Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions

Autores
Manzi, Sergio Javier; Boscoboinik, J. A.; Belardinelli, Rolando Elio; Pereyra, Victor Daniel
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work describes a novel mechanism for phase transitions during desorption, involving the formation of lattice size dependent intermediate states when there is enough adsorbate mobility. Monte Carlo simulations are performed to analyze the mechanism of the thermal desorption for adsorbed homonuclear dimers on two-dimensional square lattices. The latticegas model with nearest-neighbor repulsive interactions between particles is implemented to study the cases of mobile (with diffusion) and immobile desorption. The number of peaks for the immobile desorption spectra is related to the connectivity of the adsorbed species for both monomer and dimer molecules. However, for the case of mobile desorption, the spectra give information about the desorption mechanism, which differs significantly for monomers and dimers, particularly when the initial temperatures correspond to the critical region.
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Boscoboinik, J. A.. University Of Wisconsin; Estados Unidos
Fil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Materia
Surface Science
Thermal Programmed Desorption
Monte Carlo
Phase Transitions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/14147
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/14147
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Sequential desorption of dimers from square lattices: A novel mechanism for phase transitionsManzi, Sergio JavierBoscoboinik, J. A.Belardinelli, Rolando ElioPereyra, Victor DanielSurface ScienceThermal Programmed DesorptionMonte CarloPhase Transitionshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1This work describes a novel mechanism for phase transitions during desorption, involving the formation of lattice size dependent intermediate states when there is enough adsorbate mobility. Monte Carlo simulations are performed to analyze the mechanism of the thermal desorption for adsorbed homonuclear dimers on two-dimensional square lattices. The latticegas model with nearest-neighbor repulsive interactions between particles is implemented to study the cases of mobile (with diffusion) and immobile desorption. The number of peaks for the immobile desorption spectra is related to the connectivity of the adsorbed species for both monomer and dimer molecules. However, for the case of mobile desorption, the spectra give information about the desorption mechanism, which differs significantly for monomers and dimers, particularly when the initial temperatures correspond to the critical region.Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: Boscoboinik, J. A.. University Of Wisconsin; Estados UnidosFil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaFil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; ArgentinaElsevier Science2010-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/14147Manzi, Sergio Javier; Boscoboinik, J. A.; Belardinelli, Rolando Elio; Pereyra, Victor Daniel; Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions; Elsevier Science; Physica A: Statistical Mechanics And Its Applications; 389; 19; 10-2010; 4116-41260378-4371enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378437110004851info:eu-repo/semantics/altIdentifier/doi/10.1016/j.physa.2010.05.055info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:46Zoai:ri.conicet.gov.ar:11336/14147instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:46.751CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
title Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
spellingShingle Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
Manzi, Sergio Javier
Surface Science
Thermal Programmed Desorption
Monte Carlo
Phase Transitions
title_short Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
title_full Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
title_fullStr Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
title_full_unstemmed Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
title_sort Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions
dc.creator.none.fl_str_mv Manzi, Sergio Javier
Boscoboinik, J. A.
Belardinelli, Rolando Elio
Pereyra, Victor Daniel
author Manzi, Sergio Javier
author_facet Manzi, Sergio Javier
Boscoboinik, J. A.
Belardinelli, Rolando Elio
Pereyra, Victor Daniel
author_role author
author2 Boscoboinik, J. A.
Belardinelli, Rolando Elio
Pereyra, Victor Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Surface Science
Thermal Programmed Desorption
Monte Carlo
Phase Transitions
topic Surface Science
Thermal Programmed Desorption
Monte Carlo
Phase Transitions
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work describes a novel mechanism for phase transitions during desorption, involving the formation of lattice size dependent intermediate states when there is enough adsorbate mobility. Monte Carlo simulations are performed to analyze the mechanism of the thermal desorption for adsorbed homonuclear dimers on two-dimensional square lattices. The latticegas model with nearest-neighbor repulsive interactions between particles is implemented to study the cases of mobile (with diffusion) and immobile desorption. The number of peaks for the immobile desorption spectra is related to the connectivity of the adsorbed species for both monomer and dimer molecules. However, for the case of mobile desorption, the spectra give information about the desorption mechanism, which differs significantly for monomers and dimers, particularly when the initial temperatures correspond to the critical region.
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Boscoboinik, J. A.. University Of Wisconsin; Estados Unidos
Fil: Belardinelli, Rolando Elio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina. Universidad Nacional de San Luis; Argentina
description This work describes a novel mechanism for phase transitions during desorption, involving the formation of lattice size dependent intermediate states when there is enough adsorbate mobility. Monte Carlo simulations are performed to analyze the mechanism of the thermal desorption for adsorbed homonuclear dimers on two-dimensional square lattices. The latticegas model with nearest-neighbor repulsive interactions between particles is implemented to study the cases of mobile (with diffusion) and immobile desorption. The number of peaks for the immobile desorption spectra is related to the connectivity of the adsorbed species for both monomer and dimer molecules. However, for the case of mobile desorption, the spectra give information about the desorption mechanism, which differs significantly for monomers and dimers, particularly when the initial temperatures correspond to the critical region.
publishDate 2010
dc.date.none.fl_str_mv 2010-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/14147
Manzi, Sergio Javier; Boscoboinik, J. A.; Belardinelli, Rolando Elio; Pereyra, Victor Daniel; Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions; Elsevier Science; Physica A: Statistical Mechanics And Its Applications; 389; 19; 10-2010; 4116-4126
0378-4371
url http://hdl.handle.net/11336/14147
identifier_str_mv Manzi, Sergio Javier; Boscoboinik, J. A.; Belardinelli, Rolando Elio; Pereyra, Victor Daniel; Sequential desorption of dimers from square lattices: A novel mechanism for phase transitions; Elsevier Science; Physica A: Statistical Mechanics And Its Applications; 389; 19; 10-2010; 4116-4126
0378-4371
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378437110004851
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.physa.2010.05.055
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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