Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids

Autores
Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Materia
Multiphase System
Keggin Polyoxometalate
Hydrogen Peroxide
Alcohols
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/3023
Acceder
id CONICETDig_800f2e6138ba54710623307ad48d073c
oai_identifier_str oai:ri.conicet.gov.ar:11336/3023
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacidsRomanelli, Gustavo PabloTundo, PietroAricó, FabioVazquez, Patricia GracielaMultiphase SystemKeggin PolyoxometalateHydrogen PeroxideAlcoholshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; ItaliaFil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; ItaliaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier Science2010-07-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3023Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-11841566-7367enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.06.015info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710001974info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:47:36Zoai:ri.conicet.gov.ar:11336/3023instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:47:37.025CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
title Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
spellingShingle Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
Romanelli, Gustavo Pablo
Multiphase System
Keggin Polyoxometalate
Hydrogen Peroxide
Alcohols
title_short Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
title_full Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
title_fullStr Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
title_full_unstemmed Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
title_sort Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids
dc.creator.none.fl_str_mv Romanelli, Gustavo Pablo
Tundo, Pietro
Aricó, Fabio
Vazquez, Patricia Graciela
author Romanelli, Gustavo Pablo
author_facet Romanelli, Gustavo Pablo
Tundo, Pietro
Aricó, Fabio
Vazquez, Patricia Graciela
author_role author
author2 Tundo, Pietro
Aricó, Fabio
Vazquez, Patricia Graciela
author2_role author
author
author
dc.subject.none.fl_str_mv Multiphase System
Keggin Polyoxometalate
Hydrogen Peroxide
Alcohols
topic Multiphase System
Keggin Polyoxometalate
Hydrogen Peroxide
Alcohols
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Tundo, Pietro. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Aricó, Fabio. The Interuniversity Consortium; Chemistry for the Environment; Italia
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
description This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.
publishDate 2010
dc.date.none.fl_str_mv 2010-07-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/3023
Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-1184
1566-7367
url http://hdl.handle.net/11336/3023
identifier_str_mv Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-1184
1566-7367
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2010.06.015
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736710001974
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1848597958154518528
score 12.976206

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