Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering

Autores
Arab Pour Yazdi, Mohammad; Lizarraga, Leonardo; Vernoux, Philippe; Billard, Alain; Briois, Pascal
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Lanthanum perovskites are promising candidates to replace platinum group metal (PGM), especially regarding catalytic oxidation reactions. We have prepared thin catalytic coatings of Sr and Ag doped lanthanum perovskite by using the cathodic co-sputtering magnetron method in reactive condition. Such development of catalytic films may optimize the surface/bulk ratio to save raw materials, since a porous coating can combine a large exchange surface with the gas phase with an extremely low loading. The sputtering deposition process was optimized to generate crystallized and thin perovskites films on alumina substrates. We found that high Ag contents has a strong impact on the morphology of the coatings. High Ag loadings favor the growth of covering films with a porous wire-like morphology showing a good catalytic activity for CO oxidation. The most active composition displays similar catalytic performances than those of a Pt film. In addition, this porous coating is also efficient for CO and NO oxidation in a simulated Diesel exhaust gas mixture, demonstrating the promising catalytic properties of such nanostructured thin sputtered perovskite films.
Fil: Arab Pour Yazdi, Mohammad. Universite de Bourgogne; Francia
Fil: Lizarraga, Leonardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; Francia
Fil: Vernoux, Philippe. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; Francia
Fil: Billard, Alain. Universite de Bourgogne; Francia
Fil: Briois, Pascal. Universite de Bourgogne; Francia
Materia
PEROVSKITE
CATALYTIC COATING
CO OXIDATION
CATHODIC SPUTTERING METHOD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/108443
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron SputteringArab Pour Yazdi, MohammadLizarraga, LeonardoVernoux, PhilippeBillard, AlainBriois, PascalPEROVSKITECATALYTIC COATINGCO OXIDATIONCATHODIC SPUTTERING METHODhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Lanthanum perovskites are promising candidates to replace platinum group metal (PGM), especially regarding catalytic oxidation reactions. We have prepared thin catalytic coatings of Sr and Ag doped lanthanum perovskite by using the cathodic co-sputtering magnetron method in reactive condition. Such development of catalytic films may optimize the surface/bulk ratio to save raw materials, since a porous coating can combine a large exchange surface with the gas phase with an extremely low loading. The sputtering deposition process was optimized to generate crystallized and thin perovskites films on alumina substrates. We found that high Ag contents has a strong impact on the morphology of the coatings. High Ag loadings favor the growth of covering films with a porous wire-like morphology showing a good catalytic activity for CO oxidation. The most active composition displays similar catalytic performances than those of a Pt film. In addition, this porous coating is also efficient for CO and NO oxidation in a simulated Diesel exhaust gas mixture, demonstrating the promising catalytic properties of such nanostructured thin sputtered perovskite films.Fil: Arab Pour Yazdi, Mohammad. Universite de Bourgogne; FranciaFil: Lizarraga, Leonardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; FranciaFil: Vernoux, Philippe. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; FranciaFil: Billard, Alain. Universite de Bourgogne; FranciaFil: Briois, Pascal. Universite de Bourgogne; FranciaMultidisciplinary Digital Publishing Institute2019-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/108443Arab Pour Yazdi, Mohammad; Lizarraga, Leonardo; Vernoux, Philippe; Billard, Alain; Briois, Pascal; Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 4; 4-2019; 1-142073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/9/4/381info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.3390/catal9040381info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:34Zoai:ri.conicet.gov.ar:11336/108443instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:34.706CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
title Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
spellingShingle Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
Arab Pour Yazdi, Mohammad
PEROVSKITE
CATALYTIC COATING
CO OXIDATION
CATHODIC SPUTTERING METHOD
title_short Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
title_full Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
title_fullStr Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
title_full_unstemmed Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
title_sort Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering
dc.creator.none.fl_str_mv Arab Pour Yazdi, Mohammad
Lizarraga, Leonardo
Vernoux, Philippe
Billard, Alain
Briois, Pascal
author Arab Pour Yazdi, Mohammad
author_facet Arab Pour Yazdi, Mohammad
Lizarraga, Leonardo
Vernoux, Philippe
Billard, Alain
Briois, Pascal
author_role author
author2 Lizarraga, Leonardo
Vernoux, Philippe
Billard, Alain
Briois, Pascal
author2_role author
author
author
author
dc.subject.none.fl_str_mv PEROVSKITE
CATALYTIC COATING
CO OXIDATION
CATHODIC SPUTTERING METHOD
topic PEROVSKITE
CATALYTIC COATING
CO OXIDATION
CATHODIC SPUTTERING METHOD
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Lanthanum perovskites are promising candidates to replace platinum group metal (PGM), especially regarding catalytic oxidation reactions. We have prepared thin catalytic coatings of Sr and Ag doped lanthanum perovskite by using the cathodic co-sputtering magnetron method in reactive condition. Such development of catalytic films may optimize the surface/bulk ratio to save raw materials, since a porous coating can combine a large exchange surface with the gas phase with an extremely low loading. The sputtering deposition process was optimized to generate crystallized and thin perovskites films on alumina substrates. We found that high Ag contents has a strong impact on the morphology of the coatings. High Ag loadings favor the growth of covering films with a porous wire-like morphology showing a good catalytic activity for CO oxidation. The most active composition displays similar catalytic performances than those of a Pt film. In addition, this porous coating is also efficient for CO and NO oxidation in a simulated Diesel exhaust gas mixture, demonstrating the promising catalytic properties of such nanostructured thin sputtered perovskite films.
Fil: Arab Pour Yazdi, Mohammad. Universite de Bourgogne; Francia
Fil: Lizarraga, Leonardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Centro de Investigaciones en Bionanociencias "Elizabeth Jares Erijman"; Argentina. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; Francia
Fil: Vernoux, Philippe. Universite Claude Bernard Lyon 1. Institut de Physique Nucléaire de Lyon.; Francia. Universite Lyon 2; Francia
Fil: Billard, Alain. Universite de Bourgogne; Francia
Fil: Briois, Pascal. Universite de Bourgogne; Francia
description Lanthanum perovskites are promising candidates to replace platinum group metal (PGM), especially regarding catalytic oxidation reactions. We have prepared thin catalytic coatings of Sr and Ag doped lanthanum perovskite by using the cathodic co-sputtering magnetron method in reactive condition. Such development of catalytic films may optimize the surface/bulk ratio to save raw materials, since a porous coating can combine a large exchange surface with the gas phase with an extremely low loading. The sputtering deposition process was optimized to generate crystallized and thin perovskites films on alumina substrates. We found that high Ag contents has a strong impact on the morphology of the coatings. High Ag loadings favor the growth of covering films with a porous wire-like morphology showing a good catalytic activity for CO oxidation. The most active composition displays similar catalytic performances than those of a Pt film. In addition, this porous coating is also efficient for CO and NO oxidation in a simulated Diesel exhaust gas mixture, demonstrating the promising catalytic properties of such nanostructured thin sputtered perovskite films.
publishDate 2019
dc.date.none.fl_str_mv 2019-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/108443
Arab Pour Yazdi, Mohammad; Lizarraga, Leonardo; Vernoux, Philippe; Billard, Alain; Briois, Pascal; Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 4; 4-2019; 1-14
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/108443
identifier_str_mv Arab Pour Yazdi, Mohammad; Lizarraga, Leonardo; Vernoux, Philippe; Billard, Alain; Briois, Pascal; Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputtering; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 4; 4-2019; 1-14
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/9/4/381
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.3390/catal9040381
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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