Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins

Autores
Hamer, Mariana; Rezzano, Irene Noemí
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nanocomposites with bimetallic monolayers of porphyrins were prepared. The well-ordered metalloporphyrin monolayers covalently linked to the gold surface produce an important increase of the B band (∼400 nm) shifted 20 nm relative to that of the related high-spin iron(III) complexes in solution. The position of the B band in the bimetallic architectures is highly dependent on the relative amount of the two porphyrins, showing the most significant shift for the SiO2/APTES/AuNp/Fe-TPyP&M-TPyP (1:1) (30 nm, M = Ni(II) or Cu(II)). Resonance Raman based on the oxidation state marker bands (1553, 1354, and 390 cm–1) indicates that Fe-TPyP attached on gold nanoparticles adopts a low-spin Fe(II) conformation, which changes to Fe(II) intermediate spin or a low-spin Fe(III) in the presence of Cu-TPyP or Ni-TPyP. Surface-enhanced Raman scattering studies confirmed the hypothesis. MALDI-TOF analysis of the composites on gold nanoparticles was very useful in the detection of oxygenated forms of the metal complexes.
Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Fil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Materia
Porphyrin
Gold Nanoparticle
Raman
Uv-Vis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/18340
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/18340
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrinsHamer, MarianaRezzano, Irene NoemíPorphyrinGold NanoparticleRamanUv-Vishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Nanocomposites with bimetallic monolayers of porphyrins were prepared. The well-ordered metalloporphyrin monolayers covalently linked to the gold surface produce an important increase of the B band (∼400 nm) shifted 20 nm relative to that of the related high-spin iron(III) complexes in solution. The position of the B band in the bimetallic architectures is highly dependent on the relative amount of the two porphyrins, showing the most significant shift for the SiO2/APTES/AuNp/Fe-TPyP&M-TPyP (1:1) (30 nm, M = Ni(II) or Cu(II)). Resonance Raman based on the oxidation state marker bands (1553, 1354, and 390 cm–1) indicates that Fe-TPyP attached on gold nanoparticles adopts a low-spin Fe(II) conformation, which changes to Fe(II) intermediate spin or a low-spin Fe(III) in the presence of Cu-TPyP or Ni-TPyP. Surface-enhanced Raman scattering studies confirmed the hypothesis. MALDI-TOF analysis of the composites on gold nanoparticles was very useful in the detection of oxygenated forms of the metal complexes.Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; ArgentinaFil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; ArgentinaAmerican Chemical Society2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/18340Hamer, Mariana; Rezzano, Irene Noemí; Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins; American Chemical Society; Inorganic Chemistry; 55; 17; 8-2016; 8595-86020020-1669CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.6b01136info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01136info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:38:13Zoai:ri.conicet.gov.ar:11336/18340instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:14.255CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
title Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
spellingShingle Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
Hamer, Mariana
Porphyrin
Gold Nanoparticle
Raman
Uv-Vis
title_short Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
title_full Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
title_fullStr Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
title_full_unstemmed Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
title_sort Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins
dc.creator.none.fl_str_mv Hamer, Mariana
Rezzano, Irene Noemí
author Hamer, Mariana
author_facet Hamer, Mariana
Rezzano, Irene Noemí
author_role author
author2 Rezzano, Irene Noemí
author2_role author
dc.subject.none.fl_str_mv Porphyrin
Gold Nanoparticle
Raman
Uv-Vis
topic Porphyrin
Gold Nanoparticle
Raman
Uv-Vis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Nanocomposites with bimetallic monolayers of porphyrins were prepared. The well-ordered metalloporphyrin monolayers covalently linked to the gold surface produce an important increase of the B band (∼400 nm) shifted 20 nm relative to that of the related high-spin iron(III) complexes in solution. The position of the B band in the bimetallic architectures is highly dependent on the relative amount of the two porphyrins, showing the most significant shift for the SiO2/APTES/AuNp/Fe-TPyP&M-TPyP (1:1) (30 nm, M = Ni(II) or Cu(II)). Resonance Raman based on the oxidation state marker bands (1553, 1354, and 390 cm–1) indicates that Fe-TPyP attached on gold nanoparticles adopts a low-spin Fe(II) conformation, which changes to Fe(II) intermediate spin or a low-spin Fe(III) in the presence of Cu-TPyP or Ni-TPyP. Surface-enhanced Raman scattering studies confirmed the hypothesis. MALDI-TOF analysis of the composites on gold nanoparticles was very useful in the detection of oxygenated forms of the metal complexes.
Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Fil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
description Nanocomposites with bimetallic monolayers of porphyrins were prepared. The well-ordered metalloporphyrin monolayers covalently linked to the gold surface produce an important increase of the B band (∼400 nm) shifted 20 nm relative to that of the related high-spin iron(III) complexes in solution. The position of the B band in the bimetallic architectures is highly dependent on the relative amount of the two porphyrins, showing the most significant shift for the SiO2/APTES/AuNp/Fe-TPyP&M-TPyP (1:1) (30 nm, M = Ni(II) or Cu(II)). Resonance Raman based on the oxidation state marker bands (1553, 1354, and 390 cm–1) indicates that Fe-TPyP attached on gold nanoparticles adopts a low-spin Fe(II) conformation, which changes to Fe(II) intermediate spin or a low-spin Fe(III) in the presence of Cu-TPyP or Ni-TPyP. Surface-enhanced Raman scattering studies confirmed the hypothesis. MALDI-TOF analysis of the composites on gold nanoparticles was very useful in the detection of oxygenated forms of the metal complexes.
publishDate 2016
dc.date.none.fl_str_mv 2016-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/18340
Hamer, Mariana; Rezzano, Irene Noemí; Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins; American Chemical Society; Inorganic Chemistry; 55; 17; 8-2016; 8595-8602
0020-1669
CONICET Digital
CONICET
url http://hdl.handle.net/11336/18340
identifier_str_mv Hamer, Mariana; Rezzano, Irene Noemí; Classical characterization techniques to reveal the structural model of nanocomposites with bimetallic monolayers of porphyrins; American Chemical Society; Inorganic Chemistry; 55; 17; 8-2016; 8595-8602
0020-1669
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.6b01136
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01136
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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