Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts
- Autores
- Foresti, María Laura; Ferreira, María Luján
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Polymerization of caprolactone using lipases from Candida antarctica B, Rhizomucor meihei, Candida rugosa, and Pseudomonas fluorescens is highly effective, with 97% conversion into polycaprolactone. Poly(propylene)-supported Candida rugosa lipase achieves higher conversion values (85-92%) than free lipase (75%). Acidic and basic non-conventional catalysis with butanol yields 50-85% conversion. Simple UV/visible techniques gave the same results for measuring conversion than other studies. Applications are opened for the non-conventional catalysts.
Fil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina - Materia
-
Basic Catalysis
Enzymes
Polycaprolactone
Supports - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/57685
Ver los metadatos del registro completo
id |
CONICETDig_6de833be01ada2289ead5bcfa7a8a3f6 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/57685 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalystsForesti, María LauraFerreira, María LujánBasic CatalysisEnzymesPolycaprolactoneSupportshttps://purl.org/becyt/ford/2.9https://purl.org/becyt/ford/2Polymerization of caprolactone using lipases from Candida antarctica B, Rhizomucor meihei, Candida rugosa, and Pseudomonas fluorescens is highly effective, with 97% conversion into polycaprolactone. Poly(propylene)-supported Candida rugosa lipase achieves higher conversion values (85-92%) than free lipase (75%). Acidic and basic non-conventional catalysis with butanol yields 50-85% conversion. Simple UV/visible techniques gave the same results for measuring conversion than other studies. Applications are opened for the non-conventional catalysts.Fil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57685Foresti, María Laura; Ferreira, María Luján; Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts; Wiley VCH Verlag; Macromolecular Rapid Communications; 25; 24; 12-2004; 2025-20281022-1336CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/marc.200400392info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.200400392info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:07Zoai:ri.conicet.gov.ar:11336/57685instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:07.325CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
title |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
spellingShingle |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts Foresti, María Laura Basic Catalysis Enzymes Polycaprolactone Supports |
title_short |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
title_full |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
title_fullStr |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
title_full_unstemmed |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
title_sort |
Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts |
dc.creator.none.fl_str_mv |
Foresti, María Laura Ferreira, María Luján |
author |
Foresti, María Laura |
author_facet |
Foresti, María Laura Ferreira, María Luján |
author_role |
author |
author2 |
Ferreira, María Luján |
author2_role |
author |
dc.subject.none.fl_str_mv |
Basic Catalysis Enzymes Polycaprolactone Supports |
topic |
Basic Catalysis Enzymes Polycaprolactone Supports |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.9 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Polymerization of caprolactone using lipases from Candida antarctica B, Rhizomucor meihei, Candida rugosa, and Pseudomonas fluorescens is highly effective, with 97% conversion into polycaprolactone. Poly(propylene)-supported Candida rugosa lipase achieves higher conversion values (85-92%) than free lipase (75%). Acidic and basic non-conventional catalysis with butanol yields 50-85% conversion. Simple UV/visible techniques gave the same results for measuring conversion than other studies. Applications are opened for the non-conventional catalysts. Fil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina |
description |
Polymerization of caprolactone using lipases from Candida antarctica B, Rhizomucor meihei, Candida rugosa, and Pseudomonas fluorescens is highly effective, with 97% conversion into polycaprolactone. Poly(propylene)-supported Candida rugosa lipase achieves higher conversion values (85-92%) than free lipase (75%). Acidic and basic non-conventional catalysis with butanol yields 50-85% conversion. Simple UV/visible techniques gave the same results for measuring conversion than other studies. Applications are opened for the non-conventional catalysts. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/57685 Foresti, María Laura; Ferreira, María Luján; Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts; Wiley VCH Verlag; Macromolecular Rapid Communications; 25; 24; 12-2004; 2025-2028 1022-1336 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/57685 |
identifier_str_mv |
Foresti, María Laura; Ferreira, María Luján; Synthesis of polycaprolactone using free/supported enzymatic and non-enzymatic catalysts; Wiley VCH Verlag; Macromolecular Rapid Communications; 25; 24; 12-2004; 2025-2028 1022-1336 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/marc.200400392 info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.200400392 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613014945267712 |
score |
13.070432 |