Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presenc...

Autores
Arancibia, Juan Alberto; Escandar, Graciela Monica
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper presents a novel approach for the simultaneous determination of isoproturon, rimsulfuron and monuron, three widely used urea-derivative herbicides, in interfering environmental samples, combining the advantages of photoinduced fluorescence (PIF) emission, liquid chromatography and second-order chemometric algorithms. Chromatographic detection is performed with a fast-scanning spectrofluorimeter, which allowed efficient collection of PIF through a post-column photoreactor. Thus, second-order elution time-PIF emission data matrices are rapidly obtained (in less than 4 min) using a chromatographic system operating in an isocratic regime using a minimal amount of organic solvent. The goal of the present study was the successful resolution of a system in the presence of foreign compounds which can be present in real samples. The study was employed for the discussion of the scope of the applied second-order algorithms selected for data processing, namely parallel factor analysis (PARAFAC), multivariate curve resolution-alternating least-squares (MCR-ALS), and multidimensional and unfolded partial least-squares coupled to residual bilinearization (N- and U-PLS/RBL). U-PLS/RBL showed the best performance to quantify the herbicides, even when the foreign compounds showed very similar spectral and time profiles to the analytes. The quality of the proposed technique was assessed on the basis of the analytical recoveries from different types of water samples spiked with analytes and other selected agrochemicals. After solid-phase extraction, reaching a preconcentration factor of 50, detection limits of 2.9, 2.4, and 1.7 ng mL−1 for isoproturon, rimsulfuron, and monuron, respectively, were obtained in those interfering matrices, with relative prediction errors lower than 5%
Fil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Materia
Urea Herbicide
Second-Order Calibration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/29737
Acceder
id CONICETDig_88a8ccbf01977907c4b0c3300af75437
oai_identifier_str oai:ri.conicet.gov.ar:11336/29737
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compoundsArancibia, Juan AlbertoEscandar, Graciela MonicaUrea HerbicideSecond-Order Calibrationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper presents a novel approach for the simultaneous determination of isoproturon, rimsulfuron and monuron, three widely used urea-derivative herbicides, in interfering environmental samples, combining the advantages of photoinduced fluorescence (PIF) emission, liquid chromatography and second-order chemometric algorithms. Chromatographic detection is performed with a fast-scanning spectrofluorimeter, which allowed efficient collection of PIF through a post-column photoreactor. Thus, second-order elution time-PIF emission data matrices are rapidly obtained (in less than 4 min) using a chromatographic system operating in an isocratic regime using a minimal amount of organic solvent. The goal of the present study was the successful resolution of a system in the presence of foreign compounds which can be present in real samples. The study was employed for the discussion of the scope of the applied second-order algorithms selected for data processing, namely parallel factor analysis (PARAFAC), multivariate curve resolution-alternating least-squares (MCR-ALS), and multidimensional and unfolded partial least-squares coupled to residual bilinearization (N- and U-PLS/RBL). U-PLS/RBL showed the best performance to quantify the herbicides, even when the foreign compounds showed very similar spectral and time profiles to the analytes. The quality of the proposed technique was assessed on the basis of the analytical recoveries from different types of water samples spiked with analytes and other selected agrochemicals. After solid-phase extraction, reaching a preconcentration factor of 50, detection limits of 2.9, 2.4, and 1.7 ng mL−1 for isoproturon, rimsulfuron, and monuron, respectively, were obtained in those interfering matrices, with relative prediction errors lower than 5%Fil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaRoyal Society of Chemistry2014-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29737Arancibia, Juan Alberto; Escandar, Graciela Monica; Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds; Royal Society of Chemistry; Analytical Methods; 15; 8-2014; 5503-55111759-9660CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/C4AY00705Kinfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/AY/C4AY00705Kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:11Zoai:ri.conicet.gov.ar:11336/29737instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:11.94CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
title Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
spellingShingle Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
Arancibia, Juan Alberto
Urea Herbicide
Second-Order Calibration
title_short Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
title_full Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
