Cationization of polysaccharides; a path to greener derivatives with many industrial applications

Autores
Prado, Héctor Juan; Matulewicz, Maria Cristina
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cationic polysaccharides are widely used in diverse areas such as water treatment, papermaking, chemical, food, cosmetic, and petroleum industries. The combination of cationic polysaccharides with anionic polymers can lead to interpolyelectrolyte complexes with hydrogel-like structures further expanding the application of the former. The aim of the present review is to fill a gap on the literature about cationization reactions of different polysaccharides and to offer a systematic and up-to-date analysis on the subject. Polysaccharides such as starch, dextran, cellulose and its derivatives, hemicellulose, pectin, chitosan, and seaweed polysaccharides among others are considered. Cationized polysaccharides can be prepared by reaction with various reagents. The main focus is on the substitution with dialkylamino hydroxypropyl and trialkylammonium hydroxypropyl ethers, being that the most common modifications involve the introduction of the 2-hydroxy-3-(trimethylammonium)propyl group by reaction of the polysaccharide with 2,3-epoxypropyltrimethylammonium chloride in an alkaline solution. An alternative to this method involves generation of the reagent in situ from 3-chloro-2-hydroxypropyltrimethylammonium chloride. In addition, polysaccharides substituted with other type of cationic groups and amphoteric derivatives are presented. Different methods of analysis, toxicological studies and applications of the modified polymers are also included.
Fil: Prado, Héctor Juan. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina
Fil: Matulewicz, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono; Argentina
Materia
Cationic Polysaccharides
Cellulose
3-Chloro-2-Hydroxytrimethylammonium Chloride
Chitosan
2,3.Epoxypropyltrimethylammonium Chloride
Starch
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8164
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/8164
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Cationization of polysaccharides; a path to greener derivatives with many industrial applicationsPrado, Héctor JuanMatulewicz, Maria CristinaCationic PolysaccharidesCellulose3-Chloro-2-Hydroxytrimethylammonium ChlorideChitosan2,3.Epoxypropyltrimethylammonium ChlorideStarchhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Cationic polysaccharides are widely used in diverse areas such as water treatment, papermaking, chemical, food, cosmetic, and petroleum industries. The combination of cationic polysaccharides with anionic polymers can lead to interpolyelectrolyte complexes with hydrogel-like structures further expanding the application of the former. The aim of the present review is to fill a gap on the literature about cationization reactions of different polysaccharides and to offer a systematic and up-to-date analysis on the subject. Polysaccharides such as starch, dextran, cellulose and its derivatives, hemicellulose, pectin, chitosan, and seaweed polysaccharides among others are considered. Cationized polysaccharides can be prepared by reaction with various reagents. The main focus is on the substitution with dialkylamino hydroxypropyl and trialkylammonium hydroxypropyl ethers, being that the most common modifications involve the introduction of the 2-hydroxy-3-(trimethylammonium)propyl group by reaction of the polysaccharide with 2,3-epoxypropyltrimethylammonium chloride in an alkaline solution. An alternative to this method involves generation of the reagent in situ from 3-chloro-2-hydroxypropyltrimethylammonium chloride. In addition, polysaccharides substituted with other type of cationic groups and amphoteric derivatives are presented. Different methods of analysis, toxicological studies and applications of the modified polymers are also included.Fil: Prado, Héctor Juan. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; ArgentinaFil: Matulewicz, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8164Prado, Héctor Juan; Matulewicz, Maria Cristina; Cationization of polysaccharides; a path to greener derivatives with many industrial applications; Elsevier; European Polymer Journal; 52; 1-2014; 53-750014-3057enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2013.12.011info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305713005855info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:08:14Zoai:ri.conicet.gov.ar:11336/8164instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:08:15.059CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cationization of polysaccharides; a path to greener derivatives with many industrial applications
title Cationization of polysaccharides; a path to greener derivatives with many industrial applications
spellingShingle Cationization of polysaccharides; a path to greener derivatives with many industrial applications
Prado, Héctor Juan
Cationic Polysaccharides
Cellulose
3-Chloro-2-Hydroxytrimethylammonium Chloride
