“Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment

Autores
Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Ramos, Cinthia Paula; Haure, Patricia Monica; Cassanello Fernandez, Miryam Celeste; Ayude, María Alejandra
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the synthesis procedure of supported Prussian blue nanoparticles (PBNP) on their activity and stability as a Fenton-type catalyst is studied. Hence, two catalysts are synthesized by adsorbing onto a support of PBNP formed ex situ through the reaction between FeCl3 and K3Fe(CN)6 using H2O2 as reducing agent, and following different washing protocols. A third catalyst is prepared through a two-step impregnation process with FeCl3 and K4[Fe(CN)6] aqueous solutions. The catalysts are tested in the orange G Fenton-type oxidation. The fresh and used catalysts are characterized by BET surface area, SEM, EDS, TEM, Mössbauer spectroscopy, total iron content and UV-vis spectrophotometry. It is demonstrated that under the synthesis conditions employed, the “insoluble” form of Prussian blue is promoted in the ex situ procedure, whereas the two-step impregnation process leads to the “soluble” Prussian blue formation. The washing of the just-prepared catalysts at the reaction temperature helps in eliminating the unreacted species. Those catalysts based on “insoluble” Prussian blue nanoparticles exhibit better behaviour in terms of stability. Significant removals are attained (100% azo dye, 60% TOC), at pH = 3, 343 K after thirteen successive cycles of 300 min. The best catalyst displays the smallest amount of total “free” Fe leached without releasing PBNP, ferrocyanide or ferricyanide ions into the reaction media. Reversible adsorption–desorption of organic intermediates avoids the loss of activity due to blockage of sites and/or pores.
Fil: Doumic, Lucila Inés. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina
Fil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cassanello Fernandez, Miryam Celeste. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Prussian Blue
Fenton-Like
Orange G
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/33376
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatmentDoumic, Lucila InésSalierno, Gabriel LeonardoRamos, Cinthia PaulaHaure, Patricia MonicaCassanello Fernandez, Miryam CelesteAyude, María AlejandraPrussian BlueFenton-LikeOrange Ghttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the synthesis procedure of supported Prussian blue nanoparticles (PBNP) on their activity and stability as a Fenton-type catalyst is studied. Hence, two catalysts are synthesized by adsorbing onto a support of PBNP formed ex situ through the reaction between FeCl3 and K3Fe(CN)6 using H2O2 as reducing agent, and following different washing protocols. A third catalyst is prepared through a two-step impregnation process with FeCl3 and K4[Fe(CN)6] aqueous solutions. The catalysts are tested in the orange G Fenton-type oxidation. The fresh and used catalysts are characterized by BET surface area, SEM, EDS, TEM, Mössbauer spectroscopy, total iron content and UV-vis spectrophotometry. It is demonstrated that under the synthesis conditions employed, the “insoluble” form of Prussian blue is promoted in the ex situ procedure, whereas the two-step impregnation process leads to the “soluble” Prussian blue formation. The washing of the just-prepared catalysts at the reaction temperature helps in eliminating the unreacted species. Those catalysts based on “insoluble” Prussian blue nanoparticles exhibit better behaviour in terms of stability. Significant removals are attained (100% azo dye, 60% TOC), at pH = 3, 343 K after thirteen successive cycles of 300 min. The best catalyst displays the smallest amount of total “free” Fe leached without releasing PBNP, ferrocyanide or ferricyanide ions into the reaction media. Reversible adsorption–desorption of organic intermediates avoids the loss of activity due to blockage of sites and/or pores.Fil: Doumic, Lucila Inés. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); ArgentinaFil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cassanello Fernandez, Miryam Celeste. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaRoyal Society of Chemistry2016-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/33376Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Ramos, Cinthia Paula; Haure, Patricia Monica; Cassanello Fernandez, Miryam Celeste; et al.; “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment; Royal Society of Chemistry; RSC Advances; 6; 52; 5-2016; 46625-466332046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/C6RA06618Finfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra06618f#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:51:09Zoai:ri.conicet.gov.ar:11336/33376instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:51:09.688CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
title “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
spellingShingle “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
Doumic, Lucila Inés
Prussian Blue
Fenton-Like
Orange G
title_short “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
title_full “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
