl/ Nb2O5 as was confirmed by acidity and basicity analyses. The presence of Nb2O5 increase HMF yield (>50%) and prevented the formation of undesirable products in hot compressed water conditions, similar results could be obtained with DMSO.
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Materia
Química
5-Hydroxymethylfurfural
LaOCl/Nb2O5
Glucose
Acid–basic solids
Hot compressed water
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/104794
Acceder
id SEDICI_cfa24288b9a3c4a516053d9b48cab604
oai_identifier_str oai:sedici.unlp.edu.ar:10915/104794
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water ConditionsMartínez Zambrano, José JobannySilva, David F.Aguilera, Edna X.Rojas, Hugo A.Brijaldo, María H.Passos, Fabio B.Romanelli, Gustavo PabloQuímica5-HydroxymethylfurfuralLaOCl/Nb2O5GlucoseAcid–basic solidsHot compressed waterThe dehydration of fructose and glucose to 5-hydroxymethylfurfural was studied using LaOCl/Nb2O5 in hot compressed water conditions. The catalysts were prepared by impregnation of LaCl3 on Nb2O5 with different loadings. The solids were characterized by EDX, XRD, TGA and N2 physisorption at 77 K and pyridine and CO2 adsorption followed by FTIR; the strength of acidity and basicity was determined by NH3- TPD and CO2- TPD, respectively. The use of acid–base systems for HMF production mainly from glucose requires weak basic sites and moderate acidity condition that is reached with LaOCl/ Nb2O5 as was confirmed by acidity and basicity analyses. The presence of Nb2O5 increase HMF yield (>50%) and prevented the formation of undesirable products in hot compressed water conditions, similar results could be obtained with DMSO.Centro de Investigación y Desarrollo en Ciencias Aplicadas2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1765-1774http://sedici.unlp.edu.ar/handle/10915/104794enginfo:eu-repo/semantics/altIdentifier/issn/1572-879Xinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-017-2064-yinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:22:57Zoai:sedici.unlp.edu.ar:10915/104794Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:22:57.997SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
title Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
spellingShingle Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
Martínez Zambrano, José Jobanny
Química
5-Hydroxymethylfurfural
LaOCl/Nb2O5
Glucose
Acid–basic solids
Hot compressed water
title_short Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
title_full Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
title_fullStr Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
title_full_unstemmed Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
title_sort Dehydration of Glucose to 5-Hydroxymethylfurfural Using LaOCl/Nb2O5 Catalysts in Hot Compressed Water Conditions
dc.creator.none.fl_str_mv Martínez Zambrano, José Jobanny
Silva, David F.
Aguilera, Edna X.
Rojas, Hugo A.
Brijaldo, María H.
Passos, Fabio B.
Romanelli, Gustavo Pablo
author Martínez Zambrano, José Jobanny
author_facet Martínez Zambrano, José Jobanny
Silva, David F.
Aguilera, Edna X.
Rojas, Hugo A.
Brijaldo, María H.
Passos, Fabio B.
Romanelli, Gustavo Pablo
author_role author
author2 Silva, David F.
Aguilera, Edna X.
Rojas, Hugo A.
Brijaldo, María H.
Passos, Fabio B.
Romanelli, Gustavo Pablo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Química
5-Hydroxymethylfurfural
LaOCl/Nb2O5
Glucose
Acid–basic solids
Hot compressed water
topic Química
5-Hydroxymethylfurfural
LaOCl/Nb2O5
Glucose
Acid–basic solids
Hot compressed water
dc.description.none.fl_txt_mv The dehydration of fructose and glucose to 5-hydroxymethylfurfural was studied using LaOCl/Nb2O5 in hot compressed water conditions. The catalysts were prepared by impregnation of LaCl3 on Nb2O5 with different loadings. The solids were characterized by EDX, XRD, TGA and N2 physisorption at 77 K and pyridine and CO2 adsorption followed by FTIR; the strength of acidity and basicity was determined by NH3- TPD and CO2- TPD, respectively. The use of acid–base systems for HMF production mainly from glucose requires weak basic sites and moderate acidity condition that is reached with LaOCl/ Nb2O5 as was confirmed by acidity and basicity analyses. The presence of Nb2O5 increase HMF yield (>50%) and prevented the formation of undesirable products in hot compressed water conditions, similar results could be obtained with DMSO.
Centro de Investigación y Desarrollo en Ciencias Aplicadas
description The dehydration of fructose and glucose to 5-hydroxymethylfurfural was studied using LaOCl/Nb2O5 in hot compressed water conditions. The catalysts were prepared by impregnation of LaCl3 on Nb2O5 with different loadings. The solids were characterized by EDX, XRD, TGA and N2 physisorption at 77 K and pyridine and CO2 adsorption followed by FTIR; the strength of acidity and basicity was determined by NH3- TPD and CO2- TPD, respectively. The use of acid–base systems for HMF production mainly from glucose requires weak basic sites and moderate acidity condition that is reached with LaOCl/ Nb2O5 as was confirmed by acidity and basicity analyses. The presence of Nb2O5 increase HMF yield (>50%) and prevented the formation of undesirable products in hot compressed water conditions, similar results could be obtained with DMSO.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/104794
url http://sedici.unlp.edu.ar/handle/10915/104794
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1572-879X
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-017-2064-y
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
1765-1774
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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