Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles

Autores
Moscoso Londoño, Oscar; Gonzalez, Jimena Soledad; Muraca, D.; Hoppe, Cristina Elena; Alvarez, Vera Alejandra; López Quintela, A.; Socolovsky, Leandro Martin; Pirota, K. R.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Superparamagnetic ferrogels with high swelling ability and potential applications as solvent absorbers and stimuli-responsive drug delivery devices were obtained by a non-toxic and environmentally friendly route based on dispersion of poly(acrylic acid)-coated iron oxide nanoparticles (PAA-coated NPs) in poly(vinyl alcohol) (PVA) solutions followed by freezing–thawing. Presence of carboxylate groups arising from the PAA coating allowed hydrogen bonding formation between NPs and PVA and enabled the synthesis of optically homogenous, superparamagnetic materials formed by a homogenous distribution of NPs diffuse clusters in the PVA matrix. The addition of PAA-coated NPs produced a remarkable increase in crystallinity degree, thermal degradation and swelling percentage respect to the neat matrix, which demonstrates that ferrogels with improved properties can be obtained by this procedure. Thereafter, combination of a cryogenic technique with the use of non-toxic components and magnetic NPs coated by a pH sensitive polymer makes these ferrogels very promising for applications in the biomedical field.
Fil: Moscoso Londoño, Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Fisica. Laboratorio de Sólidos Amorfos; Argentina
Fil: Gonzalez, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Muraca, D.. Universidade Estadual de Campinas; Brasil
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: López Quintela, A.. Universidad de Santiago de Compostela; España;
Fil: Socolovsky, Leandro Martin. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto D/tec.y Cs.de la Ing.;
Fil: Pirota, K. R.. Universidade Estadual de Campinas; Brasil
Materia
FERROGEL
IRON OXIDES
MAGNETIC NANOPARTICLES
MAGNETIC PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2189
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2189
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticlesMoscoso Londoño, OscarGonzalez, Jimena SoledadMuraca, D.Hoppe, Cristina ElenaAlvarez, Vera AlejandraLópez Quintela, A.Socolovsky, Leandro MartinPirota, K. R.FERROGELIRON OXIDESMAGNETIC NANOPARTICLESMAGNETIC PROPERTIEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Superparamagnetic ferrogels with high swelling ability and potential applications as solvent absorbers and stimuli-responsive drug delivery devices were obtained by a non-toxic and environmentally friendly route based on dispersion of poly(acrylic acid)-coated iron oxide nanoparticles (PAA-coated NPs) in poly(vinyl alcohol) (PVA) solutions followed by freezing–thawing. Presence of carboxylate groups arising from the PAA coating allowed hydrogen bonding formation between NPs and PVA and enabled the synthesis of optically homogenous, superparamagnetic materials formed by a homogenous distribution of NPs diffuse clusters in the PVA matrix. The addition of PAA-coated NPs produced a remarkable increase in crystallinity degree, thermal degradation and swelling percentage respect to the neat matrix, which demonstrates that ferrogels with improved properties can be obtained by this procedure. Thereafter, combination of a cryogenic technique with the use of non-toxic components and magnetic NPs coated by a pH sensitive polymer makes these ferrogels very promising for applications in the biomedical field.Fil: Moscoso Londoño, Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Fisica. Laboratorio de Sólidos Amorfos; ArgentinaFil: Gonzalez, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaFil: Muraca, D.. Universidade Estadual de Campinas; BrasilFil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; ArgentinaFil: López Quintela, A.. Universidad de Santiago de Compostela; España;Fil: Socolovsky, Leandro Martin. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto D/tec.y Cs.de la Ing.;Fil: Pirota, K. R.. Universidade Estadual de Campinas; BrasilPergamon-Elsevier Science Ltd2012-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2189Moscoso Londoño, Oscar; Gonzalez, Jimena Soledad; Muraca, D.; Hoppe, Cristina Elena; Alvarez, Vera Alejandra; et al.; Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 49; 2; 1-12-2012; 279-2890014-3057enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2012.11.007info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S001430571200376Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:14Zoai:ri.conicet.gov.ar:11336/2189instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:15.024CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
title Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
spellingShingle Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
Moscoso Londoño, Oscar
FERROGEL
IRON OXIDES
MAGNETIC NANOPARTICLES
MAGNETIC PROPERTIES
title_short Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
title_full Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
title_fullStr Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
title_full_unstemmed Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
title_sort Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles
dc.creator.none.fl_str_mv Moscoso Londoño, Oscar
Gonzalez, Jimena Soledad
Muraca, D.
