The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure

Autores
Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Correa, Nestor Mariano
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study was carried out on the hydrolysis of phenyl trifluoroacetate (PTFA) in AOT/n-heptane/water reverse micelles. The results obtained have been interpreted by taking into account the distribution of the PTFA using a kinetic model based on the pseudophase concept and, it is demonstrated that the reaction takes place in the water pool of the reverse micelles. Moreover, it is established that the water molecules involved in the hydration of the interface do not react with PTFA or they do it at much slower rate compared with the water molecules that form the pool. The value of the second order rate constant in the water pool, kw–MI, is of the same order of magnitude as that in pure water but is greater (500 times) than those obtained in water–acetonitrile mixtures with low water content. We performed kinetic solvent isotopic effect (KSIE) and proton inventory experiments (PI) and we concluded that the water is acting as a general-base catalyst and the water sequestered in the water pool is pre-organized favoring the activation process, in contrast to what happened in water–acetonitrile mixtures.
Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales; Argentina
Materia
Reverse Micelles
Aot
Catalysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/47449
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structureSilva, Oscar FernandoHoyos, Maria Rita MicaelaCorrea, Nestor MarianoReverse MicellesAotCatalysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A study was carried out on the hydrolysis of phenyl trifluoroacetate (PTFA) in AOT/n-heptane/water reverse micelles. The results obtained have been interpreted by taking into account the distribution of the PTFA using a kinetic model based on the pseudophase concept and, it is demonstrated that the reaction takes place in the water pool of the reverse micelles. Moreover, it is established that the water molecules involved in the hydration of the interface do not react with PTFA or they do it at much slower rate compared with the water molecules that form the pool. The value of the second order rate constant in the water pool, kw–MI, is of the same order of magnitude as that in pure water but is greater (500 times) than those obtained in water–acetonitrile mixtures with low water content. We performed kinetic solvent isotopic effect (KSIE) and proton inventory experiments (PI) and we concluded that the water is acting as a general-base catalyst and the water sequestered in the water pool is pre-organized favoring the activation process, in contrast to what happened in water–acetonitrile mixtures.Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales; ArgentinaRoyal Society of Chemistry2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/47449Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Correa, Nestor Mariano; The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure; Royal Society of Chemistry; RSC Advances; 5; 44; 4-2015; 34878-348842046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA03532E#info:eu-repo/semantics/altIdentifier/doi/10.1039/c5ra03532einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:44Zoai:ri.conicet.gov.ar:11336/47449instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:45.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
title The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
spellingShingle The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
Silva, Oscar Fernando
Reverse Micelles
Aot
Catalysis
title_short The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
title_full The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
title_fullStr The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
title_full_unstemmed The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
title_sort The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure
dc.creator.none.fl_str_mv Silva, Oscar Fernando
Hoyos, Maria Rita Micaela
Correa, Nestor Mariano
author Silva, Oscar Fernando
author_facet Silva, Oscar Fernando
Hoyos, Maria Rita Micaela
Correa, Nestor Mariano
author_role author
author2 Hoyos, Maria Rita Micaela
Correa, Nestor Mariano
author2_role author
author
dc.subject.none.fl_str_mv Reverse Micelles
Aot
Catalysis
topic Reverse Micelles
Aot
Catalysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study was carried out on the hydrolysis of phenyl trifluoroacetate (PTFA) in AOT/n-heptane/water reverse micelles. The results obtained have been interpreted by taking into account the distribution of the PTFA using a kinetic model based on the pseudophase concept and, it is demonstrated that the reaction takes place in the water pool of the reverse micelles. Moreover, it is established that the water molecules involved in the hydration of the interface do not react with PTFA or they do it at much slower rate compared with the water molecules that form the pool. The value of the second order rate constant in the water pool, kw–MI, is of the same order of magnitude as that in pure water but is greater (500 times) than those obtained in water–acetonitrile mixtures with low water content. We performed kinetic solvent isotopic effect (KSIE) and proton inventory experiments (PI) and we concluded that the water is acting as a general-base catalyst and the water sequestered in the water pool is pre-organized favoring the activation process, in contrast to what happened in water–acetonitrile mixtures.
Fil: Silva, Oscar Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales; Argentina
description A study was carried out on the hydrolysis of phenyl trifluoroacetate (PTFA) in AOT/n-heptane/water reverse micelles. The results obtained have been interpreted by taking into account the distribution of the PTFA using a kinetic model based on the pseudophase concept and, it is demonstrated that the reaction takes place in the water pool of the reverse micelles. Moreover, it is established that the water molecules involved in the hydration of the interface do not react with PTFA or they do it at much slower rate compared with the water molecules that form the pool. The value of the second order rate constant in the water pool, kw–MI, is of the same order of magnitude as that in pure water but is greater (500 times) than those obtained in water–acetonitrile mixtures with low water content. We performed kinetic solvent isotopic effect (KSIE) and proton inventory experiments (PI) and we concluded that the water is acting as a general-base catalyst and the water sequestered in the water pool is pre-organized favoring the activation process, in contrast to what happened in water–acetonitrile mixtures.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/47449
Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Correa, Nestor Mariano; The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure; Royal Society of Chemistry; RSC Advances; 5; 44; 4-2015; 34878-34884
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/47449
identifier_str_mv Silva, Oscar Fernando; Hoyos, Maria Rita Micaela; Correa, Nestor Mariano; The hydrolysis of phenyl trifluoroacetate in AOT/n-heptane RMs as a sensor of the encapsulated water structure; Royal Society of Chemistry; RSC Advances; 5; 44; 4-2015; 34878-34884
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA03532E#
info:eu-repo/semantics/altIdentifier/doi/10.1039/c5ra03532e
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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