A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
- Autores
- Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.
Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil - Materia
-
emerging contaminants
liquid chromatography
multiway calibration
second order advantage - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/9376
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A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolutionMoreira, Edilene D.T.Pinto, LicarionGomes, Adriano A.Goicoechea, Hector CasimiroAraujo, Mario C.U.emerging contaminantsliquid chromatographymultiway calibrationsecond order advantagehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; ArgentinaFil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilSociedade Brasileira de Química2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9376Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-15820103-50531678-4790enginfo:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150125info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/7rftfminfo:eu-repo/semantics/altIdentifier/url/http://jbcs.sbq.org.br/imagebank/pdf/v26n8a05.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:31Zoai:ri.conicet.gov.ar:11336/9376instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:31.833CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
title |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
spellingShingle |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution Moreira, Edilene D.T. emerging contaminants liquid chromatography multiway calibration second order advantage |
title_short |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
title_full |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
title_fullStr |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
title_full_unstemmed |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
title_sort |
A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution |
dc.creator.none.fl_str_mv |
Moreira, Edilene D.T. Pinto, Licarion Gomes, Adriano A. Goicoechea, Hector Casimiro Araujo, Mario C.U. |
author |
Moreira, Edilene D.T. |
author_facet |
Moreira, Edilene D.T. Pinto, Licarion Gomes, Adriano A. Goicoechea, Hector Casimiro Araujo, Mario C.U. |
author_role |
author |
author2 |
Pinto, Licarion Gomes, Adriano A. Goicoechea, Hector Casimiro Araujo, Mario C.U. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
emerging contaminants liquid chromatography multiway calibration second order advantage |
topic |
emerging contaminants liquid chromatography multiway calibration second order advantage |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens. Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil Fil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil Fil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina Fil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil |
description |
This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/9376 Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-1582 0103-5053 1678-4790 |
url |
http://hdl.handle.net/11336/9376 |
identifier_str_mv |
Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-1582 0103-5053 1678-4790 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150125 info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/7rftfm info:eu-repo/semantics/altIdentifier/url/http://jbcs.sbq.org.br/imagebank/pdf/v26n8a05.pdf |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842269701543034880 |
score |
13.13397 |