Hoppe, Cristina Elena
Alvarez, Vera Alejandra
López Quintela, A.
Socolovsky, Leandro Martin
Pirota, K. R.
author Moscoso Londoño, Oscar
author_facet Moscoso Londoño, Oscar
Gonzalez, Jimena Soledad
Muraca, D.
Hoppe, Cristina Elena
Alvarez, Vera Alejandra
López Quintela, A.
Socolovsky, Leandro Martin
Pirota, K. R.
author_role author
author2 Gonzalez, Jimena Soledad
Muraca, D.
Hoppe, Cristina Elena
Alvarez, Vera Alejandra
López Quintela, A.
Socolovsky, Leandro Martin
Pirota, K. R.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv FERROGEL
IRON OXIDES
MAGNETIC NANOPARTICLES
MAGNETIC PROPERTIES
topic FERROGEL
IRON OXIDES
MAGNETIC NANOPARTICLES
MAGNETIC PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Superparamagnetic ferrogels with high swelling ability and potential applications as solvent absorbers and stimuli-responsive drug delivery devices were obtained by a non-toxic and environmentally friendly route based on dispersion of poly(acrylic acid)-coated iron oxide nanoparticles (PAA-coated NPs) in poly(vinyl alcohol) (PVA) solutions followed by freezing–thawing. Presence of carboxylate groups arising from the PAA coating allowed hydrogen bonding formation between NPs and PVA and enabled the synthesis of optically homogenous, superparamagnetic materials formed by a homogenous distribution of NPs diffuse clusters in the PVA matrix. The addition of PAA-coated NPs produced a remarkable increase in crystallinity degree, thermal degradation and swelling percentage respect to the neat matrix, which demonstrates that ferrogels with improved properties can be obtained by this procedure. Thereafter, combination of a cryogenic technique with the use of non-toxic components and magnetic NPs coated by a pH sensitive polymer makes these ferrogels very promising for applications in the biomedical field.
Fil: Moscoso Londoño, Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentina. Universidad de Buenos Aires. Facultad de Ingenieria. Departamento de Fisica. Laboratorio de Sólidos Amorfos; Argentina
Fil: Gonzalez, Jimena Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Muraca, D.. Universidade Estadual de Campinas; Brasil
Fil: Hoppe, Cristina Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata; Argentina
Fil: López Quintela, A.. Universidad de Santiago de Compostela; España;
Fil: Socolovsky, Leandro Martin. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto D/tec.y Cs.de la Ing.;
Fil: Pirota, K. R.. Universidade Estadual de Campinas; Brasil
description Superparamagnetic ferrogels with high swelling ability and potential applications as solvent absorbers and stimuli-responsive drug delivery devices were obtained by a non-toxic and environmentally friendly route based on dispersion of poly(acrylic acid)-coated iron oxide nanoparticles (PAA-coated NPs) in poly(vinyl alcohol) (PVA) solutions followed by freezing–thawing. Presence of carboxylate groups arising from the PAA coating allowed hydrogen bonding formation between NPs and PVA and enabled the synthesis of optically homogenous, superparamagnetic materials formed by a homogenous distribution of NPs diffuse clusters in the PVA matrix. The addition of PAA-coated NPs produced a remarkable increase in crystallinity degree, thermal degradation and swelling percentage respect to the neat matrix, which demonstrates that ferrogels with improved properties can be obtained by this procedure. Thereafter, combination of a cryogenic technique with the use of non-toxic components and magnetic NPs coated by a pH sensitive polymer makes these ferrogels very promising for applications in the biomedical field.
publishDate 2012
dc.date.none.fl_str_mv 2012-12-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2189
Moscoso Londoño, Oscar; Gonzalez, Jimena Soledad; Muraca, D.; Hoppe, Cristina Elena; Alvarez, Vera Alejandra; et al.; Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 49; 2; 1-12-2012; 279-289
0014-3057
url http://hdl.handle.net/11336/2189
identifier_str_mv Moscoso Londoño, Oscar; Gonzalez, Jimena Soledad; Muraca, D.; Hoppe, Cristina Elena; Alvarez, Vera Alejandra; et al.; Structural and magnetic behavior of ferrogels obtained by freezing thawing of polyvinyl alcohol/poly (acrylic acid) (PAA)-coated iron oxide nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 49; 2; 1-12-2012; 279-289
0014-3057
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2012.11.007
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S001430571200376X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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