Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water
- Autores
- Pérez, Hugo Alejandro; Moran Vieyra, Faustino Eduardo; Valle, Lorena; Borsarelli, Claudio Darío
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- documento de conferencia
- Estado
- versión publicada
- Descripción
- Flavins play an important role in photosensitized reactions that include a wide range ofelectron donor substrates, such as amino acids. In aqueous solutions, triplet state offlavins reacts with amino acids such as Cys, Trp and Tyr with bimolecular quenchingconstants between 1-10109 M-1 s-1 [1]. In aerobic conditions, the flavin photosensitizedoxidation of aminoacids was attributed to H2O2 produced by dismutation of O2•-, generated by the interaction of O2 with the triplet of the flavins and/or radical speciesformed by flavin triplet reaction with the aminoacids [2,3].However, to our knowledge, there are few studies about flavin-photosensitizedoxidation of amino acid in microenvironments which mimic biological systemcompartmentalization. In this work we study the riboflavin (Rf)-mediated reaction oftryptophan in nanodroplets made of sodium sulfosuccinate (AOT)-iso-octane-water bycontinuous blue-LED (460 nm) and laser pulsed (355 nm) photolysis, using bothstationary and dynamic absorption and emission spectroscopies.
Fil: Pérez, Hugo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Moran Vieyra, Faustino Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Valle, Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Borsarelli, Claudio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
21st Conference of the Inter-American Photochemical Society
Mendoza
Argentina
Inter-American Photochemical Society - Materia
-
Riboflavin
Sensitizer
AOT
Tryptophan - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/264035
Ver los metadatos del registro completo
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Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-waterPérez, Hugo AlejandroMoran Vieyra, Faustino EduardoValle, LorenaBorsarelli, Claudio DaríoRiboflavinSensitizerAOTTryptophanhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Flavins play an important role in photosensitized reactions that include a wide range ofelectron donor substrates, such as amino acids. In aqueous solutions, triplet state offlavins reacts with amino acids such as Cys, Trp and Tyr with bimolecular quenchingconstants between 1-10109 M-1 s-1 [1]. In aerobic conditions, the flavin photosensitizedoxidation of aminoacids was attributed to H2O2 produced by dismutation of O2•-, generated by the interaction of O2 with the triplet of the flavins and/or radical speciesformed by flavin triplet reaction with the aminoacids [2,3].However, to our knowledge, there are few studies about flavin-photosensitizedoxidation of amino acid in microenvironments which mimic biological systemcompartmentalization. In this work we study the riboflavin (Rf)-mediated reaction oftryptophan in nanodroplets made of sodium sulfosuccinate (AOT)-iso-octane-water bycontinuous blue-LED (460 nm) and laser pulsed (355 nm) photolysis, using bothstationary and dynamic absorption and emission spectroscopies.Fil: Pérez, Hugo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Moran Vieyra, Faustino Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Valle, Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Borsarelli, Claudio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina21st Conference of the Inter-American Photochemical SocietyMendozaArgentinaInter-American Photochemical SocietyInter-American Photochemical Society2011info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectConferenciaBookhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciaapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/264035Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water; 21st Conference of the Inter-American Photochemical Society ; Mendoza; Argentina; 2011; 120-120CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://mail.inifta.unlp.edu.ar/iaps21/abstracts.htmlInternacionalinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:32:45Zoai:ri.conicet.gov.ar:11336/264035instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:32:46.217CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
title |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
spellingShingle |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water Pérez, Hugo Alejandro Riboflavin Sensitizer AOT Tryptophan |
title_short |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
title_full |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
title_fullStr |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
title_full_unstemmed |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
title_sort |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water |
dc.creator.none.fl_str_mv |
Pérez, Hugo Alejandro Moran Vieyra, Faustino Eduardo Valle, Lorena Borsarelli, Claudio Darío |
author |
Pérez, Hugo Alejandro |
author_facet |
Pérez, Hugo Alejandro Moran Vieyra, Faustino Eduardo Valle, Lorena Borsarelli, Claudio Darío |
author_role |
author |
author2 |
Moran Vieyra, Faustino Eduardo Valle, Lorena Borsarelli, Claudio Darío |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Riboflavin Sensitizer AOT Tryptophan |
topic |
Riboflavin Sensitizer AOT Tryptophan |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Flavins play an important role in photosensitized reactions that include a wide range ofelectron donor substrates, such as amino acids. In aqueous solutions, triplet state offlavins reacts with amino acids such as Cys, Trp and Tyr with bimolecular quenchingconstants between 1-10109 M-1 s-1 [1]. In aerobic conditions, the flavin photosensitizedoxidation of aminoacids was attributed to H2O2 produced by dismutation of O2•-, generated by the interaction of O2 with the triplet of the flavins and/or radical speciesformed by flavin triplet reaction with the aminoacids [2,3].However, to our knowledge, there are few studies about flavin-photosensitizedoxidation of amino acid in microenvironments which mimic biological systemcompartmentalization. In this work we study the riboflavin (Rf)-mediated reaction oftryptophan in nanodroplets made of sodium sulfosuccinate (AOT)-iso-octane-water bycontinuous blue-LED (460 nm) and laser pulsed (355 nm) photolysis, using bothstationary and dynamic absorption and emission spectroscopies. Fil: Pérez, Hugo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina Fil: Moran Vieyra, Faustino Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina Fil: Valle, Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina Fil: Borsarelli, Claudio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina 21st Conference of the Inter-American Photochemical Society Mendoza Argentina Inter-American Photochemical Society |
description |
Flavins play an important role in photosensitized reactions that include a wide range ofelectron donor substrates, such as amino acids. In aqueous solutions, triplet state offlavins reacts with amino acids such as Cys, Trp and Tyr with bimolecular quenchingconstants between 1-10109 M-1 s-1 [1]. In aerobic conditions, the flavin photosensitizedoxidation of aminoacids was attributed to H2O2 produced by dismutation of O2•-, generated by the interaction of O2 with the triplet of the flavins and/or radical speciesformed by flavin triplet reaction with the aminoacids [2,3].However, to our knowledge, there are few studies about flavin-photosensitizedoxidation of amino acid in microenvironments which mimic biological systemcompartmentalization. In this work we study the riboflavin (Rf)-mediated reaction oftryptophan in nanodroplets made of sodium sulfosuccinate (AOT)-iso-octane-water bycontinuous blue-LED (460 nm) and laser pulsed (355 nm) photolysis, using bothstationary and dynamic absorption and emission spectroscopies. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/conferenceObject Conferencia Book http://purl.org/coar/resource_type/c_5794 info:ar-repo/semantics/documentoDeConferencia |
status_str |
publishedVersion |
format |
conferenceObject |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/264035 Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water; 21st Conference of the Inter-American Photochemical Society ; Mendoza; Argentina; 2011; 120-120 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/264035 |
identifier_str_mv |
Riboflavin-induced photodegradation of tryptophan in sodium sulfosuccinate (AOT)-iso-octane-water; 21st Conference of the Inter-American Photochemical Society ; Mendoza; Argentina; 2011; 120-120 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://mail.inifta.unlp.edu.ar/iaps21/abstracts.html |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.coverage.none.fl_str_mv |
Internacional |
dc.publisher.none.fl_str_mv |
Inter-American Photochemical Society |
publisher.none.fl_str_mv |
Inter-American Photochemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |