Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples

Autores
Tesio, Alvaro Yamil; Granero, Adrian Marcelo; Vettorazzi, Nelio Roberto; Ferreyra, Nancy Fabiana; Rivas, Gustavo Adolfo; Fernandez, Hector; Zon, María Alicia
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We describe the development of an electrochemical sensor based on glassy carbon electrodes modified with multiwalled carbon nanotubes dispersed in low molecular weight polyethylenimine for the determination of luteolin in peanut hulls. A well defined quasi-reversible surface redox couple was found using cyclic and square wave voltammetries for luteolin in 1.0 mol L− 1 HClO4 aqueous solutions. The best accumulation potential and the accumulation time were 0.55 V and 20 min, respectively. An optimal ratio of 1:5 for multiwalled carbon nanotubes/polyethylenimine was used to prepare dispersions. The linear range was from 2.4 × 10− 3 to 1.75 μmol L− 1. The luteolin contents determined in two peanut hull samples were (1.18 ± 0.08) and (1.47 ± 0.09) g per 100 g of sample, being in very good agreement with those values obtained from the same samples using HPLC. The limits of detection and quantification were 5.0 × 10− 10 and 1.5 × 10− 9 mol L− 1, respectively. The reproducibility and the repeatability were 8.0 and 7.3%, respectively. The modified glassy carbon electrode was stable even after 23 days.
Fil: Tesio, Alvaro Yamil. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Granero, Adrian Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Vettorazzi, Nelio Roberto. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Ferreyra, Nancy Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Fernandez, Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Zon, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Materia
Flavonoid
Luteolin
Multiwalled Carbon Nanotubes
Polyethylenimine
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31274
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31274
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samplesTesio, Alvaro YamilGranero, Adrian MarceloVettorazzi, Nelio RobertoFerreyra, Nancy FabianaRivas, Gustavo AdolfoFernandez, HectorZon, María AliciaFlavonoidLuteolinMultiwalled Carbon NanotubesPolyethyleniminehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We describe the development of an electrochemical sensor based on glassy carbon electrodes modified with multiwalled carbon nanotubes dispersed in low molecular weight polyethylenimine for the determination of luteolin in peanut hulls. A well defined quasi-reversible surface redox couple was found using cyclic and square wave voltammetries for luteolin in 1.0 mol L− 1 HClO4 aqueous solutions. The best accumulation potential and the accumulation time were 0.55 V and 20 min, respectively. An optimal ratio of 1:5 for multiwalled carbon nanotubes/polyethylenimine was used to prepare dispersions. The linear range was from 2.4 × 10− 3 to 1.75 μmol L− 1. The luteolin contents determined in two peanut hull samples were (1.18 ± 0.08) and (1.47 ± 0.09) g per 100 g of sample, being in very good agreement with those values obtained from the same samples using HPLC. The limits of detection and quantification were 5.0 × 10− 10 and 1.5 × 10− 9 mol L− 1, respectively. The reproducibility and the repeatability were 8.0 and 7.3%, respectively. The modified glassy carbon electrode was stable even after 23 days.Fil: Tesio, Alvaro Yamil. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaFil: Granero, Adrian Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; ArgentinaFil: Vettorazzi, Nelio Roberto. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; ArgentinaFil: Ferreyra, Nancy Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaFil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaFil: Fernandez, Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; ArgentinaFil: Zon, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; ArgentinaElsevier Science2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31274Zon, María Alicia; Fernandez, Hector; Rivas, Gustavo Adolfo; Ferreyra, Nancy Fabiana; Vettorazzi, Nelio Roberto; Granero, Adrian Marcelo; et al.; Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples; Elsevier Science; Microchemical Journal; 115; 2-2014; 100-1050026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.03.004info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000411info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:22:19Zoai:ri.conicet.gov.ar:11336/31274instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:22:19.402CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
title Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
spellingShingle Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
Tesio, Alvaro Yamil
Flavonoid
Luteolin
Multiwalled Carbon Nanotubes