Chitosan
2,3.Epoxypropyltrimethylammonium Chloride
Starch
title_short Cationization of polysaccharides; a path to greener derivatives with many industrial applications
title_full Cationization of polysaccharides; a path to greener derivatives with many industrial applications
title_fullStr Cationization of polysaccharides; a path to greener derivatives with many industrial applications
title_full_unstemmed Cationization of polysaccharides; a path to greener derivatives with many industrial applications
title_sort Cationization of polysaccharides; a path to greener derivatives with many industrial applications
dc.creator.none.fl_str_mv Prado, Héctor Juan
Matulewicz, Maria Cristina
author Prado, Héctor Juan
author_facet Prado, Héctor Juan
Matulewicz, Maria Cristina
author_role author
author2 Matulewicz, Maria Cristina
author2_role author
dc.subject.none.fl_str_mv Cationic Polysaccharides
Cellulose
3-Chloro-2-Hydroxytrimethylammonium Chloride
Chitosan
2,3.Epoxypropyltrimethylammonium Chloride
Starch
topic Cationic Polysaccharides
Cellulose
3-Chloro-2-Hydroxytrimethylammonium Chloride
Chitosan
2,3.Epoxypropyltrimethylammonium Chloride
Starch
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Cationic polysaccharides are widely used in diverse areas such as water treatment, papermaking, chemical, food, cosmetic, and petroleum industries. The combination of cationic polysaccharides with anionic polymers can lead to interpolyelectrolyte complexes with hydrogel-like structures further expanding the application of the former. The aim of the present review is to fill a gap on the literature about cationization reactions of different polysaccharides and to offer a systematic and up-to-date analysis on the subject. Polysaccharides such as starch, dextran, cellulose and its derivatives, hemicellulose, pectin, chitosan, and seaweed polysaccharides among others are considered. Cationized polysaccharides can be prepared by reaction with various reagents. The main focus is on the substitution with dialkylamino hydroxypropyl and trialkylammonium hydroxypropyl ethers, being that the most common modifications involve the introduction of the 2-hydroxy-3-(trimethylammonium)propyl group by reaction of the polysaccharide with 2,3-epoxypropyltrimethylammonium chloride in an alkaline solution. An alternative to this method involves generation of the reagent in situ from 3-chloro-2-hydroxypropyltrimethylammonium chloride. In addition, polysaccharides substituted with other type of cationic groups and amphoteric derivatives are presented. Different methods of analysis, toxicological studies and applications of the modified polymers are also included.
Fil: Prado, Héctor Juan. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina
Fil: Matulewicz, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono; Argentina
description Cationic polysaccharides are widely used in diverse areas such as water treatment, papermaking, chemical, food, cosmetic, and petroleum industries. The combination of cationic polysaccharides with anionic polymers can lead to interpolyelectrolyte complexes with hydrogel-like structures further expanding the application of the former. The aim of the present review is to fill a gap on the literature about cationization reactions of different polysaccharides and to offer a systematic and up-to-date analysis on the subject. Polysaccharides such as starch, dextran, cellulose and its derivatives, hemicellulose, pectin, chitosan, and seaweed polysaccharides among others are considered. Cationized polysaccharides can be prepared by reaction with various reagents. The main focus is on the substitution with dialkylamino hydroxypropyl and trialkylammonium hydroxypropyl ethers, being that the most common modifications involve the introduction of the 2-hydroxy-3-(trimethylammonium)propyl group by reaction of the polysaccharide with 2,3-epoxypropyltrimethylammonium chloride in an alkaline solution. An alternative to this method involves generation of the reagent in situ from 3-chloro-2-hydroxypropyltrimethylammonium chloride. In addition, polysaccharides substituted with other type of cationic groups and amphoteric derivatives are presented. Different methods of analysis, toxicological studies and applications of the modified polymers are also included.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8164
Prado, Héctor Juan; Matulewicz, Maria Cristina; Cationization of polysaccharides; a path to greener derivatives with many industrial applications; Elsevier; European Polymer Journal; 52; 1-2014; 53-75
0014-3057
url http://hdl.handle.net/11336/8164
identifier_str_mv Prado, Héctor Juan; Matulewicz, Maria Cristina; Cationization of polysaccharides; a path to greener derivatives with many industrial applications; Elsevier; European Polymer Journal; 52; 1-2014; 53-75
0014-3057
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2013.12.011
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305713005855
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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