title_fullStr Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
title_full_unstemmed Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
title_sort Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds
dc.creator.none.fl_str_mv Arancibia, Juan Alberto
Escandar, Graciela Monica
author Arancibia, Juan Alberto
author_facet Arancibia, Juan Alberto
Escandar, Graciela Monica
author_role author
author2 Escandar, Graciela Monica
author2_role author
dc.subject.none.fl_str_mv Urea Herbicide
Second-Order Calibration
topic Urea Herbicide
Second-Order Calibration
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This paper presents a novel approach for the simultaneous determination of isoproturon, rimsulfuron and monuron, three widely used urea-derivative herbicides, in interfering environmental samples, combining the advantages of photoinduced fluorescence (PIF) emission, liquid chromatography and second-order chemometric algorithms. Chromatographic detection is performed with a fast-scanning spectrofluorimeter, which allowed efficient collection of PIF through a post-column photoreactor. Thus, second-order elution time-PIF emission data matrices are rapidly obtained (in less than 4 min) using a chromatographic system operating in an isocratic regime using a minimal amount of organic solvent. The goal of the present study was the successful resolution of a system in the presence of foreign compounds which can be present in real samples. The study was employed for the discussion of the scope of the applied second-order algorithms selected for data processing, namely parallel factor analysis (PARAFAC), multivariate curve resolution-alternating least-squares (MCR-ALS), and multidimensional and unfolded partial least-squares coupled to residual bilinearization (N- and U-PLS/RBL). U-PLS/RBL showed the best performance to quantify the herbicides, even when the foreign compounds showed very similar spectral and time profiles to the analytes. The quality of the proposed technique was assessed on the basis of the analytical recoveries from different types of water samples spiked with analytes and other selected agrochemicals. After solid-phase extraction, reaching a preconcentration factor of 50, detection limits of 2.9, 2.4, and 1.7 ng mL−1 for isoproturon, rimsulfuron, and monuron, respectively, were obtained in those interfering matrices, with relative prediction errors lower than 5%
Fil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
description This paper presents a novel approach for the simultaneous determination of isoproturon, rimsulfuron and monuron, three widely used urea-derivative herbicides, in interfering environmental samples, combining the advantages of photoinduced fluorescence (PIF) emission, liquid chromatography and second-order chemometric algorithms. Chromatographic detection is performed with a fast-scanning spectrofluorimeter, which allowed efficient collection of PIF through a post-column photoreactor. Thus, second-order elution time-PIF emission data matrices are rapidly obtained (in less than 4 min) using a chromatographic system operating in an isocratic regime using a minimal amount of organic solvent. The goal of the present study was the successful resolution of a system in the presence of foreign compounds which can be present in real samples. The study was employed for the discussion of the scope of the applied second-order algorithms selected for data processing, namely parallel factor analysis (PARAFAC), multivariate curve resolution-alternating least-squares (MCR-ALS), and multidimensional and unfolded partial least-squares coupled to residual bilinearization (N- and U-PLS/RBL). U-PLS/RBL showed the best performance to quantify the herbicides, even when the foreign compounds showed very similar spectral and time profiles to the analytes. The quality of the proposed technique was assessed on the basis of the analytical recoveries from different types of water samples spiked with analytes and other selected agrochemicals. After solid-phase extraction, reaching a preconcentration factor of 50, detection limits of 2.9, 2.4, and 1.7 ng mL−1 for isoproturon, rimsulfuron, and monuron, respectively, were obtained in those interfering matrices, with relative prediction errors lower than 5%
publishDate 2014
dc.date.none.fl_str_mv 2014-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/29737
Arancibia, Juan Alberto; Escandar, Graciela Monica; Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds; Royal Society of Chemistry; Analytical Methods; 15; 8-2014; 5503-5511
1759-9660
CONICET Digital
CONICET
url http://hdl.handle.net/11336/29737
identifier_str_mv Arancibia, Juan Alberto; Escandar, Graciela Monica; Second-order chromatographic photochemically induced fluorescence emission data coupled to chemometric analysis for the simultaneous determination of urea herbicides in the presence of matrix co-eluting compounds; Royal Society of Chemistry; Analytical Methods; 15; 8-2014; 5503-5511
1759-9660
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/C4AY00705K
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/AY/C4AY00705K
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614262548332544
score 13.070432

Publicaciones similares