Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode
- Autores
- Krepper, Gabriela; Resende de Cerqueira, Paula B.; Pistonesi, Marcelo Fabian; Di Nezio, Maria Susana; Centurión, María Eugenia
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Raw propolis and bee pollen has been widely used in different areas such as medicine, food and apitherapy because they have biological and medicinal properties. The beneficial effects of both bee products for human health include antibacterial, antiviral, antimicrobial and anti-inflammatory properties. However, hives exposure to heavy metals, due beekeeping practices and environment, is one of the problems facing beekeepers. The presence of cadmium in bee products should be controlled, because of its high toxicity. A lab-made Bismuth Bulk Electrode (BiBE) was developed for cadmium residue determination in Argentinean bee products such as raw propolis and bee pollen employing square wave anodic stripping voltammetry (SWASV) as electrochemical technique. The SWASV parameters were optimised based on a 2 5 factorial design. The method presents a linear range from 2.00 to 100.0 µg L−1 of Cd (II) with a limit of detection (LOD) and a limit of quantitation (LOQ) of 0.78 µg L−1 and 2.61 µg L−1, respectively. The repeatability was 8.03%, calculated as the relative standard deviation. Recovery experiments were performed using spiked raw propolis and bee pollen samples with standard deviation values from 1.16% to 7.20%. The BiBE is easy and fast to elaborate and the propose method is environmentally friendly and low cost. Then, it can be considered as a good alternative to the quality control of bee products due to its importance in the beekeeping industry.
Fil: Krepper, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Resende de Cerqueira, Paula B.. Universidade Federal de Minas Gerais; Brasil
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina - Materia
-
Bee Pollen
Bismuth Bulk Electrode
Cadmium
Environmental Quality Control
Raw Propolis
Square Wave Anodic Stripping Voltammetry - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/55766
Ver los metadatos del registro completo
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Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrodeKrepper, GabrielaResende de Cerqueira, Paula B.Pistonesi, Marcelo FabianDi Nezio, Maria SusanaCenturión, María EugeniaBee PollenBismuth Bulk ElectrodeCadmiumEnvironmental Quality ControlRaw PropolisSquare Wave Anodic Stripping Voltammetryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Raw propolis and bee pollen has been widely used in different areas such as medicine, food and apitherapy because they have biological and medicinal properties. The beneficial effects of both bee products for human health include antibacterial, antiviral, antimicrobial and anti-inflammatory properties. However, hives exposure to heavy metals, due beekeeping practices and environment, is one of the problems facing beekeepers. The presence of cadmium in bee products should be controlled, because of its high toxicity. A lab-made Bismuth Bulk Electrode (BiBE) was developed for cadmium residue determination in Argentinean bee products such as raw propolis and bee pollen employing square wave anodic stripping voltammetry (SWASV) as electrochemical technique. The SWASV parameters were optimised based on a 2 5 factorial design. The method presents a linear range from 2.00 to 100.0 µg L−1 of Cd (II) with a limit of detection (LOD) and a limit of quantitation (LOQ) of 0.78 µg L−1 and 2.61 µg L−1, respectively. The repeatability was 8.03%, calculated as the relative standard deviation. Recovery experiments were performed using spiked raw propolis and bee pollen samples with standard deviation values from 1.16% to 7.20%. The BiBE is easy and fast to elaborate and the propose method is environmentally friendly and low cost. Then, it can be considered as a good alternative to the quality control of bee products due to its importance in the beekeeping industry.Fil: Krepper, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Resende de Cerqueira, Paula B.. Universidade Federal de Minas Gerais; BrasilFil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaTaylor & Francis Ltd2016-11-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55766Krepper, Gabriela; Resende de Cerqueira, Paula B.; Pistonesi, Marcelo Fabian; Di Nezio, Maria Susana; Centurión, María Eugenia; Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode; Taylor & Francis Ltd; International Journal of Environmental Analytical Chemistry; 96; 14; 4-11-2016; 1331-13400306-7319CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/03067319.2016.1250893info:eu-repo/semantics/altIdentifier/doi/10.1080/03067319.2016.1250893info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:21:00Zoai:ri.conicet.gov.ar:11336/55766instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:21:01.263CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| title |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| spellingShingle |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode Krepper, Gabriela Bee Pollen Bismuth Bulk Electrode Cadmium Environmental Quality Control Raw Propolis Square Wave Anodic Stripping Voltammetry |
| title_short |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| title_full |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| title_fullStr |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| title_full_unstemmed |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| title_sort |
Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode |
| dc.creator.none.fl_str_mv |
Krepper, Gabriela Resende de Cerqueira, Paula B. Pistonesi, Marcelo Fabian Di Nezio, Maria Susana Centurión, María Eugenia |
| author |
Krepper, Gabriela |
| author_facet |
Krepper, Gabriela Resende de Cerqueira, Paula B. Pistonesi, Marcelo Fabian Di Nezio, Maria Susana Centurión, María Eugenia |
| author_role |
author |
| author2 |
Resende de Cerqueira, Paula B. Pistonesi, Marcelo Fabian Di Nezio, Maria Susana Centurión, María Eugenia |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Bee Pollen Bismuth Bulk Electrode Cadmium Environmental Quality Control Raw Propolis Square Wave Anodic Stripping Voltammetry |
| topic |
Bee Pollen Bismuth Bulk Electrode Cadmium Environmental Quality Control Raw Propolis Square Wave Anodic Stripping Voltammetry |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
Raw propolis and bee pollen has been widely used in different areas such as medicine, food and apitherapy because they have biological and medicinal properties. The beneficial effects of both bee products for human health include antibacterial, antiviral, antimicrobial and anti-inflammatory properties. However, hives exposure to heavy metals, due beekeeping practices and environment, is one of the problems facing beekeepers. The presence of cadmium in bee products should be controlled, because of its high toxicity. A lab-made Bismuth Bulk Electrode (BiBE) was developed for cadmium residue determination in Argentinean bee products such as raw propolis and bee pollen employing square wave anodic stripping voltammetry (SWASV) as electrochemical technique. The SWASV parameters were optimised based on a 2 5 factorial design. The method presents a linear range from 2.00 to 100.0 µg L−1 of Cd (II) with a limit of detection (LOD) and a limit of quantitation (LOQ) of 0.78 µg L−1 and 2.61 µg L−1, respectively. The repeatability was 8.03%, calculated as the relative standard deviation. Recovery experiments were performed using spiked raw propolis and bee pollen samples with standard deviation values from 1.16% to 7.20%. The BiBE is easy and fast to elaborate and the propose method is environmentally friendly and low cost. Then, it can be considered as a good alternative to the quality control of bee products due to its importance in the beekeeping industry. Fil: Krepper, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Resende de Cerqueira, Paula B.. Universidade Federal de Minas Gerais; Brasil Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Di Nezio, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Centurión, María Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina |
| description |
Raw propolis and bee pollen has been widely used in different areas such as medicine, food and apitherapy because they have biological and medicinal properties. The beneficial effects of both bee products for human health include antibacterial, antiviral, antimicrobial and anti-inflammatory properties. However, hives exposure to heavy metals, due beekeeping practices and environment, is one of the problems facing beekeepers. The presence of cadmium in bee products should be controlled, because of its high toxicity. A lab-made Bismuth Bulk Electrode (BiBE) was developed for cadmium residue determination in Argentinean bee products such as raw propolis and bee pollen employing square wave anodic stripping voltammetry (SWASV) as electrochemical technique. The SWASV parameters were optimised based on a 2 5 factorial design. The method presents a linear range from 2.00 to 100.0 µg L−1 of Cd (II) with a limit of detection (LOD) and a limit of quantitation (LOQ) of 0.78 µg L−1 and 2.61 µg L−1, respectively. The repeatability was 8.03%, calculated as the relative standard deviation. Recovery experiments were performed using spiked raw propolis and bee pollen samples with standard deviation values from 1.16% to 7.20%. The BiBE is easy and fast to elaborate and the propose method is environmentally friendly and low cost. Then, it can be considered as a good alternative to the quality control of bee products due to its importance in the beekeeping industry. |
| publishDate |
2016 |
| dc.date.none.fl_str_mv |
2016-11-04 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/55766 Krepper, Gabriela; Resende de Cerqueira, Paula B.; Pistonesi, Marcelo Fabian; Di Nezio, Maria Susana; Centurión, María Eugenia; Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode; Taylor & Francis Ltd; International Journal of Environmental Analytical Chemistry; 96; 14; 4-11-2016; 1331-1340 0306-7319 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/55766 |
| identifier_str_mv |
Krepper, Gabriela; Resende de Cerqueira, Paula B.; Pistonesi, Marcelo Fabian; Di Nezio, Maria Susana; Centurión, María Eugenia; Determination of cadmium residues in bee products using a "lab-made" bismuth bulk electrode; Taylor & Francis Ltd; International Journal of Environmental Analytical Chemistry; 96; 14; 4-11-2016; 1331-1340 0306-7319 CONICET Digital CONICET |
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eng |
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eng |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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