Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
- Autores
- Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; Dalla Costa, Bruno Oscar; Querini, Carlos Alberto
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.
Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
2-METHYLFURAN
BIOMASS
C-C COUPLING
FURFURAL
SBA-15 - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/226198
Ver los metadatos del registro completo
id |
CONICETDig_81fd0d71e0a53b7226f2a0bf56bbd2fa |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/226198 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalystsZanuttini, María SoledadTonutti, Lucas GabrielNeyertz, Claudia A.Ferretti, Cristián AlejandroSanchez, Barbara SabrinaDalla Costa, Bruno OscarQuerini, Carlos Alberto2-METHYLFURANBIOMASSC-C COUPLINGFURFURALSBA-15https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226198Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-1193970926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926860X23003630info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2023.119383info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:38:05Zoai:ri.conicet.gov.ar:11336/226198instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:05.991CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
title |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
spellingShingle |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts Zanuttini, María Soledad 2-METHYLFURAN BIOMASS C-C COUPLING FURFURAL SBA-15 |
title_short |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
title_full |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
title_fullStr |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
title_full_unstemmed |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
title_sort |
Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts |
dc.creator.none.fl_str_mv |
Zanuttini, María Soledad Tonutti, Lucas Gabriel Neyertz, Claudia A. Ferretti, Cristián Alejandro Sanchez, Barbara Sabrina Dalla Costa, Bruno Oscar Querini, Carlos Alberto |
author |
Zanuttini, María Soledad |
author_facet |
Zanuttini, María Soledad Tonutti, Lucas Gabriel Neyertz, Claudia A. Ferretti, Cristián Alejandro Sanchez, Barbara Sabrina Dalla Costa, Bruno Oscar Querini, Carlos Alberto |
author_role |
author |
author2 |
Tonutti, Lucas Gabriel Neyertz, Claudia A. Ferretti, Cristián Alejandro Sanchez, Barbara Sabrina Dalla Costa, Bruno Oscar Querini, Carlos Alberto |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
2-METHYLFURAN BIOMASS C-C COUPLING FURFURAL SBA-15 |
topic |
2-METHYLFURAN BIOMASS C-C COUPLING FURFURAL SBA-15 |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles. Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina Fil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/226198 Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-119397 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/226198 |
identifier_str_mv |
Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-119397 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926860X23003630 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2023.119383 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614402431516672 |
score |
13.070432 |