Optical properties and sensor applications of bimetallic nanostructures of porphyrins

Autores
Hamer, Mariana; Tomba, Juan Pablo; Rezzano, Irene Noemí
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The cationic Cu(II) and Fe(III) complexes of tetra(4-pyridyl)porphyrin [T4PyP]4+ have been combined with the anionic [H4TPPS]2− to obtain bimetallic J-aggregate nanostructures defined by the tendency to form the FeIIIOCuII bridge along with electrostatic interactions. The Resonant Raman spectra of the bimetallic structures revealed subtle but detectable changes of two significant bands: 661 cm−1 (attributed to the out-of-plane bending of the Cusingle bondN bond) and 805 cm−1 (sensitive to the nature of the axial ligand opposite to the oxo ligand), both indicating the important role of the metallic centers in the formation of the CuFe nanorod aggregate. The sensing performance of the aggregates was explored monitoring the absorbance changes in the visible region induced by adding different analytes (H2O2, NO2−, SO32− and N3−). The bimetallic nanostructures maintain the J-aggregation structure after successive addition of H2O2 with an increasing absorption response at 435 cm−1 (monomer band); this architecture was the most sensitive arrangement confirming the synergic effect of the two metals.
Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Materia
Nanostructures
Raman
Sensor
Bimetallic Porphyrins
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17898
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optical properties and sensor applications of bimetallic nanostructures of porphyrinsHamer, MarianaTomba, Juan PabloRezzano, Irene NoemíNanostructuresRamanSensorBimetallic Porphyrinshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The cationic Cu(II) and Fe(III) complexes of tetra(4-pyridyl)porphyrin [T4PyP]4+ have been combined with the anionic [H4TPPS]2− to obtain bimetallic J-aggregate nanostructures defined by the tendency to form the FeIIIOCuII bridge along with electrostatic interactions. The Resonant Raman spectra of the bimetallic structures revealed subtle but detectable changes of two significant bands: 661 cm−1 (attributed to the out-of-plane bending of the Cusingle bondN bond) and 805 cm−1 (sensitive to the nature of the axial ligand opposite to the oxo ligand), both indicating the important role of the metallic centers in the formation of the CuFe nanorod aggregate. The sensing performance of the aggregates was explored monitoring the absorbance changes in the visible region induced by adding different analytes (H2O2, NO2−, SO32− and N3−). The bimetallic nanostructures maintain the J-aggregation structure after successive addition of H2O2 with an increasing absorption response at 435 cm−1 (monomer band); this architecture was the most sensitive arrangement confirming the synergic effect of the two metals.Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; ArgentinaFil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; ArgentinaElsevier Science2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17898Hamer, Mariana; Tomba, Juan Pablo; Rezzano, Irene Noemí; Optical properties and sensor applications of bimetallic nanostructures of porphyrins; Elsevier Science; Sensors And Actuators B: Chemical; 193; 3-2014; 121-1270925-4005enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925400513014275info:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2013.11.077info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:45:32Zoai:ri.conicet.gov.ar:11336/17898instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:45:32.7CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optical properties and sensor applications of bimetallic nanostructures of porphyrins
title Optical properties and sensor applications of bimetallic nanostructures of porphyrins
spellingShingle Optical properties and sensor applications of bimetallic nanostructures of porphyrins
Hamer, Mariana
Nanostructures
Raman
Sensor
Bimetallic Porphyrins
title_short Optical properties and sensor applications of bimetallic nanostructures of porphyrins
title_full Optical properties and sensor applications of bimetallic nanostructures of porphyrins
title_fullStr Optical properties and sensor applications of bimetallic nanostructures of porphyrins
title_full_unstemmed Optical properties and sensor applications of bimetallic nanostructures of porphyrins
title_sort Optical properties and sensor applications of bimetallic nanostructures of porphyrins
dc.creator.none.fl_str_mv Hamer, Mariana
Tomba, Juan Pablo
Rezzano, Irene Noemí
author Hamer, Mariana
author_facet Hamer, Mariana
Tomba, Juan Pablo
Rezzano, Irene Noemí
author_role author
author2 Tomba, Juan Pablo
Rezzano, Irene Noemí
author2_role author
author
dc.subject.none.fl_str_mv Nanostructures
Raman
Sensor
Bimetallic Porphyrins
topic Nanostructures
Raman
Sensor
Bimetallic Porphyrins
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The cationic Cu(II) and Fe(III) complexes of tetra(4-pyridyl)porphyrin [T4PyP]4+ have been combined with the anionic [H4TPPS]2− to obtain bimetallic J-aggregate nanostructures defined by the tendency to form the FeIIIOCuII bridge along with electrostatic interactions. The Resonant Raman spectra of the bimetallic structures revealed subtle but detectable changes of two significant bands: 661 cm−1 (attributed to the out-of-plane bending of the Cusingle bondN bond) and 805 cm−1 (sensitive to the nature of the axial ligand opposite to the oxo ligand), both indicating the important role of the metallic centers in the formation of the CuFe nanorod aggregate. The sensing performance of the aggregates was explored monitoring the absorbance changes in the visible region induced by adding different analytes (H2O2, NO2−, SO32− and N3−). The bimetallic nanostructures maintain the J-aggregation structure after successive addition of H2O2 with an increasing absorption response at 435 cm−1 (monomer band); this architecture was the most sensitive arrangement confirming the synergic effect of the two metals.
Fil: Hamer, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rezzano, Irene Noemí. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Química y Físico-Química Biológicas "Prof. Alejandro C. Paladini". Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Instituto de Química y Físico-Química Biológicas; Argentina
description The cationic Cu(II) and Fe(III) complexes of tetra(4-pyridyl)porphyrin [T4PyP]4+ have been combined with the anionic [H4TPPS]2− to obtain bimetallic J-aggregate nanostructures defined by the tendency to form the FeIIIOCuII bridge along with electrostatic interactions. The Resonant Raman spectra of the bimetallic structures revealed subtle but detectable changes of two significant bands: 661 cm−1 (attributed to the out-of-plane bending of the Cusingle bondN bond) and 805 cm−1 (sensitive to the nature of the axial ligand opposite to the oxo ligand), both indicating the important role of the metallic centers in the formation of the CuFe nanorod aggregate. The sensing performance of the aggregates was explored monitoring the absorbance changes in the visible region induced by adding different analytes (H2O2, NO2−, SO32− and N3−). The bimetallic nanostructures maintain the J-aggregation structure after successive addition of H2O2 with an increasing absorption response at 435 cm−1 (monomer band); this architecture was the most sensitive arrangement confirming the synergic effect of the two metals.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17898
Hamer, Mariana; Tomba, Juan Pablo; Rezzano, Irene Noemí; Optical properties and sensor applications of bimetallic nanostructures of porphyrins; Elsevier Science; Sensors And Actuators B: Chemical; 193; 3-2014; 121-127
0925-4005
url http://hdl.handle.net/11336/17898
identifier_str_mv Hamer, Mariana; Tomba, Juan Pablo; Rezzano, Irene Noemí; Optical properties and sensor applications of bimetallic nanostructures of porphyrins; Elsevier Science; Sensors And Actuators B: Chemical; 193; 3-2014; 121-127
0925-4005
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925400513014275
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2013.11.077
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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