Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking

Autores
Schnell, Carla Natali; Tarrés, Quim; Galván, María Verónica; Mocchiutti, Paulina; Delgado Aguilar, Marc; Zanuttini, Miguel Angel Mario; Mutjé, Pere
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel procedure based on the addition of polyelectrolyte complexes (PECs) onto the pulp containing lignocellulosic micro/nanofibers (LCMNF) is presented. This procedure allows increasing paper strength avoiding an excessive loss in drainability. LCMNF were obtained from partially delignified kraft pine sawdust using a high-pressure homogenizer. Cationic complexes (CatPECs) were prepared by adding the anionic polyelectrolyte solution (polyacrylic acid) on the cationic polyelectrolyte solution (poly(allylamine hydrochloride)). According to turbidity and surface morphology changes, an interaction between CatPECs and LCMNF could be established. Different CatPEC dosages (from 0.3 to 1.0% on pulp) were added on a recycled unbleached softwood kraft pulp containing 3% of LCMNF. For a PEC dosage of 0.75% on pulp, an optimum balances between negatively and positively charged materials [near to zero value of the logarithm of the colloidal titration ratio (logCTR)] was found. Britt Dynamic Drainage Jar test showed a high retention of fines and LCMNF for all PEC dosages. A maximum in retention value was obtained for the addition of 0.75% of PECs on pulp, dosage that was suggested as optimum by the logCTR. In addition, the best drainability value (18°SR) was obtained for this PEC addition level. Papermaking properties were clearly improved for all dosage of PECs. Particularly for a dosage of 0.75% of PECs on pulp, tensile strength was noticeably increased (+48%) and both compressive resistance Concora Medium Test (CMT) and Short-span Compressive Test (SCT) were markedly increased (+64% and +39%, respectively). These results suggest that PECs are a possible alternative to assist the application of LCMNF in papermaking.
Fil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Tarrés, Quim. Universidad de Girona; España
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Delgado Aguilar, Marc. Universidad de Girona; España
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mutjé, Pere. Universidad de Girona; España
Materia
CELLULOSIC NANOMATERIALS
COLLOIDAL CHARGE
POLY(ALLYLAMINE HYDROCHLORIDE)
POLYACRYLIC ACID
POLYELECTROLYTES
RECYCLED PAPER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/153331
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/153331
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermakingSchnell, Carla NataliTarrés, QuimGalván, María VerónicaMocchiutti, PaulinaDelgado Aguilar, MarcZanuttini, Miguel Angel MarioMutjé, PereCELLULOSIC NANOMATERIALSCOLLOIDAL CHARGEPOLY(ALLYLAMINE HYDROCHLORIDE)POLYACRYLIC ACIDPOLYELECTROLYTESRECYCLED PAPERhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A novel procedure based on the addition of polyelectrolyte complexes (PECs) onto the pulp containing lignocellulosic micro/nanofibers (LCMNF) is presented. This procedure allows increasing paper strength avoiding an excessive loss in drainability. LCMNF were obtained from partially delignified kraft pine sawdust using a high-pressure homogenizer. Cationic complexes (CatPECs) were prepared by adding the anionic polyelectrolyte solution (polyacrylic acid) on the cationic polyelectrolyte solution (poly(allylamine hydrochloride)). According to turbidity and surface morphology changes, an interaction between CatPECs and LCMNF could be established. Different CatPEC dosages (from 0.3 to 1.0% on pulp) were added on a recycled unbleached softwood kraft pulp containing 3% of LCMNF. For a PEC dosage of 0.75% on pulp, an optimum balances between negatively and positively charged materials [near to zero value of the logarithm of the colloidal titration ratio (logCTR)] was found. Britt Dynamic Drainage Jar test showed a high retention of fines and LCMNF for all PEC dosages. A maximum in retention value was obtained for the addition of 0.75% of PECs on pulp, dosage that was suggested as optimum by the logCTR. In addition, the best drainability value (18°SR) was obtained for this PEC addition level. Papermaking properties were clearly improved for all dosage of PECs. Particularly for a dosage of 0.75% of PECs on pulp, tensile strength was noticeably increased (+48%) and both compressive resistance Concora Medium Test (CMT) and Short-span Compressive Test (SCT) were markedly increased (+64% and +39%, respectively). These results suggest that PECs are a possible alternative to assist the application of LCMNF in papermaking.Fil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Tarrés, Quim. Universidad de Girona; EspañaFil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Delgado Aguilar, Marc. Universidad de Girona; EspañaFil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Mutjé, Pere. Universidad de Girona; EspañaSpringer2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/153331Schnell, Carla Natali; Tarrés, Quim; Galván, María Verónica; Mocchiutti, Paulina; Delgado Aguilar, Marc; et al.; Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking; Springer; Cellulose (london); 25; 10; 8-2018; 6083-60920969-0239CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s10570-018-1969-yinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10570-018-1969-yinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:08:33Zoai:ri.conicet.gov.ar:11336/153331instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:08:33.763CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
title Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
spellingShingle Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
Schnell, Carla Natali
CELLULOSIC NANOMATERIALS
COLLOIDAL CHARGE
POLY(ALLYLAMINE HYDROCHLORIDE)
POLYACRYLIC ACID
POLYELECTROLYTES
RECYCLED PAPER
