Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
- Autores
- Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina - Materia
-
Multiphase System
Keggin Polyoxometalate
Hydrogen Peroxide
Alcohols - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/3023
Ver los metadatos del registro completo
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Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacidsRomanelli, Gustavo PabloTundo, PietroAricó, FabioVazquez, Patricia GracielaMultiphase SystemKeggin PolyoxometalateHydrogen PeroxideAlcoholshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; ItaliaFil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; ItaliaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier Science2010-07-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3023Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-11841566-7367enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.06.015info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710001974info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:37Zoai:ri.conicet.gov.ar:11336/3023instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:37.799CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
title |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
spellingShingle |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids Romanelli, Gustavo Pablo Multiphase System Keggin Polyoxometalate Hydrogen Peroxide Alcohols |
title_short |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
title_full |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
title_fullStr |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
title_full_unstemmed |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
title_sort |
Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids |
dc.creator.none.fl_str_mv |
Romanelli, Gustavo Pablo Tundo, Pietro Aricó, Fabio Vazquez, Patricia Graciela |
author |
Romanelli, Gustavo Pablo |
author_facet |
Romanelli, Gustavo Pablo Tundo, Pietro Aricó, Fabio Vazquez, Patricia Graciela |
author_role |
author |
author2 |
Tundo, Pietro Aricó, Fabio Vazquez, Patricia Graciela |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Multiphase System Keggin Polyoxometalate Hydrogen Peroxide Alcohols |
topic |
Multiphase System Keggin Polyoxometalate Hydrogen Peroxide Alcohols |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity. Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; Italia Fil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; Italia Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina |
description |
This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-07-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/3023 Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-1184 1566-7367 |
url |
http://hdl.handle.net/11336/3023 |
identifier_str_mv |
Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-1184 1566-7367 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.06.015 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710001974 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613916684976128 |
score |
13.070432 |