Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]

Autores
Agotegaray, Mariela Alejandra; Quinzani, Oscar Valentín; Faccio, Ricardo; Goyenola, Cecilia; Mombru, Alvaro W.
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl-formamide mol-ecules to two copper(II) ions, building a paddle-wheel dinuclear mol-ecule. The distorted square-pyramidal coordination of each CuII atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl-formamide mol-ecule. The two enanti-omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement.
Fil: Agotegaray, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Faccio, Ricardo. Universidad de la República; Uruguay
Fil: Goyenola, Cecilia. Universidad de la República; Uruguay
Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay
Materia
Copper(II)
Fenoprofen
X Ray Diffraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/95354
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/95354
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]Agotegaray, Mariela AlejandraQuinzani, Oscar ValentínFaccio, RicardoGoyenola, CeciliaMombru, Alvaro W.Copper(II)FenoprofenX Ray Diffractionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl-formamide mol-ecules to two copper(II) ions, building a paddle-wheel dinuclear mol-ecule. The distorted square-pyramidal coordination of each CuII atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl-formamide mol-ecule. The two enanti-omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement.Fil: Agotegaray, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Quinzani, Oscar Valentín. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Faccio, Ricardo. Universidad de la República; UruguayFil: Goyenola, Cecilia. Universidad de la República; UruguayFil: Mombru, Alvaro W.. Universidad de la República; UruguayWiley Blackwell Publishing, Inc2008-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95354Agotegaray, Mariela Alejandra; Quinzani, Oscar Valentín; Faccio, Ricardo; Goyenola, Cecilia; Mombru, Alvaro W.; Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 12; 12-2008; 1612-16131600-5368CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://journals.iucr.org/e/issues/2008/12/00/bg2218/bg2218.pdfinfo:eu-repo/semantics/altIdentifier/doi/10.1107/S1600536808038786info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959860/info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S1600536808038786info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:21Zoai:ri.conicet.gov.ar:11336/95354instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:21.888CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
title Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
spellingShingle Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
Agotegaray, Mariela Alejandra
Copper(II)
Fenoprofen
X Ray Diffraction
title_short Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
title_full Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
title_fullStr Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
title_full_unstemmed Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
title_sort Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]
dc.creator.none.fl_str_mv Agotegaray, Mariela Alejandra
Quinzani, Oscar Valentín
Faccio, Ricardo
Goyenola, Cecilia
Mombru, Alvaro W.
author Agotegaray, Mariela Alejandra
author_facet Agotegaray, Mariela Alejandra
Quinzani, Oscar Valentín
Faccio, Ricardo
Goyenola, Cecilia
Mombru, Alvaro W.
author_role author
author2 Quinzani, Oscar Valentín
Faccio, Ricardo
Goyenola, Cecilia
Mombru, Alvaro W.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Copper(II)
Fenoprofen
X Ray Diffraction
topic Copper(II)
Fenoprofen
X Ray Diffraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl-formamide mol-ecules to two copper(II) ions, building a paddle-wheel dinuclear mol-ecule. The distorted square-pyramidal coordination of each CuII atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl-formamide mol-ecule. The two enanti-omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement.
Fil: Agotegaray, Mariela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Quinzani, Oscar Valentín. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Faccio, Ricardo. Universidad de la República; Uruguay
Fil: Goyenola, Cecilia. Universidad de la República; Uruguay
Fil: Mombru, Alvaro W.. Universidad de la República; Uruguay
description The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed by the chelate coordination of four racemic fenoprofenate (fenoprofenate is 2,3-phenoxyphenyl propionate) anions and two dimethyl-formamide mol-ecules to two copper(II) ions, building a paddle-wheel dinuclear mol-ecule. The distorted square-pyramidal coordination of each CuII atom is made up of four O atoms of the four fenoprofenate units and another O atom from a dimethyl-formamide mol-ecule. The two enanti-omeric forms of the fenoprofenate anions are present in the complex, in an optically inactive centrosymmetric arrangement.
publishDate 2008
dc.date.none.fl_str_mv 2008-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/95354
Agotegaray, Mariela Alejandra; Quinzani, Oscar Valentín; Faccio, Ricardo; Goyenola, Cecilia; Mombru, Alvaro W.; Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 12; 12-2008; 1612-1613
1600-5368
CONICET Digital
CONICET
url http://hdl.handle.net/11336/95354
identifier_str_mv Agotegaray, Mariela Alejandra; Quinzani, Oscar Valentín; Faccio, Ricardo; Goyenola, Cecilia; Mombru, Alvaro W.; Tetra-kis[-2-(3-phenoxy-phen-yl)propionato-κ2 O:O′]bis-[(dimethyl-formamide-O)copper(II)]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 12; 12-2008; 1612-1613
1600-5368
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://journals.iucr.org/e/issues/2008/12/00/bg2218/bg2218.pdf
info:eu-repo/semantics/altIdentifier/doi/10.1107/S1600536808038786
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959860/
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S1600536808038786
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268853964374016
score 13.13397

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