title_short Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
title_full Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
title_fullStr Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
title_full_unstemmed Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
title_sort Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking
dc.creator.none.fl_str_mv Schnell, Carla Natali
Tarrés, Quim
Galván, María Verónica
Mocchiutti, Paulina
Delgado Aguilar, Marc
Zanuttini, Miguel Angel Mario
Mutjé, Pere
author Schnell, Carla Natali
author_facet Schnell, Carla Natali
Tarrés, Quim
Galván, María Verónica
Mocchiutti, Paulina
Delgado Aguilar, Marc
Zanuttini, Miguel Angel Mario
Mutjé, Pere
author_role author
author2 Tarrés, Quim
Galván, María Verónica
Mocchiutti, Paulina
Delgado Aguilar, Marc
Zanuttini, Miguel Angel Mario
Mutjé, Pere
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv CELLULOSIC NANOMATERIALS
COLLOIDAL CHARGE
POLY(ALLYLAMINE HYDROCHLORIDE)
POLYACRYLIC ACID
POLYELECTROLYTES
RECYCLED PAPER
topic CELLULOSIC NANOMATERIALS
COLLOIDAL CHARGE
POLY(ALLYLAMINE HYDROCHLORIDE)
POLYACRYLIC ACID
POLYELECTROLYTES
RECYCLED PAPER
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A novel procedure based on the addition of polyelectrolyte complexes (PECs) onto the pulp containing lignocellulosic micro/nanofibers (LCMNF) is presented. This procedure allows increasing paper strength avoiding an excessive loss in drainability. LCMNF were obtained from partially delignified kraft pine sawdust using a high-pressure homogenizer. Cationic complexes (CatPECs) were prepared by adding the anionic polyelectrolyte solution (polyacrylic acid) on the cationic polyelectrolyte solution (poly(allylamine hydrochloride)). According to turbidity and surface morphology changes, an interaction between CatPECs and LCMNF could be established. Different CatPEC dosages (from 0.3 to 1.0% on pulp) were added on a recycled unbleached softwood kraft pulp containing 3% of LCMNF. For a PEC dosage of 0.75% on pulp, an optimum balances between negatively and positively charged materials [near to zero value of the logarithm of the colloidal titration ratio (logCTR)] was found. Britt Dynamic Drainage Jar test showed a high retention of fines and LCMNF for all PEC dosages. A maximum in retention value was obtained for the addition of 0.75% of PECs on pulp, dosage that was suggested as optimum by the logCTR. In addition, the best drainability value (18°SR) was obtained for this PEC addition level. Papermaking properties were clearly improved for all dosage of PECs. Particularly for a dosage of 0.75% of PECs on pulp, tensile strength was noticeably increased (+48%) and both compressive resistance Concora Medium Test (CMT) and Short-span Compressive Test (SCT) were markedly increased (+64% and +39%, respectively). These results suggest that PECs are a possible alternative to assist the application of LCMNF in papermaking.
Fil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Tarrés, Quim. Universidad de Girona; España
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Delgado Aguilar, Marc. Universidad de Girona; España
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mutjé, Pere. Universidad de Girona; España
description A novel procedure based on the addition of polyelectrolyte complexes (PECs) onto the pulp containing lignocellulosic micro/nanofibers (LCMNF) is presented. This procedure allows increasing paper strength avoiding an excessive loss in drainability. LCMNF were obtained from partially delignified kraft pine sawdust using a high-pressure homogenizer. Cationic complexes (CatPECs) were prepared by adding the anionic polyelectrolyte solution (polyacrylic acid) on the cationic polyelectrolyte solution (poly(allylamine hydrochloride)). According to turbidity and surface morphology changes, an interaction between CatPECs and LCMNF could be established. Different CatPEC dosages (from 0.3 to 1.0% on pulp) were added on a recycled unbleached softwood kraft pulp containing 3% of LCMNF. For a PEC dosage of 0.75% on pulp, an optimum balances between negatively and positively charged materials [near to zero value of the logarithm of the colloidal titration ratio (logCTR)] was found. Britt Dynamic Drainage Jar test showed a high retention of fines and LCMNF for all PEC dosages. A maximum in retention value was obtained for the addition of 0.75% of PECs on pulp, dosage that was suggested as optimum by the logCTR. In addition, the best drainability value (18°SR) was obtained for this PEC addition level. Papermaking properties were clearly improved for all dosage of PECs. Particularly for a dosage of 0.75% of PECs on pulp, tensile strength was noticeably increased (+48%) and both compressive resistance Concora Medium Test (CMT) and Short-span Compressive Test (SCT) were markedly increased (+64% and +39%, respectively). These results suggest that PECs are a possible alternative to assist the application of LCMNF in papermaking.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/153331
Schnell, Carla Natali; Tarrés, Quim; Galván, María Verónica; Mocchiutti, Paulina; Delgado Aguilar, Marc; et al.; Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking; Springer; Cellulose (london); 25; 10; 8-2018; 6083-6092
0969-0239
CONICET Digital
CONICET
url http://hdl.handle.net/11336/153331
identifier_str_mv Schnell, Carla Natali; Tarrés, Quim; Galván, María Verónica; Mocchiutti, Paulina; Delgado Aguilar, Marc; et al.; Polyelectrolyte complexes for assisting the application of lignocellulosic micro/nanofibers in papermaking; Springer; Cellulose (london); 25; 10; 8-2018; 6083-6092
0969-0239
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s10570-018-1969-y
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10570-018-1969-y
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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