title_fullStr “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
title_full_unstemmed “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
title_sort “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment
dc.creator.none.fl_str_mv Doumic, Lucila Inés
Salierno, Gabriel Leonardo
Ramos, Cinthia Paula
Haure, Patricia Monica
Cassanello Fernandez, Miryam Celeste
Ayude, María Alejandra
author Doumic, Lucila Inés
author_facet Doumic, Lucila Inés
Salierno, Gabriel Leonardo
Ramos, Cinthia Paula
Haure, Patricia Monica
Cassanello Fernandez, Miryam Celeste
Ayude, María Alejandra
author_role author
author2 Salierno, Gabriel Leonardo
Ramos, Cinthia Paula
Haure, Patricia Monica
Cassanello Fernandez, Miryam Celeste
Ayude, María Alejandra
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Prussian Blue
Fenton-Like
Orange G
topic Prussian Blue
Fenton-Like
Orange G
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the synthesis procedure of supported Prussian blue nanoparticles (PBNP) on their activity and stability as a Fenton-type catalyst is studied. Hence, two catalysts are synthesized by adsorbing onto a support of PBNP formed ex situ through the reaction between FeCl3 and K3Fe(CN)6 using H2O2 as reducing agent, and following different washing protocols. A third catalyst is prepared through a two-step impregnation process with FeCl3 and K4[Fe(CN)6] aqueous solutions. The catalysts are tested in the orange G Fenton-type oxidation. The fresh and used catalysts are characterized by BET surface area, SEM, EDS, TEM, Mössbauer spectroscopy, total iron content and UV-vis spectrophotometry. It is demonstrated that under the synthesis conditions employed, the “insoluble” form of Prussian blue is promoted in the ex situ procedure, whereas the two-step impregnation process leads to the “soluble” Prussian blue formation. The washing of the just-prepared catalysts at the reaction temperature helps in eliminating the unreacted species. Those catalysts based on “insoluble” Prussian blue nanoparticles exhibit better behaviour in terms of stability. Significant removals are attained (100% azo dye, 60% TOC), at pH = 3, 343 K after thirteen successive cycles of 300 min. The best catalyst displays the smallest amount of total “free” Fe leached without releasing PBNP, ferrocyanide or ferricyanide ions into the reaction media. Reversible adsorption–desorption of organic intermediates avoids the loss of activity due to blockage of sites and/or pores.
Fil: Doumic, Lucila Inés. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina
Fil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Cassanello Fernandez, Miryam Celeste. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The influence of the synthesis procedure of supported Prussian blue nanoparticles (PBNP) on their activity and stability as a Fenton-type catalyst is studied. Hence, two catalysts are synthesized by adsorbing onto a support of PBNP formed ex situ through the reaction between FeCl3 and K3Fe(CN)6 using H2O2 as reducing agent, and following different washing protocols. A third catalyst is prepared through a two-step impregnation process with FeCl3 and K4[Fe(CN)6] aqueous solutions. The catalysts are tested in the orange G Fenton-type oxidation. The fresh and used catalysts are characterized by BET surface area, SEM, EDS, TEM, Mössbauer spectroscopy, total iron content and UV-vis spectrophotometry. It is demonstrated that under the synthesis conditions employed, the “insoluble” form of Prussian blue is promoted in the ex situ procedure, whereas the two-step impregnation process leads to the “soluble” Prussian blue formation. The washing of the just-prepared catalysts at the reaction temperature helps in eliminating the unreacted species. Those catalysts based on “insoluble” Prussian blue nanoparticles exhibit better behaviour in terms of stability. Significant removals are attained (100% azo dye, 60% TOC), at pH = 3, 343 K after thirteen successive cycles of 300 min. The best catalyst displays the smallest amount of total “free” Fe leached without releasing PBNP, ferrocyanide or ferricyanide ions into the reaction media. Reversible adsorption–desorption of organic intermediates avoids the loss of activity due to blockage of sites and/or pores.
publishDate 2016
dc.date.none.fl_str_mv 2016-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/33376
Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Ramos, Cinthia Paula; Haure, Patricia Monica; Cassanello Fernandez, Miryam Celeste; et al.; “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment; Royal Society of Chemistry; RSC Advances; 6; 52; 5-2016; 46625-46633
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/33376
identifier_str_mv Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Ramos, Cinthia Paula; Haure, Patricia Monica; Cassanello Fernandez, Miryam Celeste; et al.; “Soluble” vs. “insoluble” Prussian blue based catalysts: influence on Fenton-type treatment; Royal Society of Chemistry; RSC Advances; 6; 52; 5-2016; 46625-46633
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/C6RA06618F
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra06618f#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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