Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.

Autores
Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Cassanello, Miryan C.; Haure, Patricia Monica; Ayude, María Alejandra
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The main goal of this contribution is the development of a new heterogeneous Fenton-like oxidation system based on Prussian Blue supported over a commercially available granular activated carbon (GAC). The catalysts were prepared following basically three different approaches: (i) Prussian Blue (Fe3[Fe(CN)6]2) particles adsorbed onto the GAC by impregnation, (ii) Prussian Blue nanoparticles (PBNP) prepared ex-situ and adsorbed onto the GAC; and (iii) PBNP prepared in-situ onto the GAC. The catalysts were characterized by SEM, EDS, BET surface area and Fe content. Their performance in the catalytic wet peroxide oxidation of a model azo dye, Orange G, was tested in a batch lab-scale stirred reactor. Activity and stability runs were carried out and analyzed in terms of dye discoloration, Total Organic Carbon removal, UV-vis spectra and degree of iron leaching.
Fil: Doumic, Lucila Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Cassanello, Miryan C.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Materia
ACTIVATED CARBON
AZO DYE
HETEROGENEOUS FENTON-LIKE OXIDATION
PRUSSIAN BLUE NANOPARTICLES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2921
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2921
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.Doumic, Lucila InésSalierno, Gabriel LeonardoCassanello, Miryan C.Haure, Patricia MonicaAyude, María AlejandraACTIVATED CARBONAZO DYEHETEROGENEOUS FENTON-LIKE OXIDATIONPRUSSIAN BLUE NANOPARTICLEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The main goal of this contribution is the development of a new heterogeneous Fenton-like oxidation system based on Prussian Blue supported over a commercially available granular activated carbon (GAC). The catalysts were prepared following basically three different approaches: (i) Prussian Blue (Fe3[Fe(CN)6]2) particles adsorbed onto the GAC by impregnation, (ii) Prussian Blue nanoparticles (PBNP) prepared ex-situ and adsorbed onto the GAC; and (iii) PBNP prepared in-situ onto the GAC. The catalysts were characterized by SEM, EDS, BET surface area and Fe content. Their performance in the catalytic wet peroxide oxidation of a model azo dye, Orange G, was tested in a batch lab-scale stirred reactor. Activity and stability runs were carried out and analyzed in terms of dye discoloration, Total Organic Carbon removal, UV-vis spectra and degree of iron leaching.Fil: Doumic, Lucila Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Cassanello, Miryan C.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaInternational Association of Computer Science and Information Technology Press2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2921Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Cassanello, Miryan C.; Haure, Patricia Monica; Ayude, María Alejandra; Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.; International Association of Computer Science and Information Technology Press; International Journal of Chemical Engineering and Applications; 4; 5; 10-2013; 295-3002010-0221enginfo:eu-repo/semantics/altIdentifier/doi/10.7763/IJCEA.2013.V4.313info:eu-repo/semantics/altIdentifier/url/http://www.ijcea.org/index.php?m=content&c=index&a=show&catid=51&id=634info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)https://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:24:40Zoai:ri.conicet.gov.ar:11336/2921instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:24:40.882CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
title Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
spellingShingle Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
Doumic, Lucila Inés
ACTIVATED CARBON
AZO DYE
HETEROGENEOUS FENTON-LIKE OXIDATION
PRUSSIAN BLUE NANOPARTICLES
title_short Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
title_full Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
title_fullStr Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
title_full_unstemmed Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
title_sort Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.
dc.creator.none.fl_str_mv Doumic, Lucila Inés
Salierno, Gabriel Leonardo
Cassanello, Miryan C.
Haure, Patricia Monica
Ayude, María Alejandra
author Doumic, Lucila Inés
author_facet Doumic, Lucila Inés
Salierno, Gabriel Leonardo
Cassanello, Miryan C.
Haure, Patricia Monica
Ayude, María Alejandra
author_role author
author2 Salierno, Gabriel Leonardo
Cassanello, Miryan C.
Haure, Patricia Monica
Ayude, María Alejandra
author2_role author
author
author
author
dc.subject.none.fl_str_mv ACTIVATED CARBON
AZO DYE
HETEROGENEOUS FENTON-LIKE OXIDATION
PRUSSIAN BLUE NANOPARTICLES
topic ACTIVATED CARBON
AZO DYE
HETEROGENEOUS FENTON-LIKE OXIDATION
PRUSSIAN BLUE NANOPARTICLES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The main goal of this contribution is the development of a new heterogeneous Fenton-like oxidation system based on Prussian Blue supported over a commercially available granular activated carbon (GAC). The catalysts were prepared following basically three different approaches: (i) Prussian Blue (Fe3[Fe(CN)6]2) particles adsorbed onto the GAC by impregnation, (ii) Prussian Blue nanoparticles (PBNP) prepared ex-situ and adsorbed onto the GAC; and (iii) PBNP prepared in-situ onto the GAC. The catalysts were characterized by SEM, EDS, BET surface area and Fe content. Their performance in the catalytic wet peroxide oxidation of a model azo dye, Orange G, was tested in a batch lab-scale stirred reactor. Activity and stability runs were carried out and analyzed in terms of dye discoloration, Total Organic Carbon removal, UV-vis spectra and degree of iron leaching.
Fil: Doumic, Lucila Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Salierno, Gabriel Leonardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Cassanello, Miryan C.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Haure, Patricia Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Ayude, María Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
description The main goal of this contribution is the development of a new heterogeneous Fenton-like oxidation system based on Prussian Blue supported over a commercially available granular activated carbon (GAC). The catalysts were prepared following basically three different approaches: (i) Prussian Blue (Fe3[Fe(CN)6]2) particles adsorbed onto the GAC by impregnation, (ii) Prussian Blue nanoparticles (PBNP) prepared ex-situ and adsorbed onto the GAC; and (iii) PBNP prepared in-situ onto the GAC. The catalysts were characterized by SEM, EDS, BET surface area and Fe content. Their performance in the catalytic wet peroxide oxidation of a model azo dye, Orange G, was tested in a batch lab-scale stirred reactor. Activity and stability runs were carried out and analyzed in terms of dye discoloration, Total Organic Carbon removal, UV-vis spectra and degree of iron leaching.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2921
Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Cassanello, Miryan C.; Haure, Patricia Monica; Ayude, María Alejandra; Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.; International Association of Computer Science and Information Technology Press; International Journal of Chemical Engineering and Applications; 4; 5; 10-2013; 295-300
2010-0221
url http://hdl.handle.net/11336/2921
identifier_str_mv Doumic, Lucila Inés; Salierno, Gabriel Leonardo; Cassanello, Miryan C.; Haure, Patricia Monica; Ayude, María Alejandra; Prussian blue onto activated carbon as a catalyst for heterogeneous fenton-like processes.; International Association of Computer Science and Information Technology Press; International Journal of Chemical Engineering and Applications; 4; 5; 10-2013; 295-300
2010-0221
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.7763/IJCEA.2013.V4.313
info:eu-repo/semantics/altIdentifier/url/http://www.ijcea.org/index.php?m=content&c=index&a=show&catid=51&id=634
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv International Association of Computer Science and Information Technology Press
publisher.none.fl_str_mv International Association of Computer Science and Information Technology Press
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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