Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor

Autores
Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Monolithic Stirrer Reactor
Mathematical Modeling
Kinetics
Mass Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/25553
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/25553
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactorBoldrini, Diego EmmanuelDamiani, Daniel EduardoTonetto, Gabriela MartaMonolithic Stirrer ReactorMathematical ModelingKineticsMass Transferhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditionsFil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaJohn Wiley & Sons Inc2014-07-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25553Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-35330001-15411547-5905CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/aic.14539info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/aic.14539/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:27Zoai:ri.conicet.gov.ar:11336/25553instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:27.31CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
title Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
spellingShingle Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
Boldrini, Diego Emmanuel
Monolithic Stirrer Reactor
Mathematical Modeling
Kinetics
Mass Transfer
title_short Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
title_full Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
title_fullStr Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
title_full_unstemmed Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
title_sort Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
dc.creator.none.fl_str_mv Boldrini, Diego Emmanuel
Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author Boldrini, Diego Emmanuel
author_facet Boldrini, Diego Emmanuel
Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author_role author
author2 Damiani, Daniel Eduardo
Tonetto, Gabriela Marta
author2_role author
author
dc.subject.none.fl_str_mv Monolithic Stirrer Reactor
Mathematical Modeling
Kinetics
Mass Transfer
topic Monolithic Stirrer Reactor
Mathematical Modeling
Kinetics
Mass Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions
publishDate 2014
dc.date.none.fl_str_mv 2014-07-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/25553
Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-3533
0001-1541
1547-5905
CONICET Digital
CONICET
url http://hdl.handle.net/11336/25553
identifier_str_mv Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-3533
0001-1541
1547-5905
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/aic.14539
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/aic.14539/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613609057943552
score 13.069144

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