Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor
- Autores
- Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions
Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina - Materia
-
Monolithic Stirrer Reactor
Mathematical Modeling
Kinetics
Mass Transfer - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/25553
Ver los metadatos del registro completo
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Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactorBoldrini, Diego EmmanuelDamiani, Daniel EduardoTonetto, Gabriela MartaMonolithic Stirrer ReactorMathematical ModelingKineticsMass Transferhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditionsFil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaJohn Wiley & Sons Inc2014-07-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25553Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-35330001-15411547-5905CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/aic.14539info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/aic.14539/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:22Zoai:ri.conicet.gov.ar:11336/25553instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:22.554CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
title |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
spellingShingle |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor Boldrini, Diego Emmanuel Monolithic Stirrer Reactor Mathematical Modeling Kinetics Mass Transfer |
title_short |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
title_full |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
title_fullStr |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
title_full_unstemmed |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
title_sort |
Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor |
dc.creator.none.fl_str_mv |
Boldrini, Diego Emmanuel Damiani, Daniel Eduardo Tonetto, Gabriela Marta |
author |
Boldrini, Diego Emmanuel |
author_facet |
Boldrini, Diego Emmanuel Damiani, Daniel Eduardo Tonetto, Gabriela Marta |
author_role |
author |
author2 |
Damiani, Daniel Eduardo Tonetto, Gabriela Marta |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Monolithic Stirrer Reactor Mathematical Modeling Kinetics Mass Transfer |
topic |
Monolithic Stirrer Reactor Mathematical Modeling Kinetics Mass Transfer |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina |
description |
Experimental and theoretical studies on the partial hydrogenation of vegetable oil in a monolithic stirrer reactor are reported. A complete mathematical model of the reactor was developed, including hydrogenation and isomerization kinetics, catalyst deactivation, external gas–liquid and liquid–solid as well as internal mass transfer. The experimental studies were carried out in a Pd/Al2O3/Al monolithic stirrer reactor, at a wide range of temperatures (353–373 K), pressures (414–552 kPa), and catalyst loadings (0.00084–0.00527 kgPd,exp m-3 ). Based on this model, simulated data can be used to evaluate the catalyst (Pd/Al2O3/Al) and the hydrogenation process in consecutive catalytic tests under different operating conditions |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-07-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/25553 Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-3533 0001-1541 1547-5905 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/25553 |
identifier_str_mv |
Boldrini, Diego Emmanuel; Damiani, Daniel Eduardo; Tonetto, Gabriela Marta; Mathematical modeling of the partial hydrogenation of vegetable oil in a monolithic stirrer reactor; John Wiley & Sons Inc; Aiche Journal; 60; 10; 2-7-2014; 3524-3533 0001-1541 1547-5905 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/aic.14539 info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/aic.14539/abstract |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons Inc |
publisher.none.fl_str_mv |
John Wiley & Sons Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269220221485056 |
score |
13.13397 |