Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts

Autores
Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; Dalla Costa, Bruno Oscar; Querini, Carlos Alberto
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.
Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
2-METHYLFURAN
BIOMASS
C-C COUPLING
FURFURAL
SBA-15
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226198
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/226198
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalystsZanuttini, María SoledadTonutti, Lucas GabrielNeyertz, Claudia A.Ferretti, Cristián AlejandroSanchez, Barbara SabrinaDalla Costa, Bruno OscarQuerini, Carlos Alberto2-METHYLFURANBIOMASSC-C COUPLINGFURFURALSBA-15https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2023-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226198Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-1193970926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926860X23003630info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2023.119383info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:10:13Zoai:ri.conicet.gov.ar:11336/226198instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:10:13.988CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
title Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
spellingShingle Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
Zanuttini, María Soledad
2-METHYLFURAN
BIOMASS
C-C COUPLING
FURFURAL
SBA-15
title_short Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
title_full Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
title_fullStr Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
title_full_unstemmed Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
title_sort Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts
dc.creator.none.fl_str_mv Zanuttini, María Soledad
Tonutti, Lucas Gabriel
Neyertz, Claudia A.
Ferretti, Cristián Alejandro
Sanchez, Barbara Sabrina
Dalla Costa, Bruno Oscar
Querini, Carlos Alberto
author Zanuttini, María Soledad
author_facet Zanuttini, María Soledad
Tonutti, Lucas Gabriel
Neyertz, Claudia A.
Ferretti, Cristián Alejandro
Sanchez, Barbara Sabrina
Dalla Costa, Bruno Oscar
Querini, Carlos Alberto
author_role author
author2 Tonutti, Lucas Gabriel
Neyertz, Claudia A.
Ferretti, Cristián Alejandro
Sanchez, Barbara Sabrina
Dalla Costa, Bruno Oscar
Querini, Carlos Alberto
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv 2-METHYLFURAN
BIOMASS
C-C COUPLING
FURFURAL
SBA-15
topic 2-METHYLFURAN
BIOMASS
C-C COUPLING
FURFURAL
SBA-15
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.
Fil: Zanuttini, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Neyertz, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ferretti, Cristián Alejandro. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Sanchez, Barbara Sabrina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description An effective catalyst for the production of branched chain fuel precursors with 15 carbon atoms (C15) from low carbon number, biomass-derived molecules is reported in this work. It shows that SBA-15 silica with the incorporation of sulfonic groups (S15) is highly active and selective for C-C coupling at low temperature, without solvent and under simple reaction conditions, giving a C15 condensation product with high selectivity, greater than 95 %, via hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) with furfural (FAL). As water was determined to have a great negative influence on the stability of these catalysts, synthesis modifications and various post-synthesis treatments were tested to improve yield of C15. As a result, it was possible to improve up to 12 % the efficiency of the reaction by incorporating hydrophobic groups in the synthesis of sulfonic SBA-15 by co-condensation. This catalyst can be recovered and recycled, preserving its stability over multiple reaction cycles.
publishDate 2023
dc.date.none.fl_str_mv 2023-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226198
Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-119397
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226198
identifier_str_mv Zanuttini, María Soledad; Tonutti, Lucas Gabriel; Neyertz, Claudia A.; Ferretti, Cristián Alejandro; Sanchez, Barbara Sabrina; et al.; Production of a high molecular weight jet-fuel precursor from biomass derived furfural and 2-methylfuran using propyl sulfonic SBA-15 catalysts; Elsevier Science; Applied Catalysis A: General; 665; 9-2023; 119383-119397
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926860X23003630
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2023.119383
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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