A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution

Autores
Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.
Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Materia
emerging contaminants
liquid chromatography
multiway calibration
second order advantage
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/9376
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/9376
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolutionMoreira, Edilene D.T.Pinto, LicarionGomes, Adriano A.Goicoechea, Hector CasimiroAraujo, Mario C.U.emerging contaminantsliquid chromatographymultiway calibrationsecond order advantagehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilFil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; ArgentinaFil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; BrasilSociedade Brasileira de Química2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/9376Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-15820103-50531678-4790enginfo:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150125info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/7rftfminfo:eu-repo/semantics/altIdentifier/url/http://jbcs.sbq.org.br/imagebank/pdf/v26n8a05.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:15:17Zoai:ri.conicet.gov.ar:11336/9376instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:15:17.501CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
title A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
spellingShingle A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
Moreira, Edilene D.T.
emerging contaminants
liquid chromatography
multiway calibration
second order advantage
title_short A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
title_full A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
title_fullStr A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
title_full_unstemmed A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
title_sort A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution
dc.creator.none.fl_str_mv Moreira, Edilene D.T.
Pinto, Licarion
Gomes, Adriano A.
Goicoechea, Hector Casimiro
Araujo, Mario C.U.
author Moreira, Edilene D.T.
author_facet Moreira, Edilene D.T.
Pinto, Licarion
Gomes, Adriano A.
Goicoechea, Hector Casimiro
Araujo, Mario C.U.
author_role author
author2 Pinto, Licarion
Gomes, Adriano A.
Goicoechea, Hector Casimiro
Araujo, Mario C.U.
author2_role author
author
author
author
dc.subject.none.fl_str_mv emerging contaminants
liquid chromatography
multiway calibration
second order advantage
topic emerging contaminants
liquid chromatography
multiway calibration
second order advantage
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.
Fil: Moreira, Edilene D.T.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Pinto, Licarion. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Gomes, Adriano A.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Araujo, Mario C.U.. Universidade Federal da Paraíba. Departamento de Química. Laboratorio de Automacao e instrumentacao em quimica analitica e quimiometria; Brasil
description This work reports the development of a fast chromatography methodology for quantitation of two phytoestrogens: daidzein (DAI) and genistein (GEN), in river water samples. The proposed method is based on High performance liquid chromatography-diode array detection (HPLC-DAD) data, and multivariate curve resolution-alternative least square (MCR-ALS) second-order calibration. Initially, the method was evaluated analysing a synthetic validation set, prepared based on a Taguchi design. Subsequently, the method was applied to predict the concentration of the phytoestrogens in river water samples, previously pre-processed by solid phase extraction (SPE). By implementation of the present methodology, a 50 % of reduction in operation time was achieved (from 7.00 to 3.25 min) when compared with previous work in literature. Precision were achieved even in the presence non modelled constituents and strong background. Thus, it has shown that the proposed method to be abecome in a rapid and robust alternative for the quantitation of studied phytoestrogens.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/9376
Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-1582
0103-5053
1678-4790
url http://hdl.handle.net/11336/9376
identifier_str_mv Moreira, Edilene D.T.; Pinto, Licarion; Gomes, Adriano A.; Goicoechea, Hector Casimiro; Araujo, Mario C.U.; A fast chromatographic method for determination of daidzein and genistein in spiked water river samples using multivariate curve resolution; Sociedade Brasileira de Química; Journal Of The Brazilian Chemical Society; 26; 8; 4-2015; 1573-1582
0103-5053
1678-4790
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150125
info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/7rftfm
info:eu-repo/semantics/altIdentifier/url/http://jbcs.sbq.org.br/imagebank/pdf/v26n8a05.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614087816773632
score 13.069144

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