Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers

Autores
Galván, María Verónica; Mocchiutti, Paulina; Schnell, Carla Natali; Liimets, Tiina; Zanuttini, Miguel Angel Mario
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effects of the dual-polyelectrolyte adsorption of poly(allylamine hydrochloride) (PAH) and lignosulfonate (LS) on a recycled unbleached softwood kraft pulp were studied and the method used for the determination of LS concentration was discussed. Adsorption isotherms of LS on untreated and on previously PAH-treated pulps at neutral pH, and different ionic strengths were built, and the effects of the amount of PAH on LS adsorption were considered. It was found that even at low dosages of PAH, for which fibers remain anionic, high levels of LS adsorption at room temperature and short adsorption time can be achieved. Besides, it was found that the increase in ionic strength also increased the amount of LS adsorbed. The highest values on papermaking properties were obtained using only PAH. Nevertheless, when compared to the reference pulp, the PAH/LS system clearly improved the wet tensile strength and the compressive strength, avoiding paper non-uniformity or charge-reversal problems.
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Liimets, Tiina. Vtt Technical Research Centre Of Finland; Finlandia
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Materia
RECYCLED UNBLEACHED SOFTWOOD KRAFT PULPS
DUAL-POLYMER TREATMENT
POLY(ALLYLAMINE HYDROCHLORIDE)
LIGNOSULFONATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/96500

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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibersGalván, María VerónicaMocchiutti, PaulinaSchnell, Carla NataliLiimets, TiinaZanuttini, Miguel Angel MarioRECYCLED UNBLEACHED SOFTWOOD KRAFT PULPSDUAL-POLYMER TREATMENTPOLY(ALLYLAMINE HYDROCHLORIDE)LIGNOSULFONATEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The effects of the dual-polyelectrolyte adsorption of poly(allylamine hydrochloride) (PAH) and lignosulfonate (LS) on a recycled unbleached softwood kraft pulp were studied and the method used for the determination of LS concentration was discussed. Adsorption isotherms of LS on untreated and on previously PAH-treated pulps at neutral pH, and different ionic strengths were built, and the effects of the amount of PAH on LS adsorption were considered. It was found that even at low dosages of PAH, for which fibers remain anionic, high levels of LS adsorption at room temperature and short adsorption time can be achieved. Besides, it was found that the increase in ionic strength also increased the amount of LS adsorbed. The highest values on papermaking properties were obtained using only PAH. Nevertheless, when compared to the reference pulp, the PAH/LS system clearly improved the wet tensile strength and the compressive strength, avoiding paper non-uniformity or charge-reversal problems.Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; ArgentinaFil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; ArgentinaFil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; ArgentinaFil: Liimets, Tiina. Vtt Technical Research Centre Of Finland; FinlandiaFil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; ArgentinaEditura Acad Romane2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96500Galván, María Verónica; Mocchiutti, Paulina; Schnell, Carla Natali; Liimets, Tiina; Zanuttini, Miguel Angel Mario; Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers; Editura Acad Romane; Cellulose Chemistry And Technology; 47; 7; 4-2013; 631-6410576-9787CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.roinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:02Zoai:ri.conicet.gov.ar:11336/96500instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:02.696CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
title Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
spellingShingle Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
Galván, María Verónica
RECYCLED UNBLEACHED SOFTWOOD KRAFT PULPS
DUAL-POLYMER TREATMENT
POLY(ALLYLAMINE HYDROCHLORIDE)
LIGNOSULFONATE
title_short Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
title_full Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
title_fullStr Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
title_full_unstemmed Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
title_sort Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers
dc.creator.none.fl_str_mv Galván, María Verónica
Mocchiutti, Paulina
Schnell, Carla Natali
Liimets, Tiina
Zanuttini, Miguel Angel Mario
author Galván, María Verónica
author_facet Galván, María Verónica
Mocchiutti, Paulina
Schnell, Carla Natali
Liimets, Tiina
Zanuttini, Miguel Angel Mario
author_role author
author2 Mocchiutti, Paulina
Schnell, Carla Natali
Liimets, Tiina
Zanuttini, Miguel Angel Mario
author2_role author
author
author
author
dc.subject.none.fl_str_mv RECYCLED UNBLEACHED SOFTWOOD KRAFT PULPS
DUAL-POLYMER TREATMENT
POLY(ALLYLAMINE HYDROCHLORIDE)
LIGNOSULFONATE
topic RECYCLED UNBLEACHED SOFTWOOD KRAFT PULPS
DUAL-POLYMER TREATMENT
POLY(ALLYLAMINE HYDROCHLORIDE)
LIGNOSULFONATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effects of the dual-polyelectrolyte adsorption of poly(allylamine hydrochloride) (PAH) and lignosulfonate (LS) on a recycled unbleached softwood kraft pulp were studied and the method used for the determination of LS concentration was discussed. Adsorption isotherms of LS on untreated and on previously PAH-treated pulps at neutral pH, and different ionic strengths were built, and the effects of the amount of PAH on LS adsorption were considered. It was found that even at low dosages of PAH, for which fibers remain anionic, high levels of LS adsorption at room temperature and short adsorption time can be achieved. Besides, it was found that the increase in ionic strength also increased the amount of LS adsorbed. The highest values on papermaking properties were obtained using only PAH. Nevertheless, when compared to the reference pulp, the PAH/LS system clearly improved the wet tensile strength and the compressive strength, avoiding paper non-uniformity or charge-reversal problems.
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Mocchiutti, Paulina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Schnell, Carla Natali. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
Fil: Liimets, Tiina. Vtt Technical Research Centre Of Finland; Finlandia
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Instituto de Tecnología Celulósica; Argentina
description The effects of the dual-polyelectrolyte adsorption of poly(allylamine hydrochloride) (PAH) and lignosulfonate (LS) on a recycled unbleached softwood kraft pulp were studied and the method used for the determination of LS concentration was discussed. Adsorption isotherms of LS on untreated and on previously PAH-treated pulps at neutral pH, and different ionic strengths were built, and the effects of the amount of PAH on LS adsorption were considered. It was found that even at low dosages of PAH, for which fibers remain anionic, high levels of LS adsorption at room temperature and short adsorption time can be achieved. Besides, it was found that the increase in ionic strength also increased the amount of LS adsorbed. The highest values on papermaking properties were obtained using only PAH. Nevertheless, when compared to the reference pulp, the PAH/LS system clearly improved the wet tensile strength and the compressive strength, avoiding paper non-uniformity or charge-reversal problems.
publishDate 2013
dc.date.none.fl_str_mv 2013-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/96500
Galván, María Verónica; Mocchiutti, Paulina; Schnell, Carla Natali; Liimets, Tiina; Zanuttini, Miguel Angel Mario; Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers; Editura Acad Romane; Cellulose Chemistry And Technology; 47; 7; 4-2013; 631-641
0576-9787
CONICET Digital
CONICET
url http://hdl.handle.net/11336/96500
identifier_str_mv Galván, María Verónica; Mocchiutti, Paulina; Schnell, Carla Natali; Liimets, Tiina; Zanuttini, Miguel Angel Mario; Dual-adsorption of poly(allylamine hydrochloride) and lignosulfonate onto recycled cellulosic fibers; Editura Acad Romane; Cellulose Chemistry And Technology; 47; 7; 4-2013; 631-641
0576-9787
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.ro
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Editura Acad Romane
publisher.none.fl_str_mv Editura Acad Romane
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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