Polyethylenimine
title_short Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
title_full Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
title_fullStr Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
title_full_unstemmed Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
title_sort Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples
dc.creator.none.fl_str_mv Tesio, Alvaro Yamil
Granero, Adrian Marcelo
Vettorazzi, Nelio Roberto
Ferreyra, Nancy Fabiana
Rivas, Gustavo Adolfo
Fernandez, Hector
Zon, María Alicia
author Tesio, Alvaro Yamil
author_facet Tesio, Alvaro Yamil
Granero, Adrian Marcelo
Vettorazzi, Nelio Roberto
Ferreyra, Nancy Fabiana
Rivas, Gustavo Adolfo
Fernandez, Hector
Zon, María Alicia
author_role author
author2 Granero, Adrian Marcelo
Vettorazzi, Nelio Roberto
Ferreyra, Nancy Fabiana
Rivas, Gustavo Adolfo
Fernandez, Hector
Zon, María Alicia
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Flavonoid
Luteolin
Multiwalled Carbon Nanotubes
Polyethylenimine
topic Flavonoid
Luteolin
Multiwalled Carbon Nanotubes
Polyethylenimine
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We describe the development of an electrochemical sensor based on glassy carbon electrodes modified with multiwalled carbon nanotubes dispersed in low molecular weight polyethylenimine for the determination of luteolin in peanut hulls. A well defined quasi-reversible surface redox couple was found using cyclic and square wave voltammetries for luteolin in 1.0 mol L− 1 HClO4 aqueous solutions. The best accumulation potential and the accumulation time were 0.55 V and 20 min, respectively. An optimal ratio of 1:5 for multiwalled carbon nanotubes/polyethylenimine was used to prepare dispersions. The linear range was from 2.4 × 10− 3 to 1.75 μmol L− 1. The luteolin contents determined in two peanut hull samples were (1.18 ± 0.08) and (1.47 ± 0.09) g per 100 g of sample, being in very good agreement with those values obtained from the same samples using HPLC. The limits of detection and quantification were 5.0 × 10− 10 and 1.5 × 10− 9 mol L− 1, respectively. The reproducibility and the repeatability were 8.0 and 7.3%, respectively. The modified glassy carbon electrode was stable even after 23 days.
Fil: Tesio, Alvaro Yamil. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Fil: Granero, Adrian Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Vettorazzi, Nelio Roberto. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Ferreyra, Nancy Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Fernandez, Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
Fil: Zon, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Cs.exactas Fisicoquímicas y Naturales. Departamento de Química. Area Electroquímica; Argentina
description We describe the development of an electrochemical sensor based on glassy carbon electrodes modified with multiwalled carbon nanotubes dispersed in low molecular weight polyethylenimine for the determination of luteolin in peanut hulls. A well defined quasi-reversible surface redox couple was found using cyclic and square wave voltammetries for luteolin in 1.0 mol L− 1 HClO4 aqueous solutions. The best accumulation potential and the accumulation time were 0.55 V and 20 min, respectively. An optimal ratio of 1:5 for multiwalled carbon nanotubes/polyethylenimine was used to prepare dispersions. The linear range was from 2.4 × 10− 3 to 1.75 μmol L− 1. The luteolin contents determined in two peanut hull samples were (1.18 ± 0.08) and (1.47 ± 0.09) g per 100 g of sample, being in very good agreement with those values obtained from the same samples using HPLC. The limits of detection and quantification were 5.0 × 10− 10 and 1.5 × 10− 9 mol L− 1, respectively. The reproducibility and the repeatability were 8.0 and 7.3%, respectively. The modified glassy carbon electrode was stable even after 23 days.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31274
Zon, María Alicia; Fernandez, Hector; Rivas, Gustavo Adolfo; Ferreyra, Nancy Fabiana; Vettorazzi, Nelio Roberto; Granero, Adrian Marcelo; et al.; Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples; Elsevier Science; Microchemical Journal; 115; 2-2014; 100-105
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31274
identifier_str_mv Zon, María Alicia; Fernandez, Hector; Rivas, Gustavo Adolfo; Ferreyra, Nancy Fabiana; Vettorazzi, Nelio Roberto; Granero, Adrian Marcelo; et al.; Development of an electrochemical sensor for the determination of the flavonoid luteolin in peanut hull samples; Elsevier Science; Microchemical Journal; 115; 2-2014; 100-105
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2014.03.004
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X14000411
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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