Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes
- Autores
- Pierini, Gastón Dario; Granero, Adrian Marcelo; Di Nezio, Maria Susana; Centurión, María Eugenia; Zon, María Alicia; Fernandez, Hector
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Propolis is a honeybee product which contains lead as one of the main contaminants. Taking into account that this product is used in the food industry, the Código Alimentario Argentino establishes maximum allowable level for raw propolis. Therefore, in this study an electroanalytical method to determine this metal in Argentina raw propolis samples was developed. A bismuth film electrode plated on a modified glassy carbon electrode was prepared. The use of these electrodes has been proposed as an alternative to mercury film electrodes in electroanalytical chemistry due to low toxicity of bismuth (environmentally friendly metal). The method presents a linear range between 1 and 50 μg L− 1 of Pb(II). The limits of detection and quantification were 0.6 μg L− 1 and 1.84 μg L− 1, respectively. The reproducibility and repeatability calculated as the relative standard deviations were 7.4% and 7.0%, respectively. The sample throughput was 21 sample h− 1. Argentina raw propolis samples were analyzed and some of them showed high levels of lead. The obtained results with this method are in good agreement with that obtained with the ICP-AES technique. Moreover, it is a good alternative to the quality control of raw propolis.
Fil: Pierini, Gastón Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Granero, Adrian Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Zon, María Alicia. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Fernandez, Hector. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina - Materia
-
Propolis
Lead Determination
Bismuth Electrode
Electroanalysis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/22780
Ver los metadatos del registro completo
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Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodesPierini, Gastón DarioGranero, Adrian MarceloDi Nezio, Maria SusanaCenturión, María EugeniaZon, María AliciaFernandez, HectorPropolisLead DeterminationBismuth ElectrodeElectroanalysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Propolis is a honeybee product which contains lead as one of the main contaminants. Taking into account that this product is used in the food industry, the Código Alimentario Argentino establishes maximum allowable level for raw propolis. Therefore, in this study an electroanalytical method to determine this metal in Argentina raw propolis samples was developed. A bismuth film electrode plated on a modified glassy carbon electrode was prepared. The use of these electrodes has been proposed as an alternative to mercury film electrodes in electroanalytical chemistry due to low toxicity of bismuth (environmentally friendly metal). The method presents a linear range between 1 and 50 μg L− 1 of Pb(II). The limits of detection and quantification were 0.6 μg L− 1 and 1.84 μg L− 1, respectively. The reproducibility and repeatability calculated as the relative standard deviations were 7.4% and 7.0%, respectively. The sample throughput was 21 sample h− 1. Argentina raw propolis samples were analyzed and some of them showed high levels of lead. The obtained results with this method are in good agreement with that obtained with the ICP-AES technique. Moreover, it is a good alternative to the quality control of raw propolis.Fil: Pierini, Gastón Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Granero, Adrian Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Zon, María Alicia. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Fernandez, Hector. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/22780Pierini, Gastón Dario; Granero, Adrian Marcelo; Di Nezio, Maria Susana; Centurión, María Eugenia; Zon, María Alicia; et al.; Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes; Elsevier Science; Microchemical Journal; 106; 5-2012; 102-1060026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.05.015info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12001336info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:45Zoai:ri.conicet.gov.ar:11336/22780instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:45.706CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
title |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
spellingShingle |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes Pierini, Gastón Dario Propolis Lead Determination Bismuth Electrode Electroanalysis |
title_short |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
title_full |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
title_fullStr |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
title_full_unstemmed |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
title_sort |
Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes |
dc.creator.none.fl_str_mv |
Pierini, Gastón Dario Granero, Adrian Marcelo Di Nezio, Maria Susana Centurión, María Eugenia Zon, María Alicia Fernandez, Hector |
author |
Pierini, Gastón Dario |
author_facet |
Pierini, Gastón Dario Granero, Adrian Marcelo Di Nezio, Maria Susana Centurión, María Eugenia Zon, María Alicia Fernandez, Hector |
author_role |
author |
author2 |
Granero, Adrian Marcelo Di Nezio, Maria Susana Centurión, María Eugenia Zon, María Alicia Fernandez, Hector |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Propolis Lead Determination Bismuth Electrode Electroanalysis |
topic |
Propolis Lead Determination Bismuth Electrode Electroanalysis |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Propolis is a honeybee product which contains lead as one of the main contaminants. Taking into account that this product is used in the food industry, the Código Alimentario Argentino establishes maximum allowable level for raw propolis. Therefore, in this study an electroanalytical method to determine this metal in Argentina raw propolis samples was developed. A bismuth film electrode plated on a modified glassy carbon electrode was prepared. The use of these electrodes has been proposed as an alternative to mercury film electrodes in electroanalytical chemistry due to low toxicity of bismuth (environmentally friendly metal). The method presents a linear range between 1 and 50 μg L− 1 of Pb(II). The limits of detection and quantification were 0.6 μg L− 1 and 1.84 μg L− 1, respectively. The reproducibility and repeatability calculated as the relative standard deviations were 7.4% and 7.0%, respectively. The sample throughput was 21 sample h− 1. Argentina raw propolis samples were analyzed and some of them showed high levels of lead. The obtained results with this method are in good agreement with that obtained with the ICP-AES technique. Moreover, it is a good alternative to the quality control of raw propolis. Fil: Pierini, Gastón Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Granero, Adrian Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Zon, María Alicia. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Fernandez, Hector. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
description |
Propolis is a honeybee product which contains lead as one of the main contaminants. Taking into account that this product is used in the food industry, the Código Alimentario Argentino establishes maximum allowable level for raw propolis. Therefore, in this study an electroanalytical method to determine this metal in Argentina raw propolis samples was developed. A bismuth film electrode plated on a modified glassy carbon electrode was prepared. The use of these electrodes has been proposed as an alternative to mercury film electrodes in electroanalytical chemistry due to low toxicity of bismuth (environmentally friendly metal). The method presents a linear range between 1 and 50 μg L− 1 of Pb(II). The limits of detection and quantification were 0.6 μg L− 1 and 1.84 μg L− 1, respectively. The reproducibility and repeatability calculated as the relative standard deviations were 7.4% and 7.0%, respectively. The sample throughput was 21 sample h− 1. Argentina raw propolis samples were analyzed and some of them showed high levels of lead. The obtained results with this method are in good agreement with that obtained with the ICP-AES technique. Moreover, it is a good alternative to the quality control of raw propolis. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/22780 Pierini, Gastón Dario; Granero, Adrian Marcelo; Di Nezio, Maria Susana; Centurión, María Eugenia; Zon, María Alicia; et al.; Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes; Elsevier Science; Microchemical Journal; 106; 5-2012; 102-106 0026-265X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/22780 |
identifier_str_mv |
Pierini, Gastón Dario; Granero, Adrian Marcelo; Di Nezio, Maria Susana; Centurión, María Eugenia; Zon, María Alicia; et al.; Development of an electroanalytical method for the determination of lead in Argentina raw propolis based on bismuth electrodes; Elsevier Science; Microchemical Journal; 106; 5-2012; 102-106 0026-265X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.05.015 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12